We propose a scheme for mediating many simultaneous, fast entangling gates between pairs of polar molecules using Rydberg atoms. By using microwave drives, the dipolar interactions between Rydberg atoms are nullified. Using the freedom left in the microwave dressing parameters, the Rydberg van der Waals interactions are minimized and the Rydberg-molecule interaction is tuned into resonance, allowing for the mediation of a modified iSWAP gate between molecules. In the example of mediating gates between $\rm{{}^{23}Na {}^{133}Cs}$ molecules with $\rm {}^{133}Cs$ atoms, the gate is more than two orders of magnitude faster than an equivalent direct molecule-molecule gate. We model the decay of the dressed Rydberg states and the motion of the atom and molecules and obtain a leading-order estimate of the resulting gate infidelities. Finally, we show that by detecting the state of the Rydberg atom after a gate, a subset of gate errors can be converted into erasure errors and mitigated by post-selection or quantum error-correction.We propose a scheme for mediating many simultaneous, fast entangling gates between pairs of polar molecules using Rydberg atoms. By using microwave drives, the dipolar interactions between Rydberg atoms are nullified. Using the freedom left in the microwave dressing parameters, the Rydberg van der Waals interactions are minimized and the Rydberg-molecule interaction is tuned into resonance, allowing for the mediation of a modified iSWAP gate between molecules. In the example of mediating gates between $\rm{{}^{23}Na {}^{133}Cs}$ molecules with $\rm {}^{133}Cs$ atoms, the gate is more than two orders of magnitude faster than an equivalent direct molecule-molecule gate. We model the decay of the dressed Rydberg states and the motion of the atom and molecules and obtain a leading-order estimate of the resulting gate infidelities. Finally, we show that by detecting the state of the Rydberg atom after a gate, a subset of gate errors can be converted into erasure errors and mitigated by post-selection or quantum error-correction.

quant-pharXiv:2609.28694Sep 25, 20260 citations

Rydberg atom mediated polar molecule interactions: a tool for molecular-state conditional quantum gates and individual addressability

Elena Kuznetsova, Seth T. Rittenhouse, H. R. Sadeghpour +1 more

We study the possibility to use interaction between a polar molecule in the ground electronic and vibrational state and a Rydberg atom to construct two-qubit gates between molecular qubits and to coherently control molecular states. A polar molecule within the electron orbit in a Rydberg atom can either shift the Rydberg state, or form a Rydberg molecule. Both the atomic shift and the Rydberg molecule states depend on the initial internal state of the polar molecule, resulting in molecular state dependent van der Waals or dipole-dipole interaction between Rydberg atoms. Rydberg atoms mediated interaction between polar molecules can be enhanced up to 10(3) times. We describe how the coupling between a polar molecule and a Rydberg atom can be applied to coherently control molecular states, and specifically, to individually address molecules in an optical lattice, and to non-destructively readout molecular qubits.We study the possibility to use interaction between a polar molecule in the ground electronic and vibrational state and a Rydberg atom to construct two-qubit gates between molecular qubits and to coherently control molecular states. A polar molecule within the electron orbit in a Rydberg atom can either shift the Rydberg state, or form a Rydberg molecule. Both the atomic shift and the Rydberg molecule states depend on the initial internal state of the polar molecule, resulting in molecular state dependent van der Waals or dipole-dipole interaction between Rydberg atoms. Rydberg atoms mediated interaction between polar molecules can be enhanced up to 10(3) times. We describe how the coupling between a polar molecule and a Rydberg atom can be applied to coherently control molecular states, and specifically, to individually address molecules in an optical lattice, and to non-destructively readout molecular qubits.

arXiv:1105.2010Physical Chemistry Chemical PhysicsJan 1, 201128 citations

Rydberg Atom Interactions

Jonathan D. Pritchard

Springer thesesJan 1, 20120 citations

Rydberg states in polar molecules

B. A. Zon, M. Damashek

Journal of Experimental and Theoretical PhysicsJul 1, 19921 citation

\rm{{}^{23}Na {}^{133}Cs}

molecules with

\rm {}^{133}Cs

atoms, the gate is more than two orders of magnitude faster than an equivalent direct molecule-molecule gate. We model the decay of the dressed Rydberg states and the motion of the atom and molecules and obtain a leading-order estimate of the resulting gate infidelities. Finally, we show that by detecting the state of the Rydberg atom after a gate, a subset of gate errors can be converted into erasure errors and mitigated by post-selection or quantum error-correction.