A central goal in the study of modern condensed matter physics is the characterization of the dynamical properties of quantum systems. Many decades of effort towards this goal, studying a diverse range of (near-equilibrium) quantum matter, from Fermi liquids, to quantum two-level systems, to interacting spin models, and more, has revealed a remarkable pervasiveness of the simple dynamical description of these complex systems in terms of quasi-particles that carry spin, charge, and heat, and that are generally able to equilibrate systems. \n\nThis thesis is an examination of some exceptions to this rule. Specifically, we study a number of instances of quantum matter where equilibration phenomena happens at rather long time scales, or does not occur at all. Particular emphasis is laid on the role of dimensionality, disorder, and dissipation in engendering such novel dynamical behavior.\n\nFirst, we consider non-equilibrium dynamics in one-dimensional quasi-condensates. Low dimensionality inhibits scattering in these systems, and low-energy excitations are long-lived phase fluctuations that exhibit an enriched conformal symmetry. Utilizing this symmetry, we generalize sudden quenches typically used to study non-equilibrium dynamics to quenches along general relativistic and conformal trajectories. Gases never truly equilibrate after such a quench; instead, they evolve into a `prethermal' state with thermal-looking correlations and a chiral asymmetry. \n\nWe then study the problem of the dynamical transition driven by disorder, from an ergodic to a non-ergodic phase, in one-dimensional quantum spin chains. In particular, in XXZ chains with on-site disorder, we find a unique intermediate phase straddling the boundary of the dynamical phase transition, wherein rare-region effects lead to long-time tails in equilibration and vanishing DC conduction before the onset of non-ergodicity. We propose generalizations of such `Griffiths' behavior to arbitrary dimensions. We also study the dynamics of random-bond Heisenberg chains by developing a strong-disorder renormalization group protocol for these systems. We discuss how magnetic noise from such disordered systems contains signatures of their anomalous dynamical properties. \n\nNext, we re-examine the phenomenological theory of two-level systems in amorphous materials in the light of new experimental evidence that these states have large electric/magnetic dipole moments. We propose and justify an interpretation of the model as one of tunneling electrons slowed down by a large phonon drag and discuss the dynamical consequences of such polaronic effects. \n\nFinally, we discuss how magnetic noise measurements can be used to non-invasively access the anomalous properties of systems such as those discussed above. In particular, we examine how scattering properties of isolated magnetic impurities and non-local transport in a variety of two-dimensional materials can be probed experimentally using NV centers as noise magnetometers.
A central goal in the study of modern condensed matter physics is the characterization of the dynamical properties of quantum systems. Many decades of effort towards this goal, studying a diverse range of (near-equilibrium) quantum matter, from Fermi liquids, to quantum two-level systems, to interacting spin models, and more, has revealed a remarkable pervasiveness of the simple dynamical description of these complex systems in terms of quasi-particles that carry spin, charge, and heat, and that are generally able to equilibrate systems. \n\nThis thesis is an examination of some exceptions to this rule. Specifically, we study a number of instances of quantum matter where equilibration phenomena happens at rather long time scales, or does not occur at all. Particular emphasis is laid on the role of dimensionality, disorder, and dissipation in engendering such novel dynamical behavior.\n\nFirst, we consider non-equilibrium dynamics in one-dimensional quasi-condensates. Low dimensionality inhibits scattering in these systems, and low-energy excitations are long-lived phase fluctuations that exhibit an enriched conformal symmetry. Utilizing this symmetry, we generalize sudden quenches typically used to study non-equilibrium dynamics to quenches along general relativistic and conformal trajectories. Gases never truly equilibrate after such a quench; instead, they evolve into a prethermal' state with thermal-looking correlations and a chiral asymmetry. \n\nWe then study the problem of the dynamical transition driven by disorder, from an ergodic to a non-ergodic phase, in one-dimensional quantum spin chains. In particular, in XXZ chains with on-site disorder, we find a unique intermediate phase straddling the boundary of the dynamical phase transition, wherein rare-region effects lead to long-time tails in equilibration and vanishing DC conduction before the onset of non-ergodicity. We propose generalizations of such Griffiths' behavior to arbitrary dimensions. We also study the dynamics of random-bond Heisenberg chains by developing a strong-disorder renormalization group protocol for these systems. We discuss how magnetic noise from such disordered systems contains signatures of their anomalous dynamical properties. \n\nNext, we re-examine the phenomenological theory of two-level systems in amorphous materials in the light of new experimental evidence that these states have large electric/magnetic dipole moments. We propose and justify an interpretation of the model as one of tunneling electrons slowed down by a large phonon drag and discuss the dynamical consequences of such polaronic effects. \n\nFinally, we discuss how magnetic noise measurements can be used to non-invasively access the anomalous properties of systems such as those discussed above. In particular, we examine how scattering properties of isolated magnetic impurities and non-local transport in a variety of two-dimensional materials can be probed experimentally using NV centers as noise magnetometers.
