Conductivity and Charge Stiffness In this chapter, we will consider initially metal–insulator (MI) transitions which occur in pure systems without disorder. In the final section we consider a superfluid–insulator transition induced by some special type of disorder. We will show that the quantities which characterise the phase transitions in both problems obey similar scaling laws and are governed by similar exponents. Differently from the magnetic transitions treated before metal–insulator (MI) transitions have no obvious order parameter to distinguish the metallic from the insulating phase. This precludes a power expansion of the free energy in terms of a small quantity as for magnetic phase transitions. In spite of that, the concepts of phase transitions and critical phenomena turn out to be very useful to describe metal–insulator transitions. In case this problem is approached using the renormalisation group, the localisation transition is associated with an unstable fixed point and the flow of the RG equations to the different attractors is sufficient to distinguish the nature of the phases. Then, in general, we can associate a set of critical exponents with the MI transitions. Besides, these exponents are not independent but obey scaling relations. Since we are concerned with zero temperature instabilities, the quantum hyperscaling law, Eq. 1.18, plays a crucial role in this problem. We will distinguish here two different types of metal–insulator transitions. Those due to a competition between parameters of the relevant Hamiltonian and metal–insulator transitions arising by varying the number of electrons or chemical potential. An example of the former is the Mott transition due to the competition between kinetic energy and the local Coulomb repulsion as described by the half-filled band Hubbard model. The latter will be referred as density-driven metal– insulator transitions in analogy with the superfluid–insulator transition in bosonic systems with varying particle number (Fisher et al ., 1989). These two types of transitions may occur in the same system or Hamiltonian. They in general belong to different universality classes and consequently have different critical exponents.
Conductivity and Charge Stiffness In this chapter, we will consider initially metal–insulator (MI) transitions which occur in pure systems without disorder. In the final section we consider a superfluid–insulator transition induced by some special type of disorder. We will show that the quantities which characterise the phase transitions in both problems obey similar scaling laws and are governed by similar exponents. Differently from the magnetic transitions treated before metal–insulator (MI) transitions have no obvious order parameter to distinguish the metallic from the insulating phase. This precludes a power expansion of the free energy in terms of a small quantity as for magnetic phase transitions. In spite of that, the concepts of phase transitions and critical phenomena turn out to be very useful to describe metal–insulator transitions. In case this problem is approached using the renormalisation group, the localisation transition is associated with an unstable fixed point and the flow of the RG equations to the different attractors is sufficient to distinguish the nature of the phases. Then, in general, we can associate a set of critical exponents with the MI transitions. Besides, these exponents are not independent but obey scaling relations. Since we are concerned with zero temperature instabilities, the quantum hyperscaling law, Eq. 1.18, plays a crucial role in this problem. We will distinguish here two different types of metal–insulator transitions. Those due to a competition between parameters of the relevant Hamiltonian and metal–insulator transitions arising by varying the number of electrons or chemical potential. An example of the former is the Mott transition due to the competition between kinetic energy and the local Coulomb repulsion as described by the half-filled band Hubbard model. The latter will be referred as density-driven metal– insulator transitions in analogy with the superfluid–insulator transition in bosonic systems with varying particle number (Fisher et al ., 1989). These two types of transitions may occur in the same system or Hamiltonian. They in general belong to different universality classes and consequently have different critical exponents.
