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IEEE Ukraine Conference on Electrical and Computer Engineering (UKRCON)

Basic ideas of quantum mechanics of open systems in application to electron and optic processes

Sergiy F. Lyagushyn, Alexander I. Sokolovsky, Volodymyr V. Yarlik, S. A. Sokolovsky

Published May 1, 2017• 0 citations
Publisher

Abstract

Kinetics of a quantum system immersed in an equilibrium medium and completely described by its statistical operator is investigated. The case of a separable interaction is considered in details. A concept of the effective Hamilton operator of the system is discussed. The kinetic equation for a point particle in a spatially uniform external field placed in a medium of point particles is obtained in terms of the Wigner distribution function of a particle. The kinetic equation is applicable for strong spatially inhomogeneous (localized) states of the particle and strong external field. The elaborated theory is used also for a system of two-level emitters and photons interacting with an equilibrium phonon medium. The kinetic equation for the statistical operator of the system of the emitters and photons that describes the effect of emitter motion on the super radiance phenomenon is obtained.

DOI
10.1109/ukrcon.2017.8100340

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Kinetics of a quantum system immersed in an equilibrium medium and completely described by its statistical operator is investigated. The case of a separable interaction is considered in details. A concept of the effective Hamilton operator of the system is discussed. The kinetic equation for a point particle in a spatially uniform external field placed in a medium of point particles is obtained in terms of the Wigner distribution function of a particle. The kinetic equation is applicable for strong spatially inhomogeneous (localized) states of the particle and strong external field. The elaborated theory is used also for a system of two-level emitters and photons interacting with an equilibrium phonon medium. The kinetic equation for the statistical operator of the system of the emitters and photons that describes the effect of emitter motion on the super radiance phenomenon is obtained.
While the dynamic state of a single particle can be specified quantum mechanically in terms of its state function, any rigorous description of the state of a many-particle system would require the complete knowledge of the dynamic state functions of all the particles. That is not always possible. On the other hand, for a large number of particles in, or near, thermal equilibrium in a uniform sample, the principles of statistical mechanics may be invoked to describe the averaged expectation values of the physically observable properties of such a many-particle system. The basic concepts of the density-matrix formalism and the quantum mechanic analog of the classical Boltzmann equation commonly used for optical and magnetic resonance problems of many-particle quantum systems are introduced in this chapter. Applications of this approach to such specific problems as the resonant interaction of electromagnetic radiation with optical media of two-level atoms, nonlinear optics, and the laser rate equations and transient dynamics are discussed in this chapter. Definitions of the density operator and the density matrix Up to this point, in studying the dynamics of quantum mechanic systems, we have assumed that the state of the system can be specified in terms of a precisely known state function |Ψ〉. On the other hand, for a macroscopic medium containing many particles, it is not always possible to know the exact dynamic states of all the particles in the medium, even for physically identical particles.
Kinetic equations have played a significant role in optics since the introduction of the radiative transport equation (RTE) by Schuster in the early 20th century. Now they are applied in many scientific fields such as atmospheric physics and biomedical imaging to understand how light interacts with a complex medium. In this thesis we investigate how these equations arise in: 1. models of classical optics in an inhomogeneous disordered scattering medium 2. in fully quantum real space models with a random distribution of atoms In certain spatial and temporal regimes it has been empirically observed that light interacting with a highly disordered scattering medium may be described by a radiative transport equation with a constant scattering coefficient. One way to derive such equations from microscopic principles is to model the medium as a random field which is statistically homogeneous. We show that in a quasi-homogeneous media, where statistical correlations vary rapidly on small length scales and slowly on large length scales, light obeys a radiative transport equation with variable scattering coefficient. In the second part of this thesis we introduce a new model in quantum optics which allows us to treat a quantized electromagnetic field coupled to a medium of two level atoms, both in real space. The rest of the chapter focuses on the interaction of atoms with a field consisting of at most one photon. First we recover a classical result due to Wigner and Weisskopf on the rate of single atom spontaneous emission. Next we show that in a statistically homogeneous distribution of two level atoms the field and atomic amplitude satisfy linear kinetic equations. Finally we show that at sufficiently long times and large distances these amplitudes are asymptotically governed by diffusion equations which may be solved analytically. In the final chapter we use the previous model to analyze a system in which there can be at most two photons. This allows us to study the time evolution of states that initially contain two entangled photons, a phenomenon which has no classical analogue. We show that the various probability amplitudes satisfy linear two particle kinetic equations which again may be asymptotically evaluated at large distances and long times.
