Density-matrix renormalization group calculations are used to determine the ground-state phase diagram of the mixed spin-(1/2, 5/2, 1/2) Heisenberg chain whose backbone consists of regularly alternating $s=1/2$ and $S=5/2$ spins, the latter of which are coupled to additional $s=1/2$ spins providing lateral branching. The proposed magnetic structure aims to describe the main characteristics of the heterotrimetallic coordination polymer $[{\mathrm{Cu}}^{\mathrm{II}}{\mathrm{Mn}}^{\mathrm{II}}({\mathrm{L}}^{1})][{\mathrm{Fe}}^{\mathrm{III}}(\mathrm{bpb}){(\mathrm{CN})}_{2}]\phantom{\rule{4pt}{0ex}}\ifmmode\cdot\else\textperiodcentered\fi{}\phantom{\rule{4pt}{0ex}}{\mathrm{ClO}}_{4}\phantom{\rule{4pt}{0ex}}\ifmmode\cdot\else\textperiodcentered\fi{}\phantom{\rule{4pt}{0ex}}{\mathrm{H}}_{2}\mathrm{O}$. The full ground-state phase diagram in the parameter space exchange anisotropy versus magnetic field unveils special critical points, at which the intermediate magnetization plateaus emergent at 3/7 and 5/7 of the saturation magnetization vanish. A detailed description of the zero-temperature magnetization process and pair entanglement entropy is accomplished with the aim to distinguish the main coupling regimes. A scaling analysis is performed to accurately locate Kosterlitz-Thouless and Gaussian critical points. In particular, we introduce a new finite-size scaling protocol to properly extract the critical parameters from the size dependence of the magnetic-field range corresponding to the magnetization plateau in the close vicinity of the Gaussian point at which two gapped phases meet.
Density-matrix renormalization group calculations are used to determine the ground-state phase diagram of the mixed spin-(1/2, 5/2, 1/2) Heisenberg chain whose backbone consists of regularly alternating s=1/2 and S=5/2 spins, the latter of which are coupled to additional s=1/2 spins providing lateral branching. The proposed magnetic structure aims to describe the main characteristics of the heterotrimetallic coordination polymer [CuIIMnII(L1)][FeIII(bpb)(CN)2]\ifmmode⋅\else\textperiodcentered\fiClO4\ifmmode⋅\else\textperiodcentered\fiH2O. The full ground-state phase diagram in the parameter space exchange anisotropy versus magnetic field unveils special critical points, at which the intermediate magnetization plateaus emergent at 3/7 and 5/7 of the saturation magnetization vanish. A detailed description of the zero-temperature magnetization process and pair entanglement entropy is accomplished with the aim to distinguish the main coupling regimes. A scaling analysis is performed to accurately locate Kosterlitz-Thouless and Gaussian critical points. In particular, we introduce a new finite-size scaling protocol to properly extract the critical parameters from the size dependence of the magnetic-field range corresponding to the magnetization plateau in the close vicinity of the Gaussian point at which two gapped phases meet.
The mixed-spin Ising-Heisenberg and Heisenberg branched chains whose magnetic backbone consists of regularly alternating spins 1/2 and 5/2, the latter of which are additionally coupled to an extra spin 1/2 providing lateral branching, are investigated using exact analytical and density matrix renormalization group (DMRG) methods. The proposed spin-chain models capture some relevant aspects of the heterotrimetallic coordination polymer $[\mathrm{Cu}\mathrm{Mn}(\mathrm{L})][\mathrm{Fe}(\mathrm{bpb}){(\mathrm{CN})}_{2}]\ifmmode\cdot\else\textperiodcentered\fi{}\mathrm{Cl}{\mathrm{O}}_{4}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{H}}_{2}\mathrm{O}$. The mixed spin-(1/2,5/2,1/2) Ising-Heisenberg branched chain is exactly solvable under the assumption of an Ising-like exchange coupling along the chain, while the lateral branching is treated as an anisotropic XXZ Heisenberg exchange interaction. We determine the ground-state phase diagram and quantify a bipartite quantum entanglement between dimers at lateral branching. It is shown that the studied mixed-spin Ising-Heisenberg branched chain accurately fits available experimental data for temperature dependence of the magnetic susceptibility. The ground-state phase diagram of the analogous mixed spin-(1/2,5/2,1/2) Heisenberg branched chain is obtained within the DMRG method. The ground-state phase diagrams of the Ising-Heisenberg and its full Heisenberg counterpart are contrasted. In particular, the ground-state phase diagram of the mixed-spin Heisenberg branched chain involves a special Gaussian critical point, for which a proper finite-size scaling analysis is provided to accurately estimate its location and the correlation length critical exponent.
