This thesis is concerned with modelling the dynamics of open quantum systems in several different contexts. Of principal interest is the manner in which the environment can modify, or even dominate, a system’s quantum behaviour in order to facilitate the transport of energetic excitations. In the first research chapter, a time-local, non-Markovian quantum master equation is derived in a variationally defined reference frame, for networks of two-level systems coupled to bosonic environments. The predictions of this master equation are then compared with those derived using both weak-coupling and polaron approximations. The variational master equation is found to agree with these standard approaches in their regimes of validity, whilst interpolating between them in intermediate parameter regimes. The second research chapter focusses on the dynamics of a superconducting double quantum dot embedded in a resonant circuit. The device is considered in a regime where the ground state consists of a coherent spatial superposition of a single Cooper pair, which can be excited by a variety of interactions with the environment. The relevant transition rates are calculated and the processes responsible are identified. A numerical simulation of the system is then used to explain experimental data, and show that for certain parameters a significant fraction of excitations occur via absorption of photons from the environment. The final chapter considers a model for an olfactory receptor, in which odorant molecules are recognised by their vibrational modes. Electron transfer occurs in the receptor, dependent on the presence of a vibrational mode of the right frequency. A quantum master equation for the system is derived, and the resulting dynamics is compared to earlier semi-classical treatments. The behaviour of the receptor is found to be sensitive not only to the frequency of the vibrational mode, but also to the character of the surrounding environment. Increased dissipation on the odorant mode, as well as the presence of higher frequencies in the environment is found to improve the frequency resolution of the receptor.
This thesis is concerned with modelling the dynamics of open quantum systems in several different contexts. Of principal interest is the manner in which the environment can modify, or even dominate, a system’s quantum behaviour in order to facilitate the transport of energetic excitations. In the first research chapter, a time-local, non-Markovian quantum master equation is derived in a variationally defined reference frame, for networks of two-level systems coupled to bosonic environments. The predictions of this master equation are then compared with those derived using both weak-coupling and polaron approximations. The variational master equation is found to agree with these standard approaches in their regimes of validity, whilst interpolating between them in intermediate parameter regimes. The second research chapter focusses on the dynamics of a superconducting double quantum dot embedded in a resonant circuit. The device is considered in a regime where the ground state consists of a coherent spatial superposition of a single Cooper pair, which can be excited by a variety of interactions with the environment. The relevant transition rates are calculated and the processes responsible are identified. A numerical simulation of the system is then used to explain experimental data, and show that for certain parameters a significant fraction of excitations occur via absorption of photons from the environment. The final chapter considers a model for an olfactory receptor, in which odorant molecules are recognised by their vibrational modes. Electron transfer occurs in the receptor, dependent on the presence of a vibrational mode of the right frequency. A quantum master equation for the system is derived, and the resulting dynamics is compared to earlier semi-classical treatments. The behaviour of the receptor is found to be sensitive not only to the frequency of the vibrational mode, but also to the character of the surrounding environment. Increased dissipation on the odorant mode, as well as the presence of higher frequencies in the environment is found to improve the frequency resolution of the receptor.
Almost all quantum systems are open; interactions with the surrounding \nenvironment generally lead to complex dissipative behaviour with a sensitive \ndependence on the details of the system-environment coupling. This \nthesis presents results from theoretical investigations into such behaviour \nin single and two-site quantum systems with a particular emphasis on \nstrong system-environment coupling regimes, and also the effects of spatial \ncorrelations in the environment fluctuations. \nWithin a weak system-environment coupling framework, it is found \nthat an increased level of correlation is able to protect coherence shared \nbetween two spatially separated two-level quantum systems. Moreover, \nit is found that these correlations are in fact able to generate coherence \nbetween the two systems, and in certain regimes, cause the systems to \nbecome entangled. \nUsing a polaron transform strong coupling master equation technique, \nthe discussion is extended to the strong system-environment coupling or \nhigh temperature regime. To assess the validity of this approach in an experimentally \nrelevant system, it is applied to the description of excitonic \nRabi oscillations in a resonantly driven quantum dot. For most of the \nparameters of interest, the strong coupling theory is found to be valid over \na far greater range of temperatures and coupling strengths than the standard \nweak-coupling theory. The coherent or incoherent nature of energy \ntransfer dynamics is then studied by applying the strong coupling theory \nto a donor-acceptor pair model. Increased spatial correlations are found \nto extend the range of temperatures which allow coherent energy transfer \nto take place. \nFinally, a variational theory is introduced which allows for exploration \nof certain parameter regimes where both the weak-coupling and strong coupling \ntheories become invalid. The variational theory is then used \nto investigate the ground state properties of a double two-level impurity \nmodel. High levels of spatial correlation are found to suppress the tunnelling \namplitude within each impurity.
