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Molecular Physics

Ehrenfest ‘phase-space’ trajectories and quantum chaos in He atom under strong, oscillating magnetic fields: an application of time-dependent quantum fluid density functional theory (TDQFDFT)

Mainak Sadhukhan, Bimalendu Deb

Published Feb 22, 2017• 5 citations
Publisher

Abstract

Using a dynamical signature proposed earlier from our laboratory, quantum chaos in He atom interacting with strong, oscillating magnetic fields has been studied through a comparison between the nonlinear divergence of two neighbouring Ehrenfest ‘phase-space’ (EPS) trajectories differing slightly in initial conditions and the Loschmidt echo. The dynamical EPS signature can detect quantum chaos independently of the Loschmidt echo and in agreement with the latter, even for low-lying states, in the same spirit as that of classical chaos. This time-dependent signature extends the concept of quantum chaos to systems which have no classical counterparts and brings the concept of quantum chaos closer to that of classical chaos.

DOI
10.1080/00268976.2017.1288277

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Using a dynamical signature proposed earlier from our laboratory, quantum chaos in He atom interacting with strong, oscillating magnetic fields has been studied through a comparison between the nonlinear divergence of two neighbouring Ehrenfest ‘phase-space’ (EPS) trajectories differing slightly in initial conditions and the Loschmidt echo. The dynamical EPS signature can detect quantum chaos independently of the Loschmidt echo and in agreement with the latter, even for low-lying states, in the same spirit as that of classical chaos. This time-dependent signature extends the concept of quantum chaos to systems which have no classical counterparts and brings the concept of quantum chaos closer to that of classical chaos.
Quantum chaos concerns the emergence of universal statistical and dynamical prop- erties in quantum systems whose classical counterparts exhibit chaotic behavior. Unlike classical chaos, which can be characterized by sensitivity to initial conditions and exponential divergence of trajectories, quantum chaos manifests itself through a variety of indirect diagnostics, including spectral correlations, operator growth, and information scrambling. Understanding how these signatures arise from microscopic dynamics, and how they can be accessed in realistic many-body systems, is a central challenge in modern physics. This thesis investigates quantum chaos from complementary theoretical and practical perspectives. On the theoretical side, it develops effective descriptions of chaotic dy- namics in many-body systems with approximate symmetries, focusing on how weak symmetry breaking controls the exploration of Hilbert space and the crossover to random-matrix universality. Using perturbative arguments, numerical simulations, and a nonlinear sigma-model formulation, we identify a regime of Hilbert-space dif- fusion in which chaotic dynamics unfolds through a slow, collective spreading across nearly decoupled symmetry sectors. On the practical side, the thesis addresses the question of how paradigmatic chaotic models can be realized and probed in controlled experimental platforms. In partic- ular, it explores quantum simulation schemes for Sachdev–Ye–Kitaev (SYK) models using cavity quantum electrodynamics. By employing time-dependent disorder and Trotterized evolution in single-mode optical cavities, we demonstrate how low-rank interactions can be systematically promoted to effective all-to-all randomness, re- producing the spectral and dynamical signatures of SYK physics. Extensions to open-system dynamics are discussed, including Lindbladian realizations and the role of dissipation. The thesis thus highlights the connections between effective descriptions of quantum chaos and their implementation in controlled quantum simulation settings.
We study the time evolution of driven quantum systems using analytic, algebraic, and numerical methods. First, we obtain analytic solutions for driven free and oscillator systems by shifting the coordinate and phase of the undriven wave function. We also factorize the quantum evolution operator using the generators of the Lie algebra comprising the Hamiltonian. We obtain coupled ODE's for the time evolution of the Lie algebra parameters. These parameters allow us to find physical properties of oscillator dynamics. In particular we find phase-space trajectories and transition probabilities. We then search for chaotic behavior in the Lie algebra parameters as a signature for dynamical chaos in the quantum system. We plot the trajectories, transition probabilities, and Lyapunov exponents for a wide range of the following physical parameters: strength and duration of the driving force, frequency difference, and anharmonicity of the oscillator. We identify conditions for the appearance of chaos in the system.
A bstract A classical dynamical system can be viewed as a probability space equipped with a measure-preserving time evolution map, admitting a purely algebraic formulation in terms of the algebra of bounded functions on the phase space. Similarly, a quantum dynamical system can be formulated using an algebra of bounded operators in a non-commutative probability space equipped with a time evolution map. Chaos, in either setting, can be characterized by statistical independence between observables at t = 0 and t → ∞, leading to the vanishing of cumulants involving these observables. In the quantum case, the notion of independence is replaced by free independence, which only emerges in the thermodynamic limit (asymptotic freeness). In this work, we propose a definition of quantum chaos based on asymptotic freeness and investigate its emergence in quantum many-body systems including the mixed-field Ising model with a random magnetic field, a higher spin version of the same model, and the SYK model. The hallmark of asymptotic freeness is the emergence of the free convolution prediction for the spectrum of operators of the form A (0) + B ( t ), implying the vanishing of all free cumulants between A (0) and B ( t ) in the thermodynamic limit for an infinite-temperature thermal state. We systematically investigate the spectral properties of A (0) + B ( t ) in the above-mentioned models, show that fluctuations on top of the free convolution prediction follow universal Wigner-Dyson statistics, and discuss the connection with quantum chaos. Finally, we argue that free probability theory provides a rigorous framework for understanding quantum chaos, offering a unifying perspective that connects many different manifestations of it.
Chaos in classical systems can be characterized by Lyapunov exponents that measure the exponential divergence of nearby trajectories, but directly extending this framework to quantum mechanics has been a persistent challenge. The wavelike nature of quantum states and the non-commutative geometry of quantum phase space obstruct a straightforward generalization of classical chaos theory. Here we develop a rigorous approach to quantum chaos by leveraging quantum optimal transport theory, which provides the missing geometric foundation for measuring distances between extended quantum distributions. We define quantum Lyapunov exponents that naturally avoid divergences encountered when naïvely generalizing classical exponents, and show that in the semiclassical limit they recover the classical global expansion rate, and hence the usual maximal Lyapunov exponent when they coincide. Our framework provides a tight connection between the divergence of classical trajectories and semiclassical phase space evolution, and additionally clarifies the role of out-of-time-order correlators as diagnostics of quantum chaos. These results establish quantum optimal transport as a unifying mathematical foundation for quantum chaos theory, providing new tools to characterize dynamical behavior across the full range of quantum dynamics from simple few-body models to complex many-body systems.