The study of non-equilibrium behaviors of quantum matter is one of the research directions at the frontiers of condensed matter physics and, in general, of theoretical and experimental physics. Understanding the mechanisms which prevent many quantum particles from reaching thermal equilibrium can ultimately shed light on the foundations of statistical physics and provide insight into the anomalous long-time collective behaviors observed in experiments. In this thesis, we present new theoretical developments in this direction. In the first part of the thesis we discuss the non-equilibrium dynamics of the two-dimensional quantum Ising model, the prototypical model of magnetism. In particular, we investigate the dynamics of interfaces separating different spin domains. In some regimes, we can provide an exact description of their unitary time evolution, but we also discuss the robustness of our predictions away from the exactly-solvable limit. Moreover, we address the same problem in the presence of disorder and provide a hydrodynamic interpretation of our findings. In the second part of the thesis, we investigate the localization properties of disordered quantum systems. In particular, we develop a renormalization-group picture of the Anderson localization transition in generic geometries. This provides a new framework to understand the phase diagram of such systems and their critical behavior beyond the usual finite-size scaling analysis. We also provide further insights on this topic both by studying resonances and their connection with observables and by employing unsupervised non-parametric learning techniques to probe disordered systems in an experimentally accessible form. The results presented in this thesis constitute a step forward in understanding the non-equilibrium phases and regimes of quantum matter and they pave the way to interesting future developments.
The study of collective behaviour in many-body systems often explores fundamentally new ideas absent from the mere constituents of such a system. A paradigmatic model for these studies is the spin-1/2 XXZ chain and its fermionic equivalent. This thesis can be broadly divided into the study of two fundamental aspects of this model. Firstly, we discuss localisation phenomena in one dimensional lattices as often experimentally realised in cold atom systems. Secondly, we investigate how disorder and symmetry influence heat transport in spin chains. More specifically, in the first part we consider a system of non-interacting fermions in one dimension subject to a single-particle potential consisting of a strong optical lattice, a harmonic trap, and uncorrelated on-site disorder. We investigate a global inhomogeneous quantum quench and present numerical and analytical results for static and dynamical properties. We show that the approach to the non-thermal equilibrium state is extremely slow and that it implies a sensitivity to disorder parametrically stronger than that expected from Anderson localisation. We also consider the above system in a strong non-uniform electric field. In the non-interacting case, due to Wannier-Stark localisation, the single-particle wave functions are exponentially localised without quenched disorder. We show that this system remains localised in the presence of nearest-neighbour interactions and exhibits physics analogous to models of conventional many-body localisation. The second part explores the hydrodynamics of the disordered XYZ spin chain. Using time-evolving block decimation on open chains of up to 400 spins attached to thermal baths, we probe the energy transport of this system. Our principal findings are as follows. For weak disorder there is a stable diffusive region that persists up to a critical disorder strength that depends on the XY anisotropy. Then, for disorder strengths above this critical value energy transport becomes increasingly subdiffusive.
