Significant two-body losses are observed in an ultracold gas of
85Rb or
87Rb atoms in a crossed dipole trap implemented with a broadband laser with a wavelength around 1071 nm. Using available spectroscopic data on the excited states of Rb
2, as well as accurate computed transition dipole moment functions, we interpret these losses as due to photoassociation of deeply bound levels of the 0
u+ coupled states by the trapping laser, followed by spontaneous emission down to bound levels of the Rb
2 ground state thus forming ultracold molecules. The observed ratio of 3.3 between the loss rates of
87Rb and
85Rb is well reproduced by the theoretical model.