Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Europhysics Letters (EPL)

Chemical oscillation in ultracold chemistry

Subhrajit Modak, Priyam Das, Challenger Mishra, Prasanta Kumar Panigrahi

Published Feb 1, 2024• 2 citations
Publisher

Abstract

Abstract We demonstrate the occurrence of oscillatory reactions in the ultra-cold chemistry of atom-molecular Bose-Einstein condensate. Nonlinear oscillations in the mean-field dynamics occur for a specific range of elliptic modulus, giving rise to both in- and out-phase modulations in the atom-molecule population density. The reaction front velocity is found to be controlled by photoassociation, which also regulates the condensate density. Two distinct pairs of in-phase bright localized gap solitons are found as exact solutions, the existence of one of which necessarily requires a background. Cnoidal atomic density waves along with a plane-wave molecular motion are observed in both attractive and repulsive domains. The role of intra- and inter-species interactions on both existence and stability is explicated in the presence of photoassociation.

DOI
10.1209/0295-5075/ad259e

Related papers

Chemical Oscillation in Ultracold Chemistry

Subhrajit Modak, Priyam Das, Challenger Mishra +1 more

We demonstrate the occurrence of oscillatory reactions in the ultra-cold chemistry of atom-molecular Bose-Einstein condensate. Nonlinear oscillations in the mean-field dynamics occur for a specific range of elliptic modulus, giving rise to both in- and out-phase modulations in the atom-molecule population density. The reaction front velocity is found to be controlled by photoassociation, which also regulates the condensate density. Two distinct pair of in-phase bright localized gap solitons are found as exact solutions, existence of one of which necessarily requires a background. Cnoidal atomic density-waves in a plane wave molecular background are observed in both attractive and repulsive domains. Role of intra- and inter-species interactions on both existence and stability is explicated in the presence of photoassociation.