This thesis covers open quantum systems and information transfer in the face of \ndissipation and disorder through numerical simulation. \nIn Chapter 3 we present work on an open quantum system comprising a two-level system, single bosonic mode and dissipative environment; we have included \nthe bosonic mode in the exact system treatment. This model allows us to gain an understanding of an environment’s role in small energy transfer systems. We observe \nhow the two-level system-mode coupling strength and the spectral density form characterising the environment interplay, affecting the system’s coherent behaviour. We \nfind strong coupling and a spectral density resonantly peaked on the two-level system oscillation frequency enhances the system’s coherent oscillatory dynamics. \nChapter 4 focusses on a physically motivated study of chain and ladder spin \ngeometries and their use for entanglement transfer between qubits. We consider a \nnitrogen vacancy centre qubit implementation with nitrogen impurity spin-channels \nand demonstrate how matrix product operator techniques can be used in simulations \nof this physical system. We investigate coupling parameters and environmental decay \nrates with respect to transfer efficiency effects. Then, in turn, we simulate the effects \nof missing channel spins and disorder in the spin-spin coupling. We conclude by \nhighlighting where our considered channel geometries outperform each other. \nThe work in Chapter 5 is an investigation into the feasibility of routing entanglement between distant qubits in 2D spin networks. We no longer consider a physical \nimplementation, but keep in mind the effects of dissipative environments on entanglement transfer systems. Starting with a single sending qubit-ancilla and multiple \naddressable receivers, we show it is possible to target a specific receiver and establish transferred entanglement between it and the sender’s ancilla through eigenstate tunnelling techniques. We proceed to show that eigenstate tunnelling-mediated entanglement transfer can be achieved simultaneously from two senders across one spin network.
Strong coupling between a quantum system and its many-body environment is becoming an increasingly important topic for many branches of physics. Numerous systems of experimental and technological relevance demonstrate strong system-environment coupling, leading to complex dynamical behaviour. This thesis is concerned with two particular examples of such systems, namely quantum dots (QDs) and excitonic energy transfer (EET) in molecular systems. Traditional quantum optics treatments are often insufficient to describe the transient, steady state, and optical properties of QDs due to system-environment correlations. In contrast, we present a modified theory of quantum optics capable of capturing the influence of a thermal environment on the behaviour of QDs. Using this framework we demonstrate a striking departure of the emission spectra and photon measurement statistics of a classically driven QD when compared to an analogous atomic system. Furthermore, in contradiction to accepted notions of decoherence and dissipation, we show that the interaction between a QD and its thermal environment induces non-classical light-matter correlations in an otherwise semi-classical regime of cavity quantum electrodynamics. Away from QDs, we develop the reaction coordinate (RC) formalism to describe the dynamics of a system coupled to a low frequency environment — a regime important to EET systems. We do so by identifying and incorporating important environmental degrees of freedom into an enlarged system Hamiltonian. Uniquely, this approach gives insight directly into the dynamical evolution of the environment and correlations accumulated between the system and environment. Furthermore, it is demonstrated that these corre- lations persist into the steady state, generating non-canonical equilibrium states of the system and environment. We then apply the RC model to describe EET in a molecular dimer, highlighting the effect that under- and over-damped environments have on the excitation dynamics. In doing so, we show interactions between the dimer and a structured environment can significantly enhance the energy transfer rate.
