In this paper, we examine quantum systems with relativistic dynamics. We show that for a successful description of these systems, the application of Galilei invariant nonrelativistic Hamiltonian is necessary. To modify this Hamiltonian to relativistic dynamics, we require precise relativistic kinetic energy operators instead of nonrelativistic ones for every internal (Jacobi) coordinate. Finally, we introduce and investigate the Schrödinger equation with relativistic dynamics for two-particle systems with harmonic oscillator and Coulomb potentials.
In this paper, we examine quantum systems with relativistic dynamics. We show that for a successful description of these systems, the application of Galilei invariant nonrelativistic Hamiltonian is necessary. To modify this Hamiltonian to relativistic dynamics, we require precise relativistic kinetic energy operators instead of nonrelativistic ones for every internal (Jacobi) coordinate. Finally, we introduce and investigate the Schrödinger equation with relativistic dynamics for two-particle systems with harmonic oscillator and Coulomb potentials.
The formal mathematical structure of the truly Hamiltonian formulations of nonrelativistic and relativistic quantum mechanics is critically examined for both spin 0 and spin 12 particles with nonzero mass. It is shown that the relativistic quantum mechanics can, in principle, at least be fitted into a truly covariant Hamiltonian procedure where the Hamiltonian is a Lorentz-invariant world scalar (and is the negative of 12 the rest energy of the particle, regardless of its spin). In particular, a truly covariant Hamiltonian theory of the electron is presented. It will be seen that the Lorentz-invariant Dirac theory of the electron does not fall within the framework of a truly covariant Hamiltonian procedure. Further, the dynamical variables associated with the translational degree of freedom of the particle (such as the position, the canonical momentum, and the velocity four-vectors of the relativistic quantum mechanics) correspond precisely to the same variables of the truly covariant formulation of relativistic classical mechanics. The mathematical structure of relativistic quantum mechanics is seen to be rather similar to that of nonrelativistic quantum mechanics for both spin 0 and spin 12 particles with nonzero mass.
The purpose of this chapter is to introduce the Dirac equation, which will provide us with a basis for developing the relativistic quantum mechanics of electronic systems. Thus far we have reviewed some basic features of the classical relativistic theory, which is the foundation of relativistic quantum theory. As in the nonrelativistic case, quantum mechanical equations may be obtained from the classical relativistic particle equations by use of the correspondence principle, where we replace classical variables by operators. Of particular interest are the substitutions In terms of the momentum four-vector introduced earlier, this yields In going from a classical relativistic description to relativistic quantum mechanics, we require that the equations obtained are invariant under Lorentz transformations. Other basic requirements, such as gauge invariance, must also apply to the equations of relativistic quantum mechanics. We start this chapter by reexamining the quantization of the nonrelativistic Hamiltonian and draw out some features that will be useful in the quantization of the relativistic Hamiltonian. We then turn to the Dirac equation and sketch its derivation. We discuss some properties of the equation and its solutions, and show how going to the nonrelativistic limit reduces it to a Schrödinger-type equation containing spin.
Given the classical dynamics of a non-relativistic particle in terms of a Hamiltonian or an action, it is relatively straightforward to obtain the non-relativistic quantum mechanics (NRQM) of the system. These standard procedures, based on either the Hamiltonian or the path integral, however, do not work in the case of a relativistic particle. As a result we do not have a single-particle description of relativistic quantum mechanics (RQM). Instead, the correct approach requires a transmutation of dynamical variables from the position and momentum of a single particle to a field and its canonical momentum. Particles, along with antiparticles , reappear in a very nontrivial manner as the excitations of the field. The fact that one needs to adopt completely different languages to describe a relativistic and non-relativistic free particle implies that obtaining the NRQM limit of QFT is conceptually nontrivial. I examine this limit in several approaches (like, for e.g., Hamiltonian dynamics, Lagrangian and Hamiltonian path integrals, field theoretic description etc.) and identify the precise issues which arise when one attempts to obtain the NRQM from QFT in each of these approaches. The dichotomy of NRQM and QFT does not originate just from the square root in the Hamiltonian or from the demand of Lorentz invariance, as is sometimes claimed. The real difficulty has its origin in the necessary existence of antiparticles to ensure a particular notion of relativistic causality. Because of these conceptual issues, it turns out that one cannot , in fact, obtain some of the popular descriptions of NRQM by any sensible limiting procedure applied to QFT. To obtain NRQM from QFT in a seamless manner, it is necessary to work with NRQM expressed in a language closer to that of QFT. This fact has several implications, especially for the operational notion of space coordinates in quantum theory. A close examination of these issues, which arise when quantum theory is combined with special relativity, could offer insights in the context of attempts to combine quantum theory with general relativity.
A new relativistic quantum wave equation has been derived by applying the quantum prescription to the momentum and the kinetic energy rather than to the momentum and the total energy, since after all it is the kinetic energy that generates the momentum. The resulting equation reduces to the Schrodinger equation in the nonrelativistic limit and to the Klein-Gordon equation for “massless particles” in the relativistic limit, i.e., if the velocity of the particle approaches that of light, c. For massive particles in general, the new equation deviates from the Klein-Gordon equation. The same equation is shown to decouple according to the Dirac formalism, yielding a modified form of Dirac equation. When applied to a rest particle, the modified Dirac equation is shown to avoid a negative energy solution and instead include a constant solution. The other, the time-dependent particle solution of the modified Dirac equation, has the characteristic frequency Mc2/(ћ/2) , i.e., twice those of the Dirac solutions, Mc2/ћ.
This paper is devoted to the study of the Galilei group and its representations. The Galilei group presents a certain number of essential differences with respect to the Poincaré group. As Bargmann showed, its physical representations, here explicitly constructed, are not true representations but only up-to-a-factor ones. Consequently, in nonrelativistic quantum mechanics, the mass has a very special role, and in fact, gives rise to a superselection rule which prevents the existence of unstable particles. The internal energy of a nonrelativistic system is known to be an arbitrary parameter; this is shown to come also from Galilean invariance, because of a nontrivial concept of equivalence between physical representations. On the contrary, the behavior of an elementary system with respect to rotations, is very similar to the relativistic case. We show here, in particular, how the number of polarization states reduces to two for the zero-mass case (though in fact there are no physical zero-mass systems in nonrelativistic mechanics). Finally, we study the two-particle system, where the orbital angular momenta quite naturally introduce themselves through the decomposition of the tensor product of two physical representations.