Introduction In this chapter we study metal–insulator transitions which occur due to correlations between the charge carriers. This quantum phase transitions results from the competition between kinetic energy and Coulomb repulsion where the latter has the tendency to localise the electrons. The simplest model which describes this competition is the one-band Hubbard model with its two energy scales, the bandwidth W and the Coulomb repulsion U between electrons of opposite spins on the same site. For a fixed density of electrons, n = 1; as the ratio U/W increases, we expect to find a zero-temperature phase transition from a metallic state to an insulator where the electrons are frozen at the lattice sites. The method employed here to investigate this transition is the Gutzwiller approach (Gutzwiller, 1965). This is a variational method which played an important role in providing a framework for the ideas of Mott on the problem of the metal–insulator transition (Mott, 1974). On the metallic side of the transition, this approach describes a metal with renormalised Fermi liquid parameters, essentially with enhanced effective mass and uniform susceptibility. This is the so-called highly correlated electron gas (Brinkman and Rice, 1970) for which the metal oxide V 2 O 3 is the prototype system. In the insulating side, Gutzwiller's approximation yields a noninteracting system of localised electrons. This insulating phase is incompressible , i.e. has zero compressibility and infinite zero temperature susceptibility. The latter is not a consequence of interactions but simply due to the divergence of the Curie susceptibility, χ ∝ 1 /T , of non-interacting moments at T = 0. Then, in Gutzwiller's approach the transition is from a paramagnetic metal to a paramagnetic insulator. We will continue using the designation Mott transition to describe this type of phase transition where the insulating phase has no long-range magnetic order. In real systems, most frequently, localisation due to interactions is accompanied by the appearance of antiferromagnetic order.
The Simplest Density-Driven Transition The simplest metal–insulator (MI) transition is that due to band filling (or emptying) in a system of non-interacting electrons. This is the fermionic equivalent of Bose–Einstein condensation in a system of non-interacting bosons. Let us consider a system of non-interacting electrons described by a tight-binding band in a hyper-cubic lattice in d -dimensional space. As the number of electrons per site n , for a given spin direction, approaches the value n c = 1 the system evolves from a metallic to an insulating state. This transition is a quantum critical phenomenon with which we can associate critical exponents. We can introduce a characteristic length χ , which can be identified with a screening length which diverges at the metal–insulator transition. The natural variable to describe this zero-temperature transition is the distance from the chemical potential or Fermi level μ , to the bottom, E b = 0, or to the top of the band E t , i.e. g = μ − E b,t . In terms of this variable, ξ ∝ | g | − ν and the ground state free energy density has a singular part that behaves as, f ∝ | g | 2− α , close to the transition. This expression defines the critical exponent α . The critical exponents ν and α associated with this zero temperature transition are related through the quantum hyperscaling relation 2 − α = ν ( d + z ). For this simple MI transition it is possible to determine its universality class for any dimension (Continentino, 1995a). One starts by noticing that the gap for excitations is actually a linear function of the distance g = μ − E t . This fixes the gap exponent at the value νz = 1. Furthermore, for a hypercubic lattice the density of states close to the band edges varies as, such that, the number where μ is the chemical potential.
Quantum Phase Transitions Quantum phase transitions, in contrast to temperature-driven critical phenomena, occur due to a competition between different parameters describing the basic interactions of the system. Their specific feature is the quantum character of the critical fluctuations. This implies, through the uncertainty principle, that energy fluctuations and time are coupled. Then at zero temperature time plays a crucial and fundamental role, the static properties being entangled with the dynamics (Continentino, 1994a; Sondhi et al ., 1997; Sachdev, 1999). In this book we are mainly interested in quantum phase transitions that occur in electronic many-body systems and how scaling concepts can be useful to understand their properties close to these transitions (Continentino, 1994a). Even though a similar approach has been used in the case of interacting bosons (Fisher et al ., 1989) the fermionic problem has its own idiosyncrasies and difficulties. For example, there is no natural order parameter associated with the localisation transition in the electronic case, while bosons at zero temperature are either localised or superfluid so that the superfluid order parameter can be used to distinguish between both phases. If the results of the study of quantum phase transitions were restricted to zero temperature, this would be an interesting but purely academic area of research. What is really exciting about this subject is the effect of quantum critical points (QCP) in the finite temperature phase diagram of actual physical systems, even far away from the QCP (Freitas, 2015). As we will show, there is a special line in this phase diagram, the quantum critical trajectory , where the temperature dependence of the thermodynamic and transport properties is governed by the quantum critical exponents, i.e. those associated with the QCP. This and the observed crossover effects induced by temperature in the non-critical side of the phase diagram of a material with a QCP are sufficient to make the study of quantum phase transitions an inevitable subject. We start this chapter by introducing the scaling theory of quantum critical phenomena, since scaling concepts are used throughout this book.