This thesis investigates two thematic lines of research, both underpinned by non-Markovian system-reservoir interactions in quantum optics. The overarching focus is on modelling the open system dynamics in a non-perturbative fashion, broadly on - though not restricted to - instances when the environment is structured. A theory is developed by means of enlarging the open system over environmental degrees of freedom to include memory effects in its dynamics. This is achieved using an established technique that involves mapping a bosonic environment onto a 1D chain of harmonic oscillators. Within this setting, we apply a Heisenberg equation-of-motion approach to derive an exact set coupled differential equations for the open system and a single auxiliary oscillator of the chain. The combined equations are shown to have their interpretation rooted in a quantum Markov stochastic process. Including the auxiliary chain oscillator as part of the original system then enables us to obtain an exact master equation for the enlarged system, avoiding any need for the Born-Markov approximations. Our method is valid for a dissipative two-state system, with cases of multiple excitations and added driving discussed. Separately, we apply the framework of quantum Darwinism to an atom-cavity system, and, subsequently, to a more general multiple-environment model. In both cases, the time-dependent spread of correlations between the open system and fractions of the environment is analysed during the course of the decoherence process. The degree to which information is redundant across different fractions is checked to infer the emergence of classicality. In the second case, we go further and present a decomposition of information in terms of its quantum and classical correlations. A quantitative measure of redundancy is also studied with regard to its ability to witness non-Markovian behaviour. Besides fundamental interest, our results have application to quantum information processing and quantum technologies, keeping in mind the potential beneficial use of non-Markovian effects in reservoir engineering.
The subject of this thesis is the study of a particular open quantum system consisting of a resonator coupled to a superconducting single electron transistor (SSET). The theoretical model we use is applicable to both mechanical and superconducting stripline resonators leading to a large parameter regime that can be explored. The SSET is tuned to the Josephson quasi-particle resonance, in which the transport occurs via Cooper pairs coherently tunnelling across one junction followed by the incoherent tunnelling of quasi-particles across the other. The SSET can be thought of as an artificial atom since it has a similar energy level structure and transitions to an atom. We investigate to what extent the current and current noise through the SSET can be used to infer the state of the resonator. In order to carry out these investigations we describe the system with a Born-Markov master equation, which we solve numerically. The evolution of the density matrix of the system is described by a Liouvillian superoperator. In order to better understand the results we perform an eigenfunction expansion of the Liouvillian, which is useful in connecting the behaviour of the resonator to the current noise. The mixture of coherent and incoherent processes in the SSET leads to interesting back action effects on the resonator. For weak coupling the SSET acts as an effective thermal bath on the resonator. Depending on the operating point the resonator can be either heated or cooled in comparison to its surroundings. In this regime we can use a set of mean field equations to describe the system and also capture certain aspects of the behaviour with some simple models. For sufficient coupling the SSET can drive the resonator into states of self-sustained oscillations. At the transition between stable and oscillating states of the resonator we also find regions of co-existence between oscillating and fixed point states of the resonator. The current noise provides a way to identify these transitions and the state of the resonator. The system also shows analogies with quantum optical systems such as the micromaser. We calculate the linewidth of the resonator and find deviations from the expected behaviour.
The subject of this thesis is the modelling of non-Markovian open quantum systems, in particular those that display memory effects due to time-delayed interactions. I study these systems in the context of a model of an open quantum system that interacts with a bosonic environment by way of particle exchanges. While the model is flexible enough to describe quite general memory effects, this work focuses to a large extent on a single prototypical system. This system emits into a coherent feedback loop with a time delay, and it captures the essential phenomena we aim to model. Within the context of this general model, I develop a general approach to spontaneous emission from singly-excited systems and show how to calculate the corresponding emission spectra. I also evaluate two commonly-used perturbative techniques in the context of spontaneous emission from singly-excited systems, coming to the conclusion that perturbation theory is of limited use in modelling open quantum systems with delayed feedback. I then turn attention to exact equations of motion for more general non-Markovian open quantum systems. I derive Heisenberg–Langevin equations that describe a large class of such systems, and solve these equations analytically for a series of simple bosonic systems. I also use the theory of cascaded open quantum systems to simulate systems with delayed coherent feedback in the limit of long time delay, and compare the results of these simulations with the analytic solutions obtained in the Heisenberg picture. Finally, I show that once we have a solution to a given Heisenberg–Langevin equation we can derive an alternative, time-local equation of motion that describes equivalent dynamics, and that these time-local Heisenberg–Langevin equations can in turn be used to derive corresponding time-local master equations. These master equations provide an exact description of the non-Markovian dynamics, but this treatment is limited to linear, bosonic systems—those systems for which the Heisenberg–Langevin equations can be solved in closed form. I discuss the prospect of generalising these master equations to take into account nonlinear and fermionic systems.