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Bulletin of the American Physical Society

Frequency-comb based spectroscopy of the Yb I 399 nm transition

Quinton McKnight, Michaela Kleinert, Scott Bergeson

Published Jun 7, 2017• 0 citations
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We report on the observation of the 4f146s2 1S0−4f135d6s2(J=2)4f^{14}6s^{2}~^1S_0- 4f^{13}5d6s^{2}(J=2)4f146s2 1S0​−4f135d6s2(J=2) transition at 431 nm in 171^{171}171Yb by depleting atoms in a magneto-optical trap formed by the 6s2 1S0−6s6p 3P16s^{2}~^1S_0-6s6p~^3P_16s2 1S0​−6s6p 3P1​ intercombination transition. The absolute frequency of the transition to the F=3/2F=3/2F=3/2 state is determined to be 695 171 054 858.1(8.2)695~171~054~858.1(8.2)695 171 054 858.1(8.2)~kHz against physical realization of Coordinated Universal Time maintained by the National Metrology Institute of Japan with a frequency comb. The ggg factor of the transition to the F=3/2F=3/2F=3/2 state and the A hyperfine constant are measured to be gJ=1.54(13)g_J=1.54(13)gJ​=1.54(13) and 1123.354(13)~MHz, respectively. More precise spectroscopy of this transition can lead to searches for time variation of the fine structure constant and searches for new physics with isotope shift measurements.
This work has focused on two atoms, Sr and Yb, due in part to the relatively high abundance of their odd isotopes, the use of which is necessary for appreciable direct excitation probability. The Sr clock transition has been measured (with an uncertainty of 20 kHz) using atoms in a magneto-optic trap (MOT), and has been excited with atoms confined in a one dimensional lattice. Here we report direct excitation of the Yb clock transition (at 578 nm) with atoms in a second-stage MOT, and the first fs-laser comb-based absolute measurements of the clock frequency for two different isotopes. These measurements lead to a nearly millionfold improvement in our knowledge of the transition frequencies, an important step toward Doppler-free spectroscopy of Yb atoms in a lattice.
This work has focused on two atoms, Sr and Yb, due in part to the relatively high abundance of their odd isotopes, the use of which is necessary for appreciable direct excitation probability. The Sr clock transition has been measured (with an uncertainty of 20 kHz) using atoms in a magneto-optic trap (MOT), and has been excited with atoms confined in a one dimensional lattice. Here we report direct excitation of the Yb clock transition (at 578 nm) with atoms in a second-stage MOT, and the first fs-laser comb-based absolute measurements of the clock frequency for two different isotopes. These measurements lead to a nearly millionfold improvement in our knowledge of the transition frequencies, an important step toward Doppler-free spectroscopy of Yb atoms in a lattice.