The spin-1/2 Ising-Heisenberg branched chain composed of regularly alternating Ising spins and Heisenberg dimers involving an additional side branching is rigorously solved in a magnetic field by the transfer-matrix approach. The ground-state phase diagram, the magnetization process and the concurrence measuring a degree of bipartite entanglement within the Heisenberg dimers are examined in detail. Three different ground states were found depending on a mutual interplay between the magnetic field and two different coupling constants: the modulated quantum antiferromagnetic phase, the quantum ferrimagnetic phase, and the classical ferromagnetic phase. Two former quantum ground states are manifested in zero-temperature magnetization curves as intermediate plateaus at zero and one-half of the saturation magnetization, whereas the one-half plateau disappears at a triple point induced by a strong-enough ferromagnetic Ising coupling. The ground-state phase diagram and zero-temperature magnetization curves of the analogous spin-1/2 Heisenberg branched chain were investigated using density-matrix renormalization group calculations. The latter fully quantum Heisenberg model involves, besides two gapful phases manifested as zero and one-half magnetization plateaus, gapless quantum spin-liquid phase. The intermediate one-half plateau of the spin-1/2 Heisenberg branched chain vanishes at Kosterlitz-Thouless quantum critical point between gapful and gapless quantum ground states unlike the triple point of the spin-1/2 Ising-Heisenberg branched chain.
In this work, we study alternating mixed-spin (s,S) Heisenberg ladders in the magnetic field h density matrix renormalization group and linear spin-wave calculations. The h versus interchain coupling J_{⊥} phase diagram for the (1/2,1) case is investigated in detail. In particular, we demonstrate the compatibility between the critical line estimates and magnetic ordering by analyzing chains with variable values of J_{⊥} and of h along the chain, J_{⊥} and h scans, and considering the usual case of chains with uniform couplings. The magnetization plateau at 1/3 of saturation magnetization, 1/3 plateau, is observed for J_{⊥}>0 and in a limited range for J_{⊥}<0. The critical Kosterlitz-Thouless transition point, where the 1/3 plateau closes, is identified through a finite-size analysis of the transverse spin correlation functions.
The interplay between competing interactions in low-dimensional quantum many-body systems gives rise to a wide variety of quantum phases and critical phenomena. Motivated by this scenario, we investigate the quantum phase diagram of the mixed-spin 1 2 , 1 antiferromagnetic Heisenberg chain with modulated single-ion anisotropy by means of the density matrix renormalization group (DMRG) method. The resulting phase diagram comprises four distinct quantum phases: three gapped phases, namely the 1 / 3 magnetization plateau, the trivial nonmagnetic (TnM) phase, and the topological valence-bond-solid (TVBS) phase, together with a gapless Luttinger liquid (LL) phase. The different phases are characterized through the analysis of magnetization, spin correlation functions, nonlocal order parameters, and entanglement-based observables. The TVBS phase is identified by the presence of exponentially localized edge states, finite values of the nonlocal string order parameter and twist operator, and the characteristic degeneracy pattern of the entanglement spectrum. The boundaries of the LL phase are determined from the transverse spin correlation function and the corresponding Luttinger parameter, revealing two Kosterlitz–Thouless transition lines characterized by the critical value K c = 2.0 , in agreement with finite-size scaling analyses of the spin gap. In addition, we identify a Gaussian critical line associated with the topological quantum phase transition separating the TVBS and TnM phases. By employing the tangential finite-size scaling approach, we accurately determine this critical line by extracting the correlation-length critical exponent ν and the conformal field theory central charge c . Our results demonstrate that the competition between exchange interactions and modulated single-ion anisotropy gives rise to a rich interplay between topology, quantum criticality, and magnetic ordering, highlighting the fundamental role of these interactions in determining the ground-state properties of low-dimensional quantum spin systems.
We investigate the ground-state phase diagram of a frustrated spin-1/2 Heisenberg ladder in the transverse magnetic field with an anisotropic inter-rung exchange coupling α. This bond-anisotropic parameter continuously interpolates among the Ising-like limit α=0, the isotropic point α=1, and the XY-dominated regime α≫1. Using density-matrix renormalization group calculations within a matrix-product-state framework, we analyze bipartite entanglement, magnetization, and spin correlations to characterize the emergent quantum phases. We identify six distinct ground-state phases, including rung-singlet, Haldane-like, Tomonaga-Luttinger liquid, canted Ising-ordered, XY-polarized, and ordered ferromagnetic states. While magnetization and local correlations provide a first insight into phase classifications, the finite-size scaling of the entanglement measures offers a more sensitive and unified diagnostics of both gapped and gapless regimes. In the gapless regime, we extract the central charge c≃1, confirming Tomonaga-Luttinger liquid behavior, while at the transition between the canted Ising and ferromagnetic phases, we observe c≃1/2, consistent with the Ising universality. Finally, we find that both the Haldane-like behavior and the extended critical Tomonaga-Luttinger liquid regime are strongly confined to the vicinity of the isotropic point α=1.
= 1 andS=3/2dimers is studied in detail as a function of two considered exchange interactions ascribed to similar and dissimilar spin pairs. At zero magnetic field, the ferrimagnetic mixed spin-(1, 1, 3/2, 3/2) Heisenberg tetramer chain displays, depending on a mutual interplay between two considered exchange interactions, three distinct gapped valence-bond-solid phases separated by gap-closing quantum critical points. Using density-matrix renormalization group calculations we construct the full ground-state phase diagram as a function of the interaction ratio and magnetic field, which exhibits besides three gapped valence-bond-solid phases special Kosterlitz-Thouless and topological quantum critical points. A tangential finite-size scaling analysis is employed to obtain precise estimates of the zero-field valence-bond-solid transitions and unveil their common logarithmic correction to a power-law scaling of the correlation length.