Abstract The original Bose–Einstein condensation (BEC) was theoretically established in the 1920s, for the case of an ideal gas of boson particles (a consequence of the symmetry of the wave function). In the 1990s, it was realized in systems of atomic alkali gases. At the beginning of the 21st century, investigators considered its emergence in solid‐state matter, and a BEC‐like phenomenon was observed in the case of bosonic quasiparticles (elementary excitations in solids). Both types of BEC can occur in a condensation in conditions of thermodynamic equilibrium. A third type of what has been dubbed a BEC in non‐equilibrium conditions can occur in systems of bosonic quasiparticles (phonons, magnons, excitons); this phenomenon (which can be considered as cases of systems with complex behavior) follows after a certain threshold of intensity of an external pumping source is achieved. In this review, after brief comments on the two types of BEC in equilibrium, a description is presented on how a BEC‐like phenomenon arises in systems of quasiparticles that are driven away from thermodynamic equilibrium, and several examples are described. This description is given within a unique theoretical framework, and a comparison with experimental results is performed; in addition, the possible technological applications are outlined.
Abstract The original Bose–Einstein condensation (BEC) was theoretically established in the 1920s, for the case of an ideal gas of boson particles (a consequence of the symmetry of the wave function). In the 1990s, it was realized in systems of atomic alkali gases. At the beginning of the 21st century, investigators considered its emergence in solid‐state matter, and a BEC‐like phenomenon was observed in the case of bosonic quasiparticles (elementary excitations in solids). Both types of BEC can occur in a condensation in conditions of thermodynamic equilibrium. A third type of what has been dubbed a BEC in non‐equilibrium conditions can occur in systems of bosonic quasiparticles (phonons, magnons, excitons); this phenomenon (which can be considered as cases of systems with complex behavior) follows after a certain threshold of intensity of an external pumping source is achieved. In this review, after brief comments on the two types of BEC in equilibrium, a description is presented on how a BEC‐like phenomenon arises in systems of quasiparticles that are driven away from thermodynamic equilibrium, and several examples are described. This description is given within a unique theoretical framework, and a comparison with experimental results is performed; in addition, the possible technological applications are outlined.
Introduction Bose–Einstein condensation (BEC) is one of the most intriguing phenomena in physics. The basic idea goes back to the 1920s, when Einstein made predictions for the behavior of atoms at sufficiently low temperatures and high densities. However, it took seven decades for experimental physicists to realize this phase under the low-density conditions envisioned by Einstein. In the intermediate period there were many experiments in which aspects of BEC played important roles. Therefore, phenomena such as superfluidity and superconductivity were connected to BEC long before its 1995 realization in ultra-cold, low-density atomic vapors. Since BEC can be discussed with very many different backgrounds and applications in mind, the subject can sometimes be overwhelming for interested students. There is a very good reason why a chapter on BEC does not belong in this book. In all the other chapters here, the processes described involve one or at most two atoms, and the interactions that play a role are between the particles that constitute the atom, namely between the nucleus (or nuclei) and their electrons. The interactions are described quantum mechanically by their Hamiltonian that can always be written exactly in non-relativistic terms, and in some cases can even be solved exactly. This makes atoms and molecules a branch of physics where comparisons between theory and experiments become very meaningful since theoretical predictions are often confirmed to very high accuracy. In BEC, it is the interactions among many atoms that are the key for understanding the phenomenon. Although in principle one could write a Hamiltonian for a Bose condensed gas, its large number of particles makes this not very practical. The starting point for the description of a BEC is in the area of many-body physics that belongs to the expertise of condensed-matter physicists. The interactions between ~10 23 electrons in a solid state with a lattice formed by ~10 23 ions resemble the kind of interactions in a BEC much more closely than the simple fewbody interactions in an atom or molecule. Thus all the theoretical models that have been described up to now are not applicable for the contents of this chapter.
Quantum systems consisting of many particles are both interesting from the physics and the mathematics perspective. One aspect that makes them fascinating from the physics point of view is that they can exhibit quantum effects on macroscopic scales such as Bose-Einstein condensation. This phenomenon, first predicted 100 years ago by Bose [19] and Einstein [44], occurs when a dilute gas of bosons is cooled down to very low temperatures. Below a certain critical temperature a condensate forms, meaning that a macroscopic fraction of the particles is in the same one-particle state, and thus, quantum phenomena become relevant on length scales much larger than the individual atom. The occurrence of Bose-Einstein condensation is also related to superfluidity as suggested in [88]. Bose-Einstein condensation has been achieved experimentally independently by the groups of Cornell and Wieman [3] and Ketterle [40] earning them a Nobel prize in 2001. While Bose and Einstein analyzed theoretically the non-interacting gas, an effective theory describing weakly interacting Bose gases was proposed by Bogoliubov in 1947 with the goal of explaining the occurrence of superfluidity in liquid helium [18]. Using assumptions such as that condensation indeed occurs, his theory yields predictions for the low-energy states of the system. Seen from the mathematics perspective, describing the Bose gas is an interesting challenge due to the strong correlations between particles introduced by the interaction making this case much harder to study than the non-interacting one. In particular, a proof that Bose-Einstein condensation occurs in the thermodynamic limit for continuous systems is still out of reach. However, there has been a lot of work regarding the rigorous analysis of bosonic systems in various relevant regimes. This thesis contains three new contributions establishing rigorous results on bosonic systems in different, physically relevant settings. It is based on the