There is considerable interest in the dynamics of ultracold plasmas and ultracold Rydberg gases. Ultracold plasmas are typically formed by photo-excitation of ultracold atoms to an energy region near (both above and below) an ionization threshold. Excitation to bound, highly-excited Rydberg states can lead to formation of a plasma via several processes, including collisions between Rydberg atoms. Three-body recombination in an ultracold plasma can also result in the production of ultracold Rydberg atoms. Understanding the dynamics of ultracold Rydberg gases is therefore important for understanding the dynamics of ultracold plasmas. In this dissertation, we have investigated the formation and survival of a particular class of Rydberg atoms. These atoms are known as ZEKE state Rydberg atoms, where the term ZEKE is derived from "Zero Kinetic Energy." ZEKE Rydberg states are high angular momentum and high angular momentum projection excited states which can be formed by laser excitation in the presence of electric fields. Without the electric fields, these states would be optically dark. We have investigated ZEKE Rydberg states in ultracold argon in an energy region just below the second ionization threshold of the atoms in our magneto-optical trap. Here, low angular momentum states decay very quickly (< 1 ns) by auto-ionization through a core spin flip due to the Rydberg electron-core interaction. This interaction has been significantly reduced due to the dilution of low l and m states as a result of l and m mixing during excitation. Hence, ZEKE Rydberg states live orders of magnitude longer than low angular momentum states. We are reporting on our experimental investigation of these states in the ultracold regime and prospects for future studies in which external control of these states may be used to control ultracold plasma dynamics.
There is considerable interest in the dynamics of ultracold plasmas and ultracold Rydberg gases. Ultracold plasmas are typically formed by photo-excitation of ultracold atoms to an energy region near (both above and below) an ionization threshold. Excitation to bound, highly-excited Rydberg states can lead to formation of a plasma via several processes, including collisions between Rydberg atoms. Three-body recombination in an ultracold plasma can also result in the production of ultracold Rydberg atoms. Understanding the dynamics of ultracold Rydberg gases is therefore important for understanding the dynamics of ultracold plasmas. In this dissertation, we have investigated the formation and survival of a particular class of Rydberg atoms. These atoms are known as ZEKE state Rydberg atoms, where the term ZEKE is derived from "Zero Kinetic Energy." ZEKE Rydberg states are high angular momentum and high angular momentum projection excited states which can be formed by laser excitation in the presence of electric fields. Without the electric fields, these states would be optically dark. We have investigated ZEKE Rydberg states in ultracold argon in an energy region just below the second ionization threshold of the atoms in our magneto-optical trap. Here, low angular momentum states decay very quickly (< 1 ns) by auto-ionization through a core spin flip due to the Rydberg electron-core interaction. This interaction has been significantly reduced due to the dilution of low l and m states as a result of l and m mixing during excitation. Hence, ZEKE Rydberg states live orders of magnitude longer than low angular momentum states. We are reporting on our experimental investigation of these states in the ultracold regime and prospects for future studies in which external control of these states may be used to control ultracold plasma dynamics.
We report on our investigation of the formation and survival of long-lived Rydberg states in argon produced by pulsed laser excitation of ultracold metastable state argon atoms in a magneto-optical trap. The states studied have a 2P1/2 core. Low angular momentum Rydberg states with this core normally autoionize rapidly. If, however, atoms are excited in the presence of electric fields, higher angular momentum states, traditionally termed ``ZEKE states'' (ZEKE is derived from ``zero kinetic energy'') can be formed. The lifetime of these states can be orders of magnitude greater than low angular momentum states. In this paper, we report on the time dependence of ZEKE Rydberg state population in an ultracold environment.
We have studied the development of gases of ultra-cold Rydberg atoms in Magneto Optic Traps, and discovered that such gases exhibit a range of density-dependent phenomena. In particular, we have found that at the densities of ∼ 10 7 cm -3 the Rydberg atoms spontaneously evolve into long-lived high angular momentum states. These states slowly decay due to microwave background radiation over tens of milliseconds. We have numerically simulated the effects leading to such behavior, and investigated numerically the l- and n-mixing collisions of Rydberg atoms with electrons in the range of 10 meV. These calculations show that the l- and n-mixing cross-sections follow the n 5 scaling law, expected from simple Stark map considerations, but also depend on the velocities of the colliding electrons, reflecting the adiabaticity of the atom-electron interactions. We have developed a novel technique of measuring the electric fields inside plasmas by using Rydberg excitation spectroscopy of embedded atoms, based on the disappearance of regions of zero oscillator strength in the presence of such fields. We have applied this technique to study the evolution of ultra-cold non-neutral plasmas excited from the MOT, and have found that it expands over 1 mus. We have simulated such an expansion by considering only Coulomb repulsion between the constituent ions, and have found that such a model is consistent with the experimental observations.
