The study of electronic transport through strongly confined, interacting open quantum systems has regained considerable interest over the past years. One main motivation behind this concerns the possibility of time-dependently controlled operations on individual electrons, promising applications in, e.g., metrology and electron-based quantum computing. In particular, fundamental questions of quantum thermodynamics and the practical necessity to recover waste heat from nanocircuits have attracted attention towards electronic energy currents.The research articles covered by this thesis contribute to this topic by deriving and exploring a fundamental symmetry relation -- the fermionic duality. This duality applies to the quantum master equation of any locally interacting, fermionic open quantum system tunnel-coupled to non-interacting reservoirs. It yields a crosslink between modes and amplitudes corresponding to the evolution rates in the time-dependent decay of the open-system state. This crosslink involves a mapping between the system of interest and a dual system with inverted environment potentials, local energies, and thus especially inverted interactions. The duality thereby explains many, at first sight unintuitive, transport features and significantly improves their analytic accessability. In particular, we can understand why charge- and energy currents through quantum dots with strong local Coulomb repulsion in fact exhibit features of electron-electron attraction, both in the time-dependent decay after a sudden switch and in the stationary limit.More fundamental insights are obtained by identifying the duality to be rooted in Pauli's exclusion principle and the parity superselection principle. Namely, this implies that the duality is independent of, and hence combinable with many other general symmetries, including particle-hole symmetry, time-reversal symmetry, detailed balance and Onsager reciprocity. Especially the combination with the latter offers a novel perspective on the thermoelectric response of open, locally interacting electronic nanosystems.
The study of electronic transport through strongly confined, interacting open quantum systems has regained considerable interest over the past years. One main motivation behind this concerns the possibility of time-dependently controlled operations on individual electrons, promising applications in, e.g., metrology and electron-based quantum computing. In particular, fundamental questions of quantum thermodynamics and the practical necessity to recover waste heat from nanocircuits have attracted attention towards electronic energy currents.The research articles covered by this thesis contribute to this topic by deriving and exploring a fundamental symmetry relation -- the fermionic duality. This duality applies to the quantum master equation of any locally interacting, fermionic open quantum system tunnel-coupled to non-interacting reservoirs. It yields a crosslink between modes and amplitudes corresponding to the evolution rates in the time-dependent decay of the open-system state. This crosslink involves a mapping between the system of interest and a dual system with inverted environment potentials, local energies, and thus especially inverted interactions. The duality thereby explains many, at first sight unintuitive, transport features and significantly improves their analytic accessability. In particular, we can understand why charge- and energy currents through quantum dots with strong local Coulomb repulsion in fact exhibit features of electron-electron attraction, both in the time-dependent decay after a sudden switch and in the stationary limit.More fundamental insights are obtained by identifying the duality to be rooted in Pauli's exclusion principle and the parity superselection principle. Namely, this implies that the duality is independent of, and hence combinable with many other general symmetries, including particle-hole symmetry, time-reversal symmetry, detailed balance and Onsager reciprocity. Especially the combination with the latter offers a novel perspective on the thermoelectric response of open, locally interacting electronic nanosystems.
We consider the exact time-evolution of a broad class of fermionic open quantum systems with both strong interactions and strong coupling to wide-band reservoirs. We present a nontrivial fermionic duality relation between the evolution of states (Schrödinger) and of observables (Heisenberg). We show how this highly nonintuitive relation can be understood and exploited in analytical calculations within all canonical approaches to quantum dynamics, covering Kraus measurement operators, the Choi-Jamiołkowski state, time-convolution and convolutionless quantum master equations and generalized Lindblad jump operators. We discuss the insights this offers into the divisibility and causal structure of the dynamics and the application to nonperturbative Markov approximations and their initial-slip corrections. Our results underscore that predictions for fermionic models are already fixed by fundamental principles to a much greater extent than previously thought.
We consider the exact time-evolution of a broad class of fermionic open quantum systems with both strong interactions and strong coupling to wide-band reservoirs. We present a nontrivial fermionic duality relation between the evolution of states (Schr\"odinger) and of observables (Heisenberg). We show how this highly nonintuitive relation can be understood and exploited in analytical calculations within all canonical approaches to quantum dynamics, covering Kraus measurement operators, the Choi-Jamio{\l}kowski state, time-convolution and convolutionless quantum master equations and generalized Lindblad jump operators. We discuss the insights this offers into the divisibility and causal structure of the dynamics and the application to nonperturbative Markov approximations and their initial-slip corrections. Our results underscore that predictions for fermionic models are already fixed by fundamental principles to a much greater extent than previously thought.