arXiv:1806.01255•Jun 4, 2018•1 citation

An Investigation of the Collective Modes and Phases of Bose-Einstein Condensates

Priyam Das

Bose-Einstein condensate (BEC) is a new state of matter, experimentally realized in a dilute alkali gas of weakly interacting bosons. The gas is cooled to very low temperatures, of the order of nano-Kelvin, at which point a large fraction of the atoms occupy the lowest quantum state. Under such conditions, the quantum effects become apparent on a macroscopic scale. Many fundamental ideas of quantum mechanics have been realized and proven to be true in experiments, by studying the Bose-Einstein condensates. Amongst them, the observation of macroscopic matter wave interference, the creation of vortices, dark and bright solitons etc, find special mention. The dynamics of this system in presence of an optical lattice reveals a superfluid to Mott insulator quantum phase transition. This has opened a new avenue for research on BEC and its applications. From a theoretical standpoint, the dynamics of BEC can be described by means of an effective mean-field theory. This formalism is much simpler than the many-body Schr¨odinger equation and based on a classical nonlinear evolution equation, known as Gross-Pitaevskii equation. The nonlinear nature of the GPE leads to several interesting phenomena like soliton propagation, vortices, four wave mixing etc., which are closely related to nonlinear fiber optics. The present thesis deals with nonlinear excitations and different phases of BEC and is organized as follows: after a brief introduction, in chapter two, we start with BEC in a one-dimensional shallow optical lattice, experiencing both cubic and quintic nonlinearity. A superfluid density wave, of twice the periodicity of lattice potential, is identified. This indicates matter redistribution, where atoms from neighbouring sites have been depleted leading to a density wave behaviour. Interestingly, it ceases to exist when only one of these interactions is operative. We predict the loss of superfluidity through a classical dynamical phase transition, where modulational instability leads to the loss of phase coherence. In presence of pure two-body interaction, the superfluid density shows a periodicity commensurate with the lattice potential. Apart from the superfluid state, a density wave insulating phase is also found to exist, possessing two frequency modulations commensurate with the lattice potential. A dynamical phase transition connects the superfluid phase with an insulating phase, which in turn, is connected with the density wave insulating phase. The solutions are found to be marginally stable, as per the Vakhitov-Kolokolov (VK) criterion. Chapter three describes the dynamics of the atomic-molecular Bose-Einstein condensate (AMBEC) by mean-field Gross-Pitaevskii equation (GPE), taking into account the atom-molecular interaction, as well as atom-molecule inter-conversion. The two-body atom-atom, atom-molecule and molecule-molecule interactions are analogous to the cubic nonlinearity of the standard GPE, whereas, the quadratic nonlinear term arising from the inter-conversion between atoms and molecules is identical to the scenario in strongly coupled BEC in one dimension. The presence of both weak and strong interactions adds further richness to this system. We find the molecular BEC possesses a complex dark (grey) soliton, while the atomic condensate is a bright one. The energy and momentum of this system is computed in order to see the effect of the both weak and strong interactions on Lieb mode profile and compare it with the pure atomic condensate profile. Another class of solutions exist in this system, where both atomic and molecular condensates possess bright solitons. In chapter four, we investigate the effect of a harmonic trap on the dynamics of grey solitons in Bose-Einstein condensates. It is observed that, these nonlinear excitations of the cigar-shaped Bose-Einstein condensate have strong coupling with the trap at low momenta and hence can be effectively isolated from the Bogoliubov sound modes, which respond weakly to harmonic confinement. This strong coupling with the trap also makes the grey soliton amenable for control and manipulation through trap modulation and temporal variation of the two-body interaction. We have shown that in presence of an expulsive oscillator trap, the grey soliton gets amplified, while having a compression in its width. Exact solutions are also obtained in case of the two component Bose-Einstein condensates (TBECs), where one component is a grey soliton and the other a bright one. The presence of the trap and inter-species interaction significantly affects the grey soliton dynamics. Similar to the single component, in the present case, we have shown that both grey and bright soliton can be compressed simultaneously. A detailed study of the energy and momentum of the soliton is reported, in order to find the effect of the trap on the Lieb mode. In chapter five, we study a BEC-defect complex in a quasi-one dimensional scenario, where the defect atom moves in the condensate with constant velocity. Explicit solutions of the coupled mean-field equations, describing defect-grey soliton dynamics are obtained, demonstrating the coexistence of grey soliton and a localized defect. Unlike the case of dark soliton, where the defect trapping center has vanishing superfluid density, the moving grey soliton necessarily possesses a finite superfluid component at the defect location. The presence of the defect can lower the grey soliton’s maximum velocity, as compared to the defect free case, where the maximum velocity is the sound velocity. We have also carried out the stability analysis of the obtained solutions using renormalized momentum formalism and Vakhitov-Kolokolov criteria and find that the obtained solutions are stable through both the methods. The grey soliton’s energy gets substantially modified through its interaction with the defect, opening up the possibility of its control through defect dynamics. Chapter six describes a parametrically forced Bose-Einstein condensate in the presence of a general moving optical lattice. The interaction between the atoms in the condensate and the time dependent lattice potential leads to a novel propagating superfluid matter wave, which can be controlled through chirp management. This system, when placed in a trap, accelerates and undergoes rapid nonlinear compression, controlled by the chirp. The density achieves its maximum, when the matter wave changes direction. It is also shown that this system exhibits dynamical superfluid insulator transition, where superfluidity breaks down and the condensate transits to an insulating phase. The stability has been investigated using Vakhitov-Kolokolov criterion and found that it depends on the chirp, as well as on the nature of the atom-atom interaction. The exact expression for energy is obtained and analyzed in detail to gain physical understanding of the chirp management of the sinusoidal excitations and also the dynamical phase transition.

