We have seen that we can understand matter with increasing complexity from the simple two-level system up to molecules. We further studied, how they can be control by classical electromagnetic fields to a very high accuracy. In the last lecture we also studied how we can understand the electromagnetic field as an ensemble of quantum mechanical photon modes. So in today’s lecture we will focus on the interaction between atoms and light, which is in a particularly clean set-up, namely cavity quantum electrodynamics. The fundamental ingredients are sketched in Fig. [305911].
We have seen that we can understand matter with increasing complexity from the simple two-level system up to molecules. We further studied, how they can be control by classical electromagnetic fields to a very high accuracy. In the last lecture we also studied how we can understand the electromagnetic field as an ensemble of quantum mechanical photon modes. So in today’s lecture we will focus on the interaction between atoms and light, which is in a particularly clean set-up, namely cavity quantum electrodynamics. The fundamental ingredients are sketched in Fig. [305911].
It was first realized by Purcell (1) that the spontaneous emission rate of a quantum system can be enhanced or suppressed by placing it in a resonant radiofrequency cavity. Spontaneous emission as it was first theoretically described by Einstein (2) is not a pure property of matter. It is described by matter coupled to quantized radiation field modes, which can be manipulated in an artificial structure such as a cavity. Cavity quantum electrodynamics (QED) is used to describe such effects that intimately depend on the fact that light is made of photons. Cavity QED has been extensively studied in atoms and the experimental proof was awarded with the Nobel Prize in 2012 (3). It has been applied to cooling of single atoms and for the detection of single atoms and creating and studying states with few photons and few atoms (4). In more recent developments these ideas have been extended to manipulate electronic states (5) and vibrations in molecules (6, 7). In PNAS, Flick et al. (8) introduce recent theoretical developments for the application of cavity QED to molecules and suggest possible novel applications to photochemistry. These include nonadiabatic dynamics of molecules in cavities, the modification of molecular properties, and the integration of QED with density functional theory.
A quantized electromagnetic field mode can be described as a harmonic oscillator whose coordinate is the electric field displacement (Fig. 1 A ). The zero point energy translates into a nonvanishing field intensity ⟨ e 2 ⟩ in the ground state | 0 ⟩ (vacuum fluctuations). The electric vacuum field increases for a small cavity volume e c = ℏ ω c V ϵ 0 , [1]
Fig. 1.
( A ) Illustration of the standing wave cavity mode and the resulting field quantization (Fock states). ( B ) Combined matter-field states (dressed states, | ± , n ⟩ …
[↵][1]1To whom correspondence should be addressed. Email: smukamel{at}uci.edu.
[1]: #xref-corresp-1-1
The coupling of two or more quantum mechanical states representing two different quantum mechanical systems leads to a new class of quantum mechanical states called entangled states. In this case, a two level atom, coupled to a single mode quantized electromagnetic field, results in the dressed state. The Dressed State is an example of Entangled States. This state exhibits a quantum correlation between the two entities, atom and field. The interaction energy of the atom and the quantized field can be written, in the dipolar interaction case, in the same way as in the semi classical theory. The emission of a photon by an atom creates an electromagnetic field that can act with the atom itself. An atom in the excited state, in the absence of a field, decays exponentially with time. This is Wigner Weisskopf model for spontaneous emission.
The interaction of light with matter is at the heart of quantum optics, which itself enables insight into the fundamental aspects of quantum mechanics. First experimental access to this research field has been realized by coupling atoms to light. Here, the transition between discrete energy states of the atom is associated with the absorption and emission of a photon, a single quantum of the electromagnetic field. As a central aspect of quantum optics, the light-emitter interaction can be significantly enhanced by placing the emitter in optical cavity that is on resonance with the emitter. In recent years, this has led to a rapidly evolving research field known as cavity quantum electrodynamics (CQED). In CQED two different regimes are distinguished: the strong and the weak coupling regimes. In the strong coupling regime, the emitted photon is reflected from the cavity mirrors and eventually reabsorbed by the emitter. In contrast, the weak coupling regime describes the irreversible emission, where the photon leaks out of the cavity before it can be reabsorbed. Both the weak and strong coupling regimes enabled fundamental experiments for a better understanding of quantum optical phenomena. \n \n \n \nCQED grants access to the quantum world and hence offers potentially revolutionizing applications, particularly in the field of quantum information processing. A central aspect for the successful implementation of quantum applications is the system's scalability. Unfortunately, placing atoms deterministically inside a cavity remains technologically elaborate and hence minimizes the prospect of scaling a atom-CQED system. \n \nA possibility to address this issue is to implement CQED in the solid state, where sophisticated fabrication strategies allow miniaturization and scalability of the system. Particularly the development of self-assembled quantum dots (QD) in semiconductors represent a promising route. QDs can be considered as artificial atoms that mimic the atomic two-level system. These structures interact