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Frequency measurement of the S-2(1/2)-D-2(3/2) electric quadrupole transition in a single Yb-171(+) ion.

Stephen A. Webster, R. M. Godun, S. A. King, Guilong Huang, Barney Walton, Tsatourian, Helen S. Margolis, S.N. Lea, Peter M. W. Gill

Published Jan 1, 2010• 1 citation
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We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition (2)S(1/2)(F=0)→(2)F(7/2)(F=3) in a single trapped (171)Yb(+) ion. The extraordinary features of this transition result from the long natural lifetime and from the 4f(13)6s(2) configuration of the upper state. The electric-quadrupole moment of the (2)F(7/2) state is measured as -0.041(5)ea(0)(2), where e is the elementary charge and a(0) the Bohr radius. We also obtain information on the differential scalar and tensorial components of the static polarizability and of the probe-light-induced ac Stark shift of the octupole transition. With a real-time extrapolation scheme that eliminates this shift, the unperturbed transition frequency is realized with a fractional uncertainty of 7.1×10(-17). The frequency is measured as 642 121 496 772 645.15(52) Hz.