Understanding the effects of disorder in quantum many-body systems is one of the central challenges of contemporary statistical physics. Its interplay with interactions and quantum fluctuations profoundly modifies the nature of quantum states and their dynamics, giving rise to phenomena such as localization, ergodicity breaking, and the emergence of complex collective behavior. This thesis presents new results on two classes of disordered quantum systems. The first part is devoted to the study of the many-body localization transition, a paradigmatic example of disorder-induced ergodicity breaking. The critical properties of the transition are investigated using a numerical renormalization-group approach, establishing a connection between its scaling behavior and that of the Anderson localization transition on tree-like graphs. The second part focuses on the zero-temperature quantum spin-glass phase of the two-dimensional bond-disordered Heisenberg model. Combining large-scale numerical simulations with a semiclassical expansion, evidence is provided for the existence of the spin-glass phase. The effective model governing the semiclassical fluctuations is further analyzed to characterize the low-energy excitation spectrum and its localization properties. Finally, the weak-disorder regime is investigated and its implications for the ferromagnetic phase are discussed. Overall, the results presented in this thesis contribute to the understanding of the effects of disorder in interacting quantum many-body systems, encompassing both localization phenomena and the collective behavior of disordered quantum magnets.
Quantum phase transitions occur strictly at zero temperature and are accessed by varying a physical parameter such as a magnetic field or chemical potential. While these transitions themselves are experimentally inaccessible, the existence of a zero temperature quantum critical point has remarkable effects on the dynamical properties of interacting quantum many-body systems at finite temperatures. In this thesis, we study dynamics in four strongly interacting many-body systems near quantum critical points in the context of NMR relaxation, quantum quenches, many-body quantum chaos, and charge diffusion. In chapter 1, we begin by revisiting the issue of NMR relaxation in the quantum disordered phase of Ising spin chains. We find that the imaginary part of the spin susceptibility at low frequences is dominated by rare quantum processes which leads to an NMR relaxation rate that scales as 1/T1∼exp(−T2Δ) near the quantum critical point rather than the previously conjectured 1/T1∼exp(−TΔ). These results resolve certain discrepancies between the energy scales measured with different experimental probes in the quantum disordered paramagnetic phase of the Ising chain system CoNb2O6. In chapter 2, we study the non-equilibrium dynamics of Sachdev-Ye-Kitaev (SYK) models with q body interactions after a quantum quench, considering a quench protocol which drives the system from an initial state with long-lived quasiparticle excitations to a final state lacking any long-lived quasiparticle excitations. For q=4, we find that the timescale for the system to locally thermalize τeq∼kBTℏ and for q→∞ we find that the system thermalizes instantaneously. In chapter 3, we study the real time dynamics of quantum electrodynamics in 2+1 dimensions with Nf flavors of fermions. We focus on thermalization and the onset of many-body quantum chaos and compute the quantum Lyapunov exponent in a Nf1 expansion. We briefly comment on chaos, locality, and gauge invariance. Finally, in Chapter 4 we consider whether the butterfly velocity - a speed at which quantum information propagates - may provide a fundamental bound on diffusion constants in dirty incoherent metals by computing the charge diffusion constant and the butterfly velocity in charge-neutral holographic matter with long wavelength ``hydrodynamic" disorder. In this limit, we find that the butterfly velocity does not set a sharp lower bound for the charge diffusion constant.