•Jul 1, 2011•0 citations

New cross-phase modulated localized solitons in coupled atomic-molecular BEC

Mishra, Challenger, Priyam Das, Krishna Rai Dastidar +1 more

The interacting atom-molecule BEC (AMBEC) dynamics is investigated in the mean field ap- proach. The presence of atom-atom, atom-molecule and molecule-molecule interactions, coupled with a characteristically different interaction representing atom-molecule interconversion, endows this system with nonlinearities, which differ significantly from the standard Gross-Pitaevskii (GP) equation. Exact localized solutions are found to belong to two distinct classes. The first ones are analogous to the soliton solutions of the weakly coupled GP equation, whereas the second non- equivalent class is related to the solitons of the strongly coupled BEC. Distinct parameter domains characterize these solitons, some of which are analogous to the complex profile Bloch solitons in magnetic systems. These localized solutions are found to represent a variety of phenomena, which include co-existence of both atom-molecule complex and miscible-immiscible phases. Numerical sta- bility is explicitly checked, as also the stability analysis based on the study of quantum uctuations around our solutions. We also find out the domain of modulation instability in this system.

arXiv:1109.5571•Sep 26, 2011•0 citations

Atom–molecule coherence in a Bose–Einstein condensate

Elizabeth A. Donley, N. R. Claussen, Sarah T. Thompson +1 more

Abstract Recent advances in the precise control of ultracold atomic systems have led to the realisation of Bose–Einstein condensates (BECs) and degenerate Fermi gases. An important challenge is to extend this level of control to more complicated molecular systems. One route for producing ultracold molecules is to form them from the atoms in a BEC. For example, a two-photon stimulated Raman transition in a 87Rb BEC has been used to produce 87Rb2 molecules in a single rotational-vibrational state1, and ultracold molecules have also been formed2 through photoassociation of a sodium BEC. Although the coherence properties of such systems have not hitherto been probed, the prospect of creating a superposition of atomic and molecular condensates has initiated much theoretical work3, 4, 5, 6, 7. Here we make use of a time-varying magnetic field near a Feshbach resonance8, 9, 10, 11, 12 to produce coherent coupling between atoms and molecules in a 85Rb BEC. A mixture of atomic and molecular states is created and probed by sudden changes in the magnetic field, which lead to oscillations in the number of atoms that remain in the condensate. The oscillation frequency, measured over a large range of magnetic fields, is in excellent agreement with the theoretical molecular binding energy, indicating that we have created a quantum superposition of atoms and diatomic molecules—two chemically different species.

WORLD SCIENTIFIC eBooks•Jan 1, 2008•1 citation

Bifurcations and bistability in cavity-assisted photoassociation of Bose-Einstein-condensed molecules

M. Jääskeläinen, Jae‐Yoon Jeong, Christopher P. Search

We study the photoassociation of Bose-Einstein condensed atoms into molecules using an optical cavity field. The driven cavity field introduces a dynamical degree of freedom into the photoassociation process, whose role in determining the stationary behavior has not previously been considered. The semiclassical stationary solutions for the atom and molecules as well as the intracavity field are found and their stability and scaling properties are determined in terms of experimentally controllable parameters including driving amplitude of the cavity and the nonlinear interactions between atoms and molecules. For weak cavity driving, we find a bifurcation in the atom and molecule number occurs that signals a transition from a stable steady state to nonlinear Rabi oscillations. For a strongly driven cavity, there exists bistability in the atom and molecule number.

