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Acta Physica Polonica A

Semiclassical Motion of Systems with Internal States

Stig Stenholm

Published Jul 1, 1994• 0 citations
Publisher

Abstract

In many fields of atomic and molecular physics we need to combination!center-of-mass motion with internal degrees of freedom.In this work, the classical motion in phase space is separated from the quantum processes by a multiple-time-scale approach.The expansion parameter is proportional to Planck's constant.The theory is given and illustrated by examples: the semiclassical description of a particle without internal states, the extraction of a classical trajectory and the derivation of the light-induced force.

DOI
10.12693/aphyspola.86.51

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In many fields of atomic and molecular physics we need to combination!center-of-mass motion with internal degrees of freedom.In this work, the classical motion in phase space is separated from the quantum processes by a multiple-time-scale approach.The expansion parameter is proportional to Planck's constant.The theory is given and illustrated by examples: the semiclassical description of a particle without internal states, the extraction of a classical trajectory and the derivation of the light-induced force.
In this paper, we consider a system with both translational degrees of freedom and a structure of discrete internal states. Applying a multiple-time-scale approach we can separate the dynamical processes describing internal quantum transitions between the states and semiclassical propagation in phase space. The freedom provided by the multiple-time-scale method seems to offer the possibility of carrying out such a separation without internal contradictions. The case with no internal states is extracted and compared with other semiclassical results in the literature; it is found that our approach can be related to these, but it is not identical with any previously reported results. When a unique particle trajectory can be defined, the procedure is shown to lead to the customary classical-path approximation often employed in scattering theory and quantum optics. This approach is generalized into a self-consistent method, but it is not expected to be applicable in the coherence-destroying case with widely separated trajectories for the internal states. The validity of the approach and its limitations are discussed.
The coupling between internal degrees of freedom of quantum systems and their overall motion in an external gravitational field plays a central role in multiple extensions of Einstein's equivalence principle to quantum physics. While previous models of such effects were predominantly restricted to linearized gravity and often required quantum particles to follow prescribed world-lines, this letter shows how such phenomena can be understood using generally covariant semi-classical approximations in the framework of quantum field theory in curved space-times. This method provides a unification and generalization of previously established results, but also predicts new effects such as an influence of internal energies on field amplitudes, as well as correction terms to the internal Schrödinger equation that give rise to Berry phases.
The quantum kinetic equation describing slow atomic motion in laser light is derived by an operational method which provides mathematical expressions with a transparent physical structure. The authors prove in a general way that the coefficients appearing in this equation, which is of a Fokker-Planck type, are simply related to the mean value and to the correlation functions of the Heisenberg radiative force of the semiclassical approach, where the atomic position is treated classically. They derive in particular a new theoretical expression for the damping force responsible for radiative cooling and they interpret it in terms of linear response theory. The authors also obtain a new crossed r-p derivative term, which does not appear in semiclassical treatments, but which they find to be very small in most situations. Finally, all the theoretical expressions derived are valid for any J g to J e transitions and are not restricted to two-level atoms.
Using very general and well established ideas of the statistical physics of macroscopic bodies, that is, of those composed of many degrees of freedom, we show how classical behavior of the center of mass motion arises from a fully quantum mechanical description of the dynamics of the whole body. We do not attempt to provide a rigorous proof of the latter statement, but rather, we show or, at least, indicate the hypotheses needed to obtain the purported result. Moreover, we neither attempt to deal with the "most general" physical situation and, instead, we concentrate on a stylized model of a small solid, yet macroscopic, that we shall call a "little stone". The main hypothesis is that a macroscopic body can be decomposed into several smaller pieces, still macroscopic, that become statistically independent due to the short-range interaction nature of their constituent atoms. The ensuing main result is that the quantum distributions of extensive variables of the body become sharply-peaked. The center of mass variables are of this type and hence their dynamics is essentially classical. We point out the crucial role played by the external potential, in which the motion occurs, as the macroscopic agent that executes the "measurement" process of the center of mass.
We study the back-reaction of quantum systems onto classical ones. Taking the starting point that semi-classical physics should be described at all times by a point in classical phase space and a quantum state in Hilbert space, we consider an unravelling approach, describing the system in terms of a classical-quantum trajectory. We derive the general form of the dynamics under the assumptions that the classical trajectories are continuous and the evolution is autonomous, and the requirement that the dynamics is linear and completely positive in the combined classical-quantum state. This requirement is necessary in order to consistently describe probabilities, and forces the dynamics to be stochastic when the back-reaction is non-zero. The resulting equations of motion are natural generalisations of the standard semi-classical equations of motion, but since the resulting dynamics is linear in the combined classical-quantum state, it does not lead to the pathologies which usually follow from evolution laws based on expectation values. In particular, the evolution laws we present account for correlations between the classical and quantum system, which resolves issues associated with other semi-classical approaches. In addition, despite a breakdown of predictability in the classical degrees of freedom, the quantum state evolves deterministically conditioned on the classical trajectory, provided a trade-off between decoherence and diffusion is saturated. As a result, the quantum state remains pure when conditioned on the classical trajectory. To illustrate these points, we numerically simulate a number of semi-classical toy models, including one of vacuum fluctuations as a source driving the expansion of the universe. Finally, we discuss the application of these results to semi-classical gravity, and the black-hole information problem.
Mixed quantum-classical equations of motion are derived for a quantum subsystem of light (mass m) particles coupled to a classical bath of massive (mass M) particles. The equation of motion follows from a partial Wigner transform over the bath degrees of freedom of the Liouville equation for the full quantum system, followed by an expansion in the small parameter μ=(m/M)1/2 in analogy with the theory of Brownian motion. The resulting mixed quantum-classical Liouville equation accounts for the coupled evolution of the subsystem and bath. The quantum subsystem is represented in an adiabatic (or other) basis and the series solution of the Liouville equation leads to a representation of the dynamics in an ensemble of surface-hopping trajectories. A generalized Pauli master equation for the evolution of the diagonal elements of the density matrix is derived by projection operator methods and its structure is analyzed in terms of surface-hopping trajectories.