The work presented in this thesis is divided into two main parts: strong zero modes in quantum spin chains with open boundaries and large deviations in classical spin systems. The results concerning the strong zero modes are presented in chapters 2 and 3, while chapter 4 contains the results about large deviations in systems of many, but independent, classical degrees of freedom. These two distinct classes of problems in spin chains are both about aspects of slow relaxation to equilibrium in many-body systems. Nowadays slow dynamics and non-ergodicity in many-body quantum systems are receiving much attention due to their notable technological potential for storing and processing, for very long times, the quantum information encoded in boundary degrees of freedom. In the first part of the work presented in this thesis we mainly focus on quantum spin chains with open boundaries, which can display coherence times for edge spins, that diverge with the system size, as a consequence of the emergence, in the thermodynamic limit, of conserved local quantities, called strong zero modes. First, we discuss the fate of these coherence times when dynamics becomes dissipative. Understanding the behavior of these long correlation times in open quantum systems, undergoing Markovian (memoryless) dynamics, would allow for the possibility of exploiting the protected information encoded in the boundary spins for applications in quantum devices in realistic non-equilibrium settings. Second, we study one possible simple generalization of the transverse field Ising model to a class of ladder spin systems with plaquette interactions in the presence of a transverse field. Also for these systems one can explicitly construct the strong zero mode operators and understand the behavior of the consequential long coherence times for the edge degrees of freedom under isolated (unitary) dynamics. This is possible because the models we consider, while appearing complex superficially, can be brought to simple forms by exploiting an extensive number of conserved quantities they possess. The results presented in chapters 2 and 3 are closely related, even if they focus on different models and investigate different aspects of their dynamics. Nevertheless, the underlying concept they are based on is the same one, that is, an eigenstate phase transition for the strong zero modes that has interesting consequences for the full energy spectrum. In the second part of the thesis we focus on a different type of phase transitions. Here we address the issue of dynamical large deviation phase transitions from a disordered phase to an ordered one, in classical systems which consist in a collection of independent Ising spins evolving stochastically. Surprisingly, by reweighing trajectories accordingly to a certain type of time-integrated observable, even a system of independently evolving spins can display some critical behavior, at the fluctuation level, in trajectory space in the large size and long time limit. By making use of the tilted generator techniques we study the statistics of two particular time-integrated observables. Their associated tilted generators have an exact Kramers-Wannier duality and they look like, up to a sign and an additive constant, some specific well known quantum Hamiltonians. In this sense, the dynamical large deviation phase transitions we observe in these classical stochastic systems translate in ground state quantum phase transitions taking place at the self dual point of the tilted generators we study.
Isolated, many-body quantum systems, evolving under their intrinsic dynamics, exhibit a multitude of exotic phenomena and raise foundational questions about statistical mechanics. A flurry of theoretical work has been devoted to understanding how these systems reach thermal equilibrium in the absence of coupling to an external bath and, when thermalization does not occur, investigating the emergent non-equilibrium phases of matter. With the advent of synthetic quantum systems, such as ultra-cold atoms in optical lattices or trapped ions, these questions are no longer academic and can be directly studied in the laboratory. This dissertation explores the non-equilibrium phenomena that stem from the interplay between interactions, disorder, symmetry, topology, and external driving. First, we study how strong disorder, leading to many-body localization, can arrest the heating of a Floquet system and stabilize symmetry-protected topological order that does not have a static analogue. We analyze its dynamical and entanglement properties, highlight its duality to a discrete time crystal, and propose an experimental implementation in a cold-atom setting.Quenched disorder and the many-body localized state are crucial ingredients in protecting macroscopic quantum coherence. We explore the stability of many-body localization in two and higher dimensions and analyze its robustness to rare regions of weak disorder.We then study a second example of non-thermal behavior, namely integrability. We show that a class of random spin models, realizable in systems of atoms coupled to an optical cavity, gives rise to a rich dynamical phase diagram, which includes regions of integrability, classical chaos, and of a novel integrable structure whose conservation laws are reminiscent of the integrals of motion found in a many-body localized phase.The third group of disordered, non-ergodic systems we consider, spin glasses, have fascinating connections to complexity theory and the hardness of constraint satisfaction. We define a statistical ensemble that interpolates between the classical and quantum limits of such a problem and show that there exists a sharp boundary separating satisfiable and unsatisfiable phases.