This thesis is concerned with modelling the dynamics of open quantum systems in several different contexts. Of principal interest is the manner in which the environment can modify, or even dominate, a system’s quantum behaviour in order to facilitate the transport of energetic excitations. In the first research chapter, a time-local, non-Markovian quantum master equation is derived in a variationally defined reference frame, for networks of two-level systems coupled to bosonic environments. The predictions of this master equation are then compared with those derived using both weak-coupling and polaron approximations. The variational master equation is found to agree with these standard approaches in their regimes of validity, whilst interpolating between them in intermediate parameter regimes. The second research chapter focusses on the dynamics of a superconducting double quantum dot embedded in a resonant circuit. The device is considered in a regime where the ground state consists of a coherent spatial superposition of a single Cooper pair, which can be excited by a variety of interactions with the environment. The relevant transition rates are calculated and the processes responsible are identified. A numerical simulation of the system is then used to explain experimental data, and show that for certain parameters a significant fraction of excitations occur via absorption of photons from the environment. The final chapter considers a model for an olfactory receptor, in which odorant molecules are recognised by their vibrational modes. Electron transfer occurs in the receptor, dependent on the presence of a vibrational mode of the right frequency. A quantum master equation for the system is derived, and the resulting dynamics is compared to earlier semi-classical treatments. The behaviour of the receptor is found to be sensitive not only to the frequency of the vibrational mode, but also to the character of the surrounding environment. Increased dissipation on the odorant mode, as well as the presence of higher frequencies in the environment is found to improve the frequency resolution of the receptor.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
Modern quantum materials host a wide range of electronic phases in which transport properties are governed by strong interactions and collective effects. This thesis investigates charge, heat, and momentum transport in interacting electronic systems across different theoretical frameworks, ranging from Fermi liquid theory to strongly coupled strange metals.The first part of the thesis focuses on two-dimensional Fermi liquids at finite temperature, where rapid electron-electron scattering can give rise to hydrodynamic behavior. A kinetic-theory framework allowing an exact treatment of quasiparticle distribution functions beyond the asymptotic low-temperature regime is used to compute the full spectrum of collective modes, providing a detailed characterization of long-lived odd-parity excitations and the intermediate transport regime between ballistic and hydrodynamic flow. The same framework is employed to determine the shear viscosity of interacting electron liquids beyond conventional perturbative limits.The second part of the thesis concerns strongly interacting quantum systems where the quasiparticle picture breaks down.Holographic duality is used to study transport and thermoelectric response in quantum critical systems subject to periodic potentials, providing a controlled framework for momentum relaxation and magnetotransport in non-Fermi liquids. The thesis further develops holographic models of collective charge dynamics in systems with dynamical electromagnetism, including bulk plasmons and surface plasmon polaritons, and explores connections between Fermi surface physics and holographic gauge-field dynamics.
Abstract Processes at the nanoscale happen far away from the thermodynamic limit, far from equilibrium and are dominated by fluctuations and, perhaps, even quantum effects. This book establishes a consistent thermodynamic framework for such processes by combining tools from non-equilibrium statistical mechanics and the theory of open quantum systems. The book is accessible for graduate students and of interest to all researchers striving for a deeper understanding of the laws of thermodynamics beyond their traditional realm of applicability. It puts most emphasis on the microscopic derivation and understanding of key principles and concepts as well as their interrelation. The topics covered in this book include (quantum) stochastic processes, (quantum) master equations, local detailed balance, classical stochastic thermodynamics, (quantum) fluctuation theorems, strong coupling and non non-Markovian effects, thermodynamic uncertainty relations, operational approaches, Maxwell's demon and time-reversal symmetry, among other topics. Furthermore, the book treats a few applications in detail to illustrate the general theory and its potential for practical applications. These are single-molecule pulling experiments, quantum transport and thermoelectric effects in quantum dots, the micromaser and related set-ups in quantum optics.