This chapter focuses on studies of the critical behavior of conductivity in two-dimensional electron systems (2DES) with different amounts and types of disorder as well as different ranges of Coulomb interactions, in order to identify possible universality classes of the 2D metal-insulator transition (MIT). It discusses the manifestations of glassiness in both low- and high-disorder samples. The chapter examines the critical region near the 2D MIT in particular on describing conductivity measurements that have demonstrated dynamical scaling, the main signature of the MIT as a quantum phase transition. It also focuses on experiments that probe the nature of the insulating state, as well as charge dynamics across the MIT, in both high- and low-disorder 2DESs. There is substantial evidence that in many materials near the MIT both strong electronic correlations and disorder play an important role, and thus their competition is expected to lead to glassy behavior of electrons, in analogy with other frustrated systems.
Metallic states near the Mott insulator show a variety of quantum phases, including various magnetic, charge-ordered states and high-temperature superconductivity in various transition metal oxides and organic solids. The emergence of a variety of phases and their competitions are likely intimately associated with quantum transitions between the electron-correlation-driven Mott insulator and metals characterized by its criticality, and is related to many central questions of condensed matter. The quantum criticality is, however, not well understood when the transition is controlled by the bandwidth through physical parameters such as pressure. Here, we quantitatively estimate the universality class of the transition characterized by a comprehensive set of critical exponents by using a variational Monte Carlo method implemented as an open-source innovated quantum many-body solver, with the help of established scaling laws at a typical bandwidth-controlled Mott transition. The criticality indicates a weaker charge and density instability in contrast to the filling-controlled transition realized by carrier doping, implying a weaker instability to superconductivity as well. The present comprehensive clarification opens up a number of routes for quantitative experimental studies for complete understanding of elusive quantum Mott transition and nearby strange metal that cultivate future design of functionality.
Introduction The quantum phase transitions considered so far in this book are mostly continuous, second order. They are associated with the divergence of a correlation length and of a characteristic time that renders the quantum critical point scale invariant. However, there are many important phase transitions at which the order parameter goes abruptly to zero and, more important, at which the characteristics of length and critical time do not diverge. In general there is also a latent heat , or work required, to transform one phase into another. In this and the next chapter we study these discontinuous quantum phase transitions. We proceed by considering initially some important cases of what is known as fluctuation induced quantum phase transitions to next treat a more general case of a first-order quantum phase transition. We will show through the study of these problems that the concepts of critical exponents and scaling remain useful, even though these systems do not exhibit scale invariance at their critical point. In Chapter 15 we present the scaling theory of first-order quantum phase transitions and use its results to treat some general problems. One of the most interesting cases of fluctuation-induced transitions occurs in superconductors due to the coupling of the charged carriers to the electromagnetic field. We consider initially a wider class of systems with macroscopic wave functions, the superfluids, of which superconductors are the charged version. We adopt a macroscopic approach to this problem and describe the superfluid by a complex order parameter φ , such that | φ | 2 is proportional to the density of condensed particles. The zero temperature phase diagram is expressed in terms of a control parameter, m 2 , such that, at m 2 = 0, the system presents a quantum phase transition from a superfluid state, for m 2 < 0, φ ≠ 0, to a normal state for m 2 > 0 where φ = 0. In the case of the superconductor with particles of charge q = 2 e , we will include the coupling of these particles to the electromagnetic field and study its effect in the phase diagram of these systems. We show that in the neutral superfluid, the zero temperature transition to the normal state is continuous and occurs at a quantum critical point.