arXiv:0706.0032•Physical Review A•Dec 18, 2007•4 citations

Three-dimensional solitons in coupled atomic-molecular Bose-Einstein condensates

Timothy G. Vaughan, Karen V. Kheruntsyan, P. D. Drummond

We present a theoretical analysis of three-dimensional (3D) matter-wave solitons and their stability properties in coupled atomic and molecular Bose-Einstein condensates (BECs). The soliton solutions to the mean-field equations are obtained in an approximate analytical form by means of a variational approach. We investigate soliton stability within the parameter space described by the atom-molecule conversion coupling, the atom-atom $s$-wave scattering, and the bare formation energy of the molecular species. In terms of ordinary optics, this is analogous to the process of sub- or second-harmonic generation in a quadratic nonlinear medium modified by a cubic nonlinearity, together with a phase mismatch term between the fields. While the possibility of formation of multidimensional spatiotemporal solitons in pure quadratic media has been theoretically demonstrated previously, here we extend this prediction to matter-wave interactions in BEC systems where higher-order nonlinear processes due to interparticle collisions are unavoidable and may not be neglected. The stability of the solitons predicted for repulsive atom-atom interactions is investigated by direct numerical simulations of the equations of motion in a full 3D lattice. Our analysis also leads to a possible technique for demonstrating the ground state of the Schr\"odinger-Newton and related equations that describe Bose-Einstein condensates with nonlocal interparticle forces.

