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Physical review. E

Stochastic quantum thermodynamics, entropy production, and transport properties of a bosonic system

Mário J. de Oliveira

Published Jan 5, 2018• 9 citations
Publisher

Abstract

The transport properties of a bosonic chain have been calculated by placing the ends of the chain in contact with thermal and particle reservoirs at different temperatures and chemical potentials. The contact with the reservoirs is described by the use of a quantum Fokker-Planck-Kramers equation, which is a canonical quantization of the classical Fokker-Planck-Kramers equation. From the quantum equation we obtain equations for the covariances of the creation and annihilation boson operators and solve them in the stationary state for small interactions. From the covariances we determine the Onsager coefficients and in particular the conductance, which was found to be finite for any chain size leading to an infinite conductivity and the absence of Fourier's law.

DOI
10.1103/physreve.97.012105

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The transport properties of a bosonic chain have been calculated by placing the ends of the chain in contact with thermal and particle reservoirs at different temperatures and chemical potentials. The contact with the reservoirs is described by the use of a quantum Fokker-Planck-Kramers equation, which is a canonical quantization of the classical Fokker-Planck-Kramers equation. From the quantum equation we obtain equations for the covariances of the creation and annihilation boson operators and solve them in the stationary state for small interactions. From the covariances we determine the Onsager coefficients and in particular the conductance, which was found to be finite for any chain size leading to an infinite conductivity and the absence of Fourier's law.
We use a canonical quantization procedure to set up a quantum Fokker-Planck-Kramers equation that accounts for quantum dissipation in a thermal environment. The dissipation term is chosen to ensure that the thermodynamic equilibrium is described by the Gibbs state. An expression for the quantum entropy production that properly describes quantum systems in a nonequilibrium stationary state is also provided. The time-dependent solution is given for a quantum harmonic oscillator in contact with a heat bath. We also obtain the stationary solution for a system of two coupled harmonic oscillators in contact with reservoirs at distinct temperatures, from which we obtain the entropy production and the quantum thermal conductance.
Abstract This paper investigates the dynamics of current and quantum transport factor in a bosonic system consisting of a central system interacting with two reservoirs at different temperatures. We derive a master equation describing the time evolution of the density matrix of the system, accounting for the interactions and energy transfer between the components. We quantify the current, representing the flow of bosons through the system and analyse its dependence on the system's parameters and temperatures of the thermal reservoirs. In the steady state regime, we derived an expression for the quantum transport factor of the energy transfer process. Our analysis show that quantum effects, such as the dependence on temperature can significantly impact this factor. In particular, we observe that the transport factor of the quantum system is greater than the corresponding factor when the temperature goes to infinity, where the factor has an identical form with the Carnot efficiency of an ideal heat engine. We then derived the Fokker-Planck equation to find out the Glauber-Sudarsan P-representation. In the steady state of the equation, the probability distribution comes out to be in Gaussian form. We then calculated the entropic force for this probability distribution which gives the Hooke's law in the steady state, in agreement with the fact that our system is a harmonic oscillator.
The present thesis is concerned with the study of a quantum physical system composed of a small particle system (such as a spin chain) and several quantized massless boson fields (as photon gasses or phonon fields) at positive temperature. The setup serves as a simplified model for matter in interaction with thermal "radiation" from different sources. Hereby, questions concerning the dynamical and thermodynamic properties of particle-boson configurations far from thermal equilibrium are in the center of interest. We study a specific situation where the particle system is brought in contact with the boson systems (occasionally referred to as heat reservoirs) where the reservoirs are prepared close to thermal equilibrium states, each at a different temperature. We analyze the interacting time evolution of such an initial configuration and we show thermal relaxation of the system into a stationary state, i.e., we prove the existence of a time invariant state which is the unique limit state of the considered initial configurations evolving in time. As long as the reservoirs have been prepared at different temperatures, this stationary state features thermodynamic characteristics as stationary energy fluxes and a positive entropy production rate which distinguishes it from being a thermal equilibrium at any temperature. Therefore, we refer to it as non-equilibrium stationary state or simply NESS. The physical setup is phrased mathematically in the language of C*-algebras. The thesis gives an extended review of the application of operator algebraic theories to quantum statistical mechanics and introduces in detail the mathematical objects to describe matter in interaction with radiation. The C*-theory is adapted to the concrete setup. The algebraic description of the system is lifted into a Hilbert