Rare-earth ion crystals are a promising platform for implementing solid-state quantum interfaces, yet there are few combinations of rare-earth and host crystals that simultaneously deliver large optical absorption, narrow inhomogeneous linewidths, and long coherence times. This work investigates the optical and spin properties of
171Yb
3+ ions in YVO
4. The observed properties and simple energy-level structure of the
171Yb
3+ ion show that this material has significant potential for creating efficient quantum interfaces, such as ensemble-based memories, microwave-to-optical transducers, and optically addressable single rare-earth ion spin qubits.
Compared to other stable isotopes of
Yb+,
173Yb+ has a richer hyperfine structure, which leads to more favorable clock transitions, spectroscopic techniques for probing new physics, and more sophisticated quantum computing architectures. However, to date, its electronic spectrum remains poorly characterized. Here, we report on efficient laser cooling, state preparation, and detection of a single trapped
173Yb+ ion. The previously unobserved
2S1/2→2D3/2 electric quadrupole transition at 436 nm is coherently excited, and the isotope shift between
171Yb+ and
173Yb+ on this transition is determined with an uncertainty of 1.4 Hz. Using microwave spectroscopy, we resolve the hyperfine structure (HFS) of the
2D3/2 state with a relative uncertainty below
10−8. From the HFS measurement data, we infer for
173Yb a nuclear magnetic octupole moment
Ω=−0.062(8)(b×μN) with uncertainty reduced by more than 2 orders of magnitude compared to previous studies. The data also allow us to determine hyperfine anomalies for the
2S1/2 and
2D3/2 states.