We consider an open quantum many-particle system in which there are dissipative processes. The evolution of this system is described by a kinetic equation for the density matrix. From the equation describing a random Markov process in this system, we obtain an equation for the single-particle statistical operator. This equation describes the evolution of a system of identical particles in a mean-field approximation. The equation for interacting particles in thermodynamic equilibrium was obtained. The distribution function of a system of interacting electrons in metals has multivalence in a certain region of wave vectors. Among many solutions one is isotropic. Other solutions have the anisotropy of the electron distribution over the wave vectors. The anisotropy arises as a result of repulsion and attraction between electrons.
Construction of a kinetic equation for a dynamical system interacting with a boson field in the case of spatial inhomogeneity is based on a method expounded in [1–3]. In the present article, it is shown that approaches considered in [1, 2] can be generalized for the case of spatial inhomogeneity. An arbitrary operator function that depends on the momentum and spatial variable is applied for derivation of a kinetic equation. We consider a method of studying an electron-phonon system by means of exclusion of boson operators from corresponding operator equations. In particular, interaction of an electron with a boson field is described by a kinetic equation for a polaron in the case of spatial inhomogeneity. In the relevant limit, a Boltzmann equation for the polaron is obtained.
The method of the nonequilibrium statistical operator developed by D. N. Zubarev is employed to analyze and derive generalized transport and kinetic equations. The degrees of freedom in solids can often be represented as a few interacting subsystems (electrons, spins, phonons, nuclear spins, etc.). Perturbation of one subsystem may produce a nonequilibrium state which is then relaxed to an equilibrium state due to the interaction between particles or with a thermal bath. The generalized kinetic equations were derived for a system weakly coupled to a thermal bath to elucidate the nature of transport and relaxation processes. It was shown that the "collision term" had the same functional form as for the generalized kinetic equations for the system with small interactions among particles. The applicability of the general formalism to physically relevant situations is investigated. It is shown that some known generalized kinetic equations (e.g. kinetic equation for magnons, Peierls equation for phonons) naturally emerges within the NSO formalism. The relaxation of a small dynamic subsystem in contact with a thermal bath is considered on the basis of the derived equations. The Schrödinger-type equation for the average amplitude describing the energy shift and damping of a particle in a thermal bath and the coupled kinetic equation describing the dynamic and statistical aspects of the motion are derived and analyzed. The equations derived can help in the understanding of the origin of irreversible behavior in quantum phenomena.
The method of the nonequilibrium statistical operator developed by D. N. Zubarev is employed to analyze and derive generalized transport and kinetic equations. The degrees of freedom in solids can often be represented as a few interacting subsystems (electrons, spins, phonons, nuclear spins, etc.). Perturbation of one subsystem may produce a nonequilibrium state which is then relaxed to an equilibrium state due to the interaction between particles or with a thermal bath. The generalized kinetic equations were derived for a system weakly coupled to a thermal bath to elucidate the nature of transport and relaxation processes. It was shown that the "collision term" had the same functional form as for the generalized kinetic equations for the system with small interactions among particles. The applicability of the general formalism to physically relevant situations is investigated. It is shown that some known generalized kinetic equations (e.g. kinetic equation for magnons, Peierls equation for phonons) naturally emerges within the NSO formalism. The relaxation of a small dynamic subsystem in contact with a thermal bath is considered on the basis of the derived equations. The Schrödinger-type equation for the average amplitude describing the energy shift and damping of a particle in a thermal bath and the coupled kinetic equation describing the dynamic and statistical aspects of the motion are derived and analyzed. The equations derived can help in the understanding of the origin of irreversible behavior in quantum phenomena.