space framework. The appropriate Hilbert space representation is given by a bosonic Fock space over a suitable L2-space. The first part of the present work is concluded by the derivation of a spectral theory which connects the dynamical and thermodynamic features with spectral properties of a suitable generator, say K, of the time evolution in this Hilbert space setting. That way, the question about thermal relaxation becomes a spectral problem. The operator K is of Pauli-Fierz type. The spectral analysis of the generator K follows. This task is the core part of the work and it employs various kinds of functional analytic techniques. The operator K results from a perturbation of an operator L0 which describes the non-interacting particle-boson system. All spectral considerations are done in a perturbative regime, i.e., we assume that the strength of the coupling is sufficiently small. The extraction of dynamical features of the system from properties of K requires, in particular, the knowledge about the spectrum of K in the nearest vicinity of eigenvalues of the unperturbed operator L0. Since convergent Neumann series expansions only qualify to study the perturbed spectrum in the neighborhood of the unperturbed one on a scale of order of the coupling strength we need to apply a more refined tool, the Feshbach map. This technique allows the analysis of the spectrum on a smaller scale by transferring the analysis to a spectral subspace. The need of spectral information on arbitrary scales requires an iteration of the Feshbach map. This procedure leads to an operator-theoretic renormalization group. The reader is introduced to the Feshbach technique and the renormalization procedure based on it is discussed in full detail. Further, it is explained how the spectral information is extracted from the renormalization group flow. The present dissertation is an extension of two kinds of a recent research contribution by Jakšić and Pillet to a similar physical setup. Firstly, we consider the more delicate situation of bosonic heat reservoirs instead of fermionic ones, and secondly, the system can be studied uniformly for small reservoir temperatures. The adaption of the Feshbach map-based renormalization procedure by Bach, Chen, Fröhlich, and Sigal to concrete spectral problems in quantum statistical mechanics is a further novelty of this work.
The multivariate fluctuation relation is established for the full counting statistics of the energy and particle fluxes across an open quantum system in contact with several reservoirs on the basis of microreversibility The quantum version of the nonequilibrium work fluctuation relation is recovered in the presence of a single reservoir. In the long-time limit, the time-reversal symmetry relation is expressed in terms of the cumulative generating function for the full counting statistics. In systems with independent particles, the symmetry relation can be obtained in the scattering approach for the transport of bosons and fermions. The temporal disorder and its time asymmetry can be characterized by the quantum version of the entropy and coentropy per unit time. Their difference gives the thermodynamic entropy production rate. Furthermore, the stochastic approach is also considered for electron transport in quantum dots, quantum point contacts, and single-electron transistors.
The theory of Brownian motion of a quantum oscillator is developed. The Brownian motion is described by a model Hamiltonian which is taken to be the one describing the interaction between this oscillator and a reservoir. Use is made of the master equation recently derived by the author, to obtain the equation of motion for the various reduced phase-space distribution functions that are obtained by mapping the density operator onto ccc-number functions. The equations of motion for the reduced phase-space distribution functions are found to be of the Fokker-Planck type. On transforming the Fokker-Planck equation to real variables, it is found to have the same form as the Fokker-Planck equation obtained by Wang and Uhlenbeck to describe the Brownian motion of a classical oscillator. The Fokker-Planck equation is solved for the conditional probability (Green's function) which is found to be in the form of a two-dimensional Gaussian distribution. This solution is then used to obtain various time-dependent quantum statistical properties of the oscillator. Next, the entropy for a quantum oscillator undergoing Brownian motion is calculated and we show that this system approaches equilibrium as $t\ensuremath{\rightarrow}\ensuremath{\infty}$. Finally we show that in the weak-coupling limit the Fokker-Planck equation reduces to the one obtained by making the usual rotating-wave approximation.
A formalism for quantum many-body systems is proposed through a semiclassical treatment in phase space, allowing us to establish stochastic thermodynamics incorporating quantum statistics. Specifically, we utilize a stochastic Fokker-Planck equation as the dynamics at the mesoscopic level. Here, the noise term characterizing the fluctuation of the flux density accounts for the finite-NNN effects arising from random collisions between the system and the reservoir. Accordingly, the stationary solution is a quasiequilibrium state in a canonical system. We define stochastic thermodynamic quantities based on the trajectories of the phase-space distribution. The conservation law of energy, the HHH theorem, and fluctuation theorems are therefore obtained. Our work sets an alternative formalism of quantum stochastic thermodynamics that is independent of the two-point measurement scheme. The numerous projective measurements of quantum systems are replaced by the sampling of the phase-space distribution, offering hope for experimental verifications in the future.