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The effect of van der Waals forces in two-atomic elastic collision

Hasi Ray

Published Aug 8, 2013• 0 citations
OpenAlex

Abstract

The modified static exchange model (MSEM) recently introduced by Ray [1] to study two-atomic collision processes at low and cold-energies, is used for detailed analysis of the long-range effects due to induced dipole-dipole van der Waals interaction between Ps and H atoms. The MSEM includes the non-adiabatic short-range effect due to electron-exchange and the long-range effect due to induced dynamic dipole polarisabilities of the atoms. The effective interatomic potential is highly sensitive to the minimum distance between the atoms ( ). The s-, p- and d- wave elastic phase shifts, corresponding partial cross sections, the scattering length and effective ranges are calculated and studied with the variation of the chosen least interatomic distance between them. It is found that the scattering length is highly sensitive to the effective interatomic potential that depends on the least interatomic distance. In addition the studies are made in search of Feshbach resonances. The observed interesting feature with the variation of in the triplet channel invites more accurate investigations if new physics.

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The modified static exchange model (MSEM) recently introduced by Ray [1] to study two-atomic collision processes at low and cold-energies, is used for detailed analysis of the long-range effects due to induced dipole-dipole van der Waals interaction between Ps and H atoms. The MSEM includes the non-adiabatic short-range effect due to electron-exchange and the long-range effect due to induced dynamic dipole polarisabilities of the atoms. The effective interatomic potential is highly sensitive to the minimum distance between the atoms ( ). The s-, p- and d- wave elastic phase shifts, corresponding partial cross sections, the scattering length and effective ranges are calculated and studied with the variation of the chosen least interatomic distance between them. It is found that the scattering length is highly sensitive to the effective interatomic potential that depends on the least interatomic distance. In addition the studies are made in search of Feshbach resonances. The observed interesting feature with the variation of in the triplet channel invites more accurate investigations if new physics.

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A. Calle Cordón, E. Ruiz Arriola

At long distances, interactions between neutral ground-state atoms can be described by the van der Waals potential. In the ultracold regime, atom-atom scattering is dominated by $s$-waves phase shifts given by an effective range expansion in terms of the scattering length ${\ensuremath{\alpha}}_{0}$ and the effective range ${r}_{0}$. We show that while the scattering length cannot be predicted for these potentials, the effective range is given by the universal low-energy theorem ${r}_{0}=A+B/{\ensuremath{\alpha}}_{0}+C/{\ensuremath{\alpha}}_{0}^{2}$, where $A$, $B$, and $C$ depend on the dispersion coefficients ${C}_{n}$ and the reduced diatom mass. We confront this formula to about 100 determinations of ${r}_{0}$ and ${\ensuremath{\alpha}}_{0}$ and show why the result is dominated by the leading dispersion coefficient ${C}_{6}$. Universality and scaling extend much beyond naive dimensional analysis estimates.

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The modified static exchange model (MSEM) recently introduced by Ray [1] to study two-atomic collision processes at low and cold-energies, is used for detailed analysis of the long-range effects due to induced dipole-dipole van der Waals interaction between Ps and H atoms. The MSEM includes the non-adiabatic short-range effect due to electron-exchange and the long-range effect due to induced dynamic dipole polarisabilities of the atoms. The effective interatomic potential is highly sensitive to the minimum distance between the atoms ( ). The s-, p- and d- wave elastic phase shifts, corresponding partial cross sections, the scattering length and effective ranges are calculated and studied with the variation of the chosen least interatomic distance between them. It is found that the scattering length is highly sensitive to the effective interatomic potential that depends on the least interatomic distance. In addition the studies are made in search of Feshbach resonances. The observed interesting feature with the variation of in the triplet channel invites more accurate investigations if new physics.
The modified static exchange model (MSEM) recently introduced by Ray [1] to study two-atomic collision processes at low and cold-energies, is used for detailed analysis of the long-range effects due to induced dipole-dipole van der Waals interaction between Ps and H atoms. The MSEM includes the non-adiabatic short-range effect due to electron-exchange and the long-range effect due to induced dynamic dipole polarisabilities of the atoms. The effective interatomic potential is highly sensitive to the minimum distance between the atoms ( ). The s-, p- and d- wave elastic phase shifts, corresponding partial cross sections, the scattering length and effective ranges are calculated and studied with the variation of the chosen least interatomic distance between them. It is found that the scattering length is highly sensitive to the effective interatomic potential that depends on the least interatomic distance. In addition the studies are made in search of Feshbach resonances. The observed interesting feature with the variation of in the triplet channel invites more accurate investigations if new physics.
A modified static exchange model is introduced, it could be useful to control the elastic s-wave scattering length in studying cold-atomic interaction. The theory includes the long-range van der Waals interaction in addition to short-range exchange force. The model is applied on Ps-H system to study the Feshbach resonances e.g. the s-wave elastic phase shifts and the corresponding cross sections at ultracold energies. These are compared with the data obtained using the static exchange model. A very interesting features are observed when we vary the interatomic separation i.e. the strength of dipole-dipole interaction.
Elastic collision between two H-like atoms using the ab initio static-exchange model (SEM) and a modified static-exchange model (MSEM) at cold energies are investigated in the center of mass frame considering the system as a four-body Coulomb problem where all the Coulomb interaction terms in the direct and exchange channels are treated exactly.The importance of an exact calculation to find basic physics is highlighted.In addition, the dependence of scattering length on the van der Waals interaction between the atoms and the dependence of scattering length on reduced-mass of the system are derived which is completely new information in the field of science.
The elastic collision between two ortho-positronium (e.g. S=1) atoms is studied using an ab-initio static-exchange model (SEM) in the center of mass (CM) frame considering the system as a four-body Coulomb problem where all the Coulomb interaction terms in the direct and exchange channels are treated exactly. A coupled-channel methodology in momentum space is used to solve Lippman-Schwinger equation following the integral approach. A new SEM code is developed in which the Born-Oppenheimer (BO) scattering amplitude acts as input to derive the SEM amplitude adapting the partial wave analysis. The s-, p- and d- wave elastic phase shifts and the corresponding partial cross sections for the spin alignment S=0, i.e. singlet (+) and S=2, i.e. triplet (-) states are studied. An augmented-Born approximation is used to include the contribution of higher partial waves more accurately to determine the total/integrated elastic cross section ( ), the quenching cross section ( ) and ortho to para conversion ratio ( ). The effective range theory is used to determine the scattering lengths and effective ranges in the s-wave elastic scattering. The theory includes the non-adiabatic short-range effects due to exchange.
At long distances, interactions between neutral ground-state atoms can be described by the van der Waals potential. In the ultracold regime, atom-atom scattering is dominated by sss-waves phase shifts given by an effective range expansion in terms of the scattering length ${\ensuremath{\alpha}}_{0}$ and the effective range r0{r}_{0}r0​. We show that while the scattering length cannot be predicted for these potentials, the effective range is given by the universal low-energy theorem ${r}_{0}=A+B/{\ensuremath{\alpha}}_{0}+C/{\ensuremath{\alpha}}_{0}^{2}$, where AAA, BBB, and CCC depend on the dispersion coefficients Cn{C}_{n}Cn​ and the reduced diatom mass. We confront this formula to about 100 determinations of r0{r}_{0}r0​ and ${\ensuremath{\alpha}}_{0}$ and show why the result is dominated by the leading dispersion coefficient C6{C}_{6}C6​. Universality and scaling extend much beyond naive dimensional analysis estimates.