arXiv:cond-mat/0410234•Physical Review A•Dec 14, 2004•13 citations
Abstract We demonstrate the occurrence of oscillatory reactions in the ultra-cold chemistry of atom-molecular Bose-Einstein condensate. Nonlinear oscillations in the mean-field dynamics occur for a specific range of elliptic modulus, giving rise to both in- and out-phase modulations in the atom-molecule population density. The reaction front velocity is found to be controlled by photoassociation, which also regulates the condensate density. Two distinct pairs of in-phase bright localized gap solitons are found as exact solutions, the existence of one of which necessarily requires a background. Cnoidal atomic density waves along with a plane-wave molecular motion are observed in both attractive and repulsive domains. The role of intra- and inter-species interactions on both existence and stability is explicated in the presence of photoassociation.
We demonstrate the occurrence of oscillatory reactions in the ultra-cold chemistry of atom-molecular Bose-Einstein condensate. Nonlinear oscillations in the mean-field dynamics occur for a specific range of elliptic modulus, giving rise to both in- and out-phase modulations in the atom-molecule population density. The reaction front velocity is found to be controlled by photoassociation, which also regulates the condensate density. Two distinct pair of in-phase bright localized gap solitons are found as exact solutions, existence of one of which necessarily requires a background. Cnoidal atomic density-waves in a plane wave molecular background are observed in both attractive and repulsive domains. Role of intra- and inter-species interactions on both existence and stability is explicated in the presence of photoassociation.
Bose-Einstein condensate (BEC) is a new state of matter, experimentally realized in a dilute alkali gas of weakly interacting bosons. The gas is cooled to very low temperatures, of the order of nano-Kelvin, at which point a large fraction of the atoms occupy the lowest quantum state. Under such conditions, the quantum effects become apparent on a macroscopic scale. Many fundamental ideas of quantum mechanics have been realized and proven to be true in experiments, by studying the Bose-Einstein condensates. Amongst them, the observation of macroscopic matter wave interference, the creation of vortices, dark and bright solitons etc, find special mention. The dynamics of this system in presence of an optical lattice reveals a superfluid to Mott insulator quantum phase transition. This has opened a new avenue for research on BEC and its applications. From a theoretical standpoint, the dynamics of BEC can be described by means of an effective mean-field theory. This formalism is much simpler than the many-body Schr¨odinger equation and based on a classical nonlinear evolution equation, known as Gross-Pitaevskii equation. The nonlinear nature of the GPE leads to several interesting phenomena like soliton propagation, vortices, four wave mixing etc., which are closely related to nonlinear fiber optics. The present thesis deals with nonlinear excitations and different phases of BEC and is organized as follows: after a brief introduction, in chapter two, we start with BEC in a one-dimensional shallow optical lattice, experiencing both cubic and quintic nonlinearity. A superfluid density wave, of twice the periodicity of lattice potential, is identified. This indicates matter redistribution, where atoms from neighbouring sites have been depleted leading to a density wave behaviour. Interestingly, it ceases to exist when only one of these interactions is operative. We predict the loss of superfluidity through a classical dynamical phase transition, where modulational instability leads to the loss of phase coherence. In presence of pure two-body interaction, the superfluid density shows a periodicity commensurate with the lattice potential. Apart from the superfluid state, a density wave insulating phase is also found to exist, possessing two frequency modulations commensurate with the lattice potential. A dynamical phase transition connects the superfluid phase with an insulating phase, which in turn, is connected with the density wave insulating phase. The solutions are found to be marginally stable, as per the Vakhitov-Kolokolov (VK) criterion. Chapter three describes the dynamics of the atomic-molecular Bose-Einstein condensate (AMBEC) by mean-field Gross-Pitaevskii equation (GPE), taking into account the atom-molecular interaction, as well as atom-molecule inter-conversion. The two-body atom-atom, atom-molecule and molecule-molecule interactions are analogous to the cubic nonlinearity of the standard GPE, whereas, the quadratic nonlinear term arising from the inter-conversion between atoms and molecules is identical to the scenario in strongly coupled BEC in one dimension. The presence of both weak and strong interactions adds further richness to this system. We find the molecular BEC possesses a complex dark (grey) soliton, while the atomic condensate is a bright one. The energy and momentum of this system is computed in order to see the effect of the both weak and strong interactions on Lieb mode profile and compare it with the pure atomic condensate profile. Another class of solutions exist in this system, where both atomic and molecular condensates possess bright solitons. In chapter four, we investigate the effect of a harmonic trap on the dynamics of grey solitons in Bose-Einstein condensates. It is observed that, these nonlinear excitations of the cigar-shaped Bose-Einstein condensate have strong coupling with the trap at low momenta and hence can be effectively isolated from the Bogoliubov sound modes, which respond weakly to harmonic confinement. This strong coupling with the trap also makes the grey soliton amenable for control and manipulation through trap modulation and temporal variation of the two-body interaction. We have shown that in presence of an expulsive oscillator trap, the grey soliton gets amplified, while having a compression in its width. Exact solutions are also obtained in case of the two component Bose-Einstein condensates (TBECs), where one component is a grey soliton and the other a bright one. The presence of the trap and inter-species interaction significantly affects the grey soliton dynamics. Similar to the single component, in the present case, we have shown that both grey and bright soliton can be compressed simultaneously. A detailed study of the energy and momentum of the soliton is reported, in order to find the effect of the trap on the Lieb mode. In chapter five, we study a BEC-defect complex in a quasi-one dimensional scenario, where the defect atom moves in the condensate with constant velocity. Explicit solutions of the coupled mean-field