We have observed the evolution of cold Rydberg gases and ultracold plasmas in an environment that allows for the control of interactions of the blackbody radiation temperature from 4K to 300K. The work in this thesis describes the influence of initial densities, populations, excitation state, evolution time and thermal background temperature on the evolution of cold Rydberg gases as well as directly excited ultracold plasmas. With some initial ionization, cold-Rydberg-atom gases easily develop a positive space charge that traps electrons for times on the order of tens of mus. This acts as a catalyst for electron-Rydberg atom collisions, increasing the collision probabilities by orders of magnitude and profoundly altering the final state of the Rydberg gas. Using state-selective field ionization, we have provided direct proof that these collisions cause changes in l-states, and we have seen the first experimental evidence that they also lead to inelastic n-changing collisions, as predicted by theory. We have also found evidence for Rydberg-Rydberg collisions, enabled by the attractive electric-dipole forces between atoms in high-l states and possibly by van-der-Waal's interactions at very high-n . Thermal interactions are seen to influence the formation of a plasma from a cold Rydberg gas. Plasmas form more easily in the presence of a 300K radiation field than at 4K, due to the contribution of thermal ionization to the plasma formation. The background temperature also appears to affect the electron temperature in both the directly excited plasma and the plasma spontaneously formed from a cold Rydberg gas. In Rydberg atom gases that have undergone partial ionization, electron temperatures were estimated using the dependence of n-changing collisions on the electron temperature.
Cold, dense Rydberg gases produced in a cold-atom trap are investigated using spectroscopic methods and time-resolved electron counting. On the discrete Rydberg resonances we observe large trap losses and long lasting electron emission from the Rydberg gas (>30ms). Our observations are explained by quasi-elastic l-mixing collisions between Rydberg atoms and slow electrons that lead to the population of long-lived high-angular-momentum Rydberg states. These atoms thermally ionize slowly and with large probabilities, leading to the observed effects.
By photoionizing samples of laser-cooled atoms with laser light tuned just above the ionization limit, plasmas can be created with electron and ion temperatures below 10 K. These ultracold neutral plasmas have extended the temperature bounds of plasma physics by two orders of magnitude. Table-top experiments, using many of the tools from atomic physics, allow for the study of plasma phenomena in this new regime with independent control over the density and temperature of the plasma through the excitation process. Characteristic of these systems is an inhomogeneous density profile, inherited from the density distribution of the laser-cooled neutral atom sample. Most work has dealt with unconfined plasmas in vacuum, which expand outward at velocities of order 100 m/s, governed by electron pressure, and with lifetimes of order 100 μs, limited by stray electric fields. Using detection of charged particles and optical detection techniques, a wide variety of properties and phenomena have been observed, including expansion dynamics, collective excitations in both the electrons and ions, and collisional properties. Through three-body recombination collisions, the plasmas rapidly form Rydberg atoms, and clouds of cold Rydberg atoms have been observed to spontaneously avalanche ionize to form plasmas. Of particular interest is the possibility of the formation of strongly coupled plasmas, where Coulomb forces dominate thermal motion and correlations become important. The strongest impediment to strong coupling is disorder-induced heating, a process in which Coulomb energy from an initially disordered sample is converted into thermal energy. This restricts electrons to a weakly coupled regime and leaves the ions barely within the strongly coupled regime. This review will give an overview of the field of ultracold neutral plasmas, from its inception in 1999 to current work, including efforts to increase strong coupling and effects on plasma properties due to strong coupling.
By photoionizing cold, trapped atoms it is possible to produce ultracold plasmas with temperatures in the vicinity of 1 K, roughly 4 orders of magnitude colder than conventional cold plasmas. After the first photoelectrons leave, the resulting positive charge traps the remaining electrons in the plasma. Monitoring the dynamics of the expansion of these plasmas shows explicitly the flow of energy from electrons to the ionic motion, which is manifested as the expansion of the plasma. The electron energy can either be their initial energy from photoionization or can come from the energy redistribution inherent in recombination and superelastic scattering from recombined Rydberg atoms. If the cold atoms are excited to Rydberg states instead of being photoionized, the resulting cold Rydberg gas quickly evolves into an ultracold plasma. After a few percent of the atoms are ionized by collisions or blackbody radiation, electrons are trapped by the resulting positive charge, and they quickly lead to ionization of the Rydberg atoms, forming a plasma. While the source of this energy is not clear, a likely candidate is superelastic scattering, also thought to be important for the expansion of deliberately made plasmas.