strongly with light and therefore have the potential for replacing atoms in CQED. As a central advantage, QDs are naturally trapped, which greatly simplifies the deterministic incorporation into the cavity. \n \nIn recent years, many efforts have been made to couple self-assembled QDs to microcavities. Generally, the successful implementation of CQED requires a cavity with a high quality factor Q and a low mode volume. In a majority of the approaches, the high Q/small mode volume cavities were monolithically defined around the QD, embedding the QD at a fixed position inside the cavity. Both the weak and strong coupling regimes have been reached with these systems. However, for future applications they suffer from several disadvantages. The fixed position of the QD inside the cavity minimizes the prospects for spectral tunability and spatial positioning the QD inside the cavity. Furthermore, prospects for further increasing of the cavity Q-factor and minimization of the mode volume remain limited in these systems. \n \nIn this thesis the mentioned disadvantages are addressed by developing a fully tunable miniaturized Fabry-Pérot microcavity with low mode volume. The design enables both spatial positioning of the emitter inside the cavity and spectral tunability. Successful coupling of a single QD to the microcavity is demonstrated including the strong coupling regime. Further a new approach to decrease the cavity mode volume is presented, where we demonstrate weak coupling is achieved
In nanostructures where confinement of a light wave is manifested, the conditions of strong light–matter interaction become feasible. In this case, the approach based on the environment-sensitive probability of quantum transitions is no longer applicable. Instead, joint states of light and matter should be considered and their time evolution explored. The content of the previous Chapters 13 and 14 can then be treated as a perturbative description of light–matter interactions with a limited range of applicability. In this chapter a few representative examples are given where joint light–matter states bring an unprecedented flavor of nanophotonic engineering to frozen excited states for quantum memory devices and single photon sources for quantum computing. Cavity quantum electrodynamics in the strong coupling regime The regime of strong coupling of a quantum system with an electromagnetic field can be performed in a cavity with very high Q-factor, where light can survive for a reasonable time until it either leaves the cavity or dies through being absorbed by cavity imperfections. In a simplified picture, a photon once emitted stays within the cavity so long that it is absorbed again by the emitter (an imaginary two-level system, an atom or a quantum dot). Thus spontaneous emission appears to become reversible. In a more accurate presentation, an “atom+field” state develops which evolves via oscillations between the state | E , 0〉 (“excited atom, depleted cavity”) to the state | G , 1〉 (“de-excited atom, a photon in the cavity”).
We present the results of the numerical investigations of light-matter interactions in one and two dimensions from the quantum mechanical perspective.We investigate the dynamics of two-level systems coupled to quantized electromagnetic fields.We construct a quantum mechanical model to demonstrate how light interacts with classical objects such as mirrors and beam-splitters made from group of atoms, where each atom is modelled as a two-level system.We have been able to simulate behaviour of a singlephoton being reflected and transmitted as a process of absorption and re-emission by the atoms.i
Rapid advances in quantum technology have made possible the control of quantum states of elementary material quantum systems, such as atoms or molecules, and of the electromagnetic radiation field resulting from spontaneous photon emission of their unstable excited states to such a level of precision that subtle quantum electrodynamical phenomena have become observable experimentally. Recent developments in the area of quantum information processing demonstrate that characteristic quantum electrodynamical effects can even be exploited for practical purposes provided the relevant electromagnetic field modes are controlled by appropriate cavities. A central problem in this context is the realization of an ideal transfer of quantum information between a state of a material quantum system and a quantum state of the electromagnetic radiation field which contains a small number or even a single photon only. Despite much recent work in cavity quantum electrodynamics, which has explored this problem successfully in cases in which the number of accessible electromagnetic field modes is strongly restricted by a cavity, currently still much less is known about ideal quantum state transfer between matter and few-photon quantum states of the electromagnetic field in the extreme opposite case of free space. In this contribution we review recent work which explores characteristic quantum electrodynamical phenomena governing the interaction of a material quantum system with the electromagnetic field in extreme many-mode cases which are close to cavity-free situations. For this purpose the simplest possible quantum electrodynamical situation, namely the interaction of a single material two-level system with the wave packet of a single optical photon, is investigated in free space and in situations in which a large cavity modifies the mode structure of the electromagnetic field modes. It is demonstrated that perfect excitation of an atom by a properly shaped single-photon wave packet is possible even in free space. In particular, it is demonstrated that perfect excitation of an atom can be achieved by a single optical photon which is prepared initially in an appropriate superposition of plane-wave modes, provided this photon is focused subsequently onto the absorbing atom by a parabolic cavity.