equations, describing defect-grey soliton dynamics are obtained, demonstrating the coexistence of grey soliton and a localized defect. Unlike the case of dark soliton, where the defect trapping center has vanishing superfluid density, the moving grey soliton necessarily possesses a finite superfluid component at the defect location. The presence of the defect can lower the grey soliton’s maximum velocity, as compared to the defect free case, where the maximum velocity is the sound velocity. We have also carried out the stability analysis of the obtained solutions using renormalized momentum formalism and Vakhitov-Kolokolov criteria and find that the obtained solutions are stable through both the methods. The grey soliton’s energy gets substantially modified through its interaction with the defect, opening up the possibility of its control through defect dynamics. Chapter six describes a parametrically forced Bose-Einstein condensate in the presence of a general moving optical lattice. The interaction between the atoms in the condensate and the time dependent lattice potential leads to a novel propagating superfluid matter wave, which can be controlled through chirp management. This system, when placed in a trap, accelerates and undergoes rapid nonlinear compression, controlled by the chirp. The density achieves its maximum, when the matter wave changes direction. It is also shown that this system exhibits dynamical superfluid insulator transition, where superfluidity breaks down and the condensate transits to an insulating phase. The stability has been investigated using Vakhitov-Kolokolov criterion and found that it depends on the chirp, as well as on the nature of the atom-atom interaction. The exact expression for energy is obtained and analyzed in detail to gain physical understanding of the chirp management of the sinusoidal excitations and also the dynamical phase transition.
The interacting atom-molecule BEC (AMBEC) dynamics is investigated in the mean field ap- proach. The presence of atom-atom, atom-molecule and molecule-molecule interactions, coupled with a characteristically different interaction representing atom-molecule interconversion, endows this system with nonlinearities, which differ significantly from the standard Gross-Pitaevskii (GP) equation. Exact localized solutions are found to belong to two distinct classes. The first ones are analogous to the soliton solutions of the weakly coupled GP equation, whereas the second non- equivalent class is related to the solitons of the strongly coupled BEC. Distinct parameter domains characterize these solitons, some of which are analogous to the complex profile Bloch solitons in magnetic systems. These localized solutions are found to represent a variety of phenomena, which include co-existence of both atom-molecule complex and miscible-immiscible phases. Numerical sta- bility is explicitly checked, as also the stability analysis based on the study of quantum uctuations around our solutions. We also find out the domain of modulation instability in this system.
Abstract Recent advances in the precise control of ultracold atomic systems have led to the realisation of Bose–Einstein condensates (BECs) and degenerate Fermi gases. An important challenge is to extend this level of control to more complicated molecular systems. One route for producing ultracold molecules is to form them from the atoms in a BEC. For example, a two-photon stimulated Raman transition in a 87Rb BEC has been used to produce 87Rb2 molecules in a single rotational-vibrational state1, and ultracold molecules have also been formed2 through photoassociation of a sodium BEC. Although the coherence properties of such systems have not hitherto been probed, the prospect of creating a superposition of atomic and molecular condensates has initiated much theoretical work3, 4, 5, 6, 7. Here we make use of a time-varying magnetic field near a Feshbach resonance8, 9, 10, 11, 12 to produce coherent coupling between atoms and molecules in a 85Rb BEC. A mixture of atomic and molecular states is created and probed by sudden changes in the magnetic field, which lead to oscillations in the number of atoms that remain in the condensate. The oscillation frequency, measured over a large range of magnetic fields, is in excellent agreement with the theoretical molecular binding energy, indicating that we have created a quantum superposition of atoms and diatomic molecules—two chemically different species.
We study the photoassociation of Bose-Einstein condensed atoms into molecules using an optical cavity field. The driven cavity field introduces a dynamical degree of freedom into the photoassociation process, whose role in determining the stationary behavior has not previously been considered. The semiclassical stationary solutions for the atom and molecules as well as the intracavity field are found and their stability and scaling properties are determined in terms of experimentally controllable parameters including driving amplitude of the cavity and the nonlinear interactions between atoms and molecules. For weak cavity driving, we find a bifurcation in the atom and molecule number occurs that signals a transition from a stable steady state to nonlinear Rabi oscillations. For a strongly driven cavity, there exists bistability in the atom and molecule number.
We present a theoretical analysis of three-dimensional (3D) matter-wave solitons and their stability properties in coupled atomic and molecular Bose-Einstein condensates (BECs). The soliton solutions to the mean-field equations are obtained in an approximate analytical form by means of a variational approach. We investigate soliton stability within the parameter space described by the atom-molecule conversion coupling, the atom-atom sss-wave scattering, and the bare formation energy of the molecular species. In terms of ordinary optics, this is analogous to the process of sub- or second-harmonic generation in a quadratic nonlinear medium modified by a cubic nonlinearity, together with a phase mismatch term between the fields. While the possibility of formation of multidimensional spatiotemporal solitons in pure quadratic media has been theoretically demonstrated previously, here we extend this prediction to matter-wave interactions in BEC systems where higher-order nonlinear processes due to interparticle collisions are unavoidable and may not be neglected. The stability of the solitons predicted for repulsive atom-atom interactions is investigated by direct numerical simulations of the equations of motion in a full 3D lattice. Our analysis also leads to a possible technique for demonstrating the ground state of the Schr\"odinger-Newton and related equations that describe Bose-Einstein condensates with nonlocal interparticle forces.