articles [37, 27, 31]. The first result concerns the time-evolution of initially trapped Bose gases in the ultra-dilute Gross-Pitaevskii regime. Under some assumptions on the initial data satisfied in particular by a class of states that are expected to approximate the ground state in a trap, we derive a quasi-free approximation that is close to the true solution in L2-norm. In particular, we show that this approximate wave function is described in terms of a Bose-Einstein condensate in a one-particle state following the time-dependent Gross-Pitaevskii equation together with pair excitations with respect to this condensate. As a corollary, we establish a central limit theorem for bounded one-particle observables. The second result is a simple proof of Bose-Einstein condensation for interacting, ultra-dilute gases. More specifically, we consider scalings interpolating between the Gross-Pitaevskii regime and the thermodynamic limit. While condensation had been shown to hold in these regimes before, the advantage of the method used here is its simplicity. Lastly, the third result establishes an upper bound on the ground state energy of a dilute Bose gas in the thermodynamic limit. It captures rigorously the third order correction to the energy per unit volume for sufficiently low densities as predicted in the physics literature first by Wu and subsequently others. Full-text embargoed until: 2026-01-01
Bose-Einstein condensation (BEC) is a thermodynamic phase transition of an interacting Bose gas. Its key signatures are remarkable quantum effects like superfluidity and a phonon-like Bogoliubov excitation spectrum, which have been verified for atomic BECs. In the solid state, BEC of exciton-polaritons has been reported. Polaritons are strongly coupled light-matter quasiparticles in semiconductor microcavities and composite bosons. However, they are subject to dephasing and decay and need external pumping to reach a steady state. Accordingly the polariton BEC is a nonequilibrium process of a degenerate polariton gas in self-equilibrium, but out of equilibrium with the baths it is coupled to and therefore deviates from the thermodynamic phase transition seen in atomic BECs. Here we show that key signatures of BEC can even be observed without fulfilling the self-equilibrium condition in a highly photonic quantum degenerate nonequilibrium system.
This article reviews recent investigations on the phenomenon of Bose-Einstein condensation of dilute gases. Since the experimental observation of quantum degeneracy in atomic gases, the research activity in the field of coherent matter-waves literally exploded. The present topical review aims to give an introduction into the thermodynamics of Bose-Einstein condensation, a general overview over experimental techniques and investigations, and a theoretical foundation for the description of bosonic many-body quantum systems.
Bose-Einstein condensation is a unique phase transition in that it is not driven by interparticle interactions, but can theoretically occur in an ideal gas, purely as a consequence of quantum statistics. This chapter addresses the question, ‘ How is this ideal Bose gas condensation modified in the presence of interactions between the particles?’ This seemingly simple question turns out to be surprisingly difficult to answer. Here we outline the theoretical background to this question and discuss some recent measurements on ultracold atomic Bose gases that have sought to provide some answers. Introduction Unlike the vast majority of phase transitions, Bose-Einstein condensation (BEC) is not driven by interparticle interactions but can theoretically occur in an ideal (noninteracting) gas, purely as a consequence of quantum statistics. However, in reality, interactions are needed for a Bose gas to remain close to thermal equilibrium. It is thus interesting to discuss if something close to ideal gas BEC can be observed in a real system and what happens in the vicinity of the BEC transition in the presence of interparticle interactions. These simple questions have not been easy to answer, either theoretically or experimentally. The theoretical foundations for studying the effect of interactions on Bose condensed systems were laid over half a century ago by Bogoliubov [1], Penrose and Onsager [2], and Belieav [3], among others. These works initially focused on zerotemperature properties and were extended to nonzero temperature in the pioneering papers of Lee, Huang, and Yang [4, 5, 6, 7]. At that time, the main experimental system was liquid He-4 in which the inter-particle interactions are strong, making connections with theory difficult. The realisation in 1995 of BEC in weakly interacting ultracold atomic gases [8, 9] thus opened up the possibility to experimentally revisit some of these long-discussed questions. This was further aided by, among other advances, the use of Feshbach resonances to tune the interaction strength in atomic gases [10, 11]. Thus, in the last twenty years the study of ultracold Bose gases has been very successful (see Chapter 3 for an insightful account of selected topics and surprising developments over this exciting period). However, the fact that, until recently, ultracold atoms were confined using harmonic potentials has hindered the study of the BEC transition itself.
The peculiarities in the Bose-Einstein condensation of particles and quasiparticles are discussed. The difference between the condensation of conserved and unconserved particles is analyzed. A classification of quasiparticles is given. The emphasis is made on the ability of particles and quasiparticles to condense. Illustrations include: general Bose-condensed atomic systems, such as ensembles of trapped atoms, Bose gases with conserved and unconserved number of atoms, vibrating atoms in double-well lattices, Holstein-Primakoff magnons, Schwinger bosons, slave bosons, and the condensation of singletons and triplons. The basic difference is that the system of particles, whose total number is conserved, can form equilibrium as well as nonequilibrium condensates, while unconserved particles can condense only in a nonequilibrium system subject to external pumping supporting the density of these particles sufficient for their condensation. The examples of such a nonequilibrium condensation of unconserved particles are the Bose-Einstein condensation of excitons, polaritons, and photons. Elementary collective excitations, such as bogolons and phonons, being self-consistently defined, do not condense. Magnons cannot condense in equilibrium systems. Controversies, existing in literature with regard to the Bose-Einstein condensation of some quasiparticles, are explained. Pushing a system out of equilibrium may favor the condensation of unconserved quasiparticles, but suppresses the condensate fraction of conserved particles.