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Beilstein Journal of Nanotechnology

Selective photodissociation of tailored molecular tags as a tool for quantum optics

Uĝur Sezer, Philipp Geyer, Moritz Kriegleder, Maxime Debiossac, Armin Shayeghi, Markus Arndt, Lukas Felix, Marcel Mayor

Published Feb 2, 2017• 7 citations
Publisher

Abstract

Recent progress in synthetic chemistry and molecular quantum optics has enabled demonstrations of the quantum mechanical wave-particle duality for complex particles, with masses exceeding 10 kDa. Future experiments with even larger objects will require new optical preparation and manipulation methods that shall profit from the possibility to cleave a well-defined molecular tag from a larger parent molecule. Here we present the design and synthesis of two model compounds as well as evidence for the photoinduced beam depletion in high vacuum in one case.

DOI
10.3762/bjnano.8.35

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Recent progress in synthetic chemistry and molecular quantum optics has enabled demonstrations of the quantum mechanical wave-particle duality for complex particles, with masses exceeding 10 kDa. Future experiments with even larger objects will require new optical preparation and manipulation methods that shall profit from the possibility to cleave a well-defined molecular tag from a larger parent molecule. Here we present the design and synthesis of two model compounds as well as evidence for the photoinduced beam depletion in high vacuum in one case.
We describe the state of the art in preparing, manipulating and detecting coherent molecular matter. We focus on experimental methods for handling the quantum motion of compound systems from diatomic molecules to clusters or biomolecules.Molecular quantum optics offers many challenges and innovative prospects: already the combination of two atoms into one molecule takes several well-established methods from atomic physics, such as for instance laser cooling, to their limits. The enormous internal complexity that arises when hundreds or thousands of atoms are bound in a single organic molecule, cluster or nanocrystal provides a richness that can only be tackled by combining methods from atomic physics, chemistry, cluster physics, nanotechnology and the life sciences.We review various molecular beam sources and their suitability for matter-wave experiments. We discuss numerous molecular detection schemes and give an overview over diffraction and interference experiments that have already been performed with molecules or clusters.Applications of de Broglie studies with composite systems range from fundamental tests of physics up to quantum-enhanced metrology in physical chemistry, biophysics and the surface sciences.Nanoparticle quantum optics is a growing field, which will intrigue researchers still for many years to come. This review can, therefore, only be a snapshot of a very dynamical process.
Miniaturization has been the driving force in contemporary technologies. However, two main obstacles limit further progress: additional reduction in size has reached its quantum limit, and lithography has reached its threshold. Future progress requires tackling three challenges: chemical synthesis of a complete device, active cooling for exploiting quantum characteristics, and quantum coherent control for operation. Chemical synthesis replaces the current top-bottom approach to manufacturing with bottom-up synthesis from elementary building blocks. New ultracold synthetic methods should be developed. An additional challenge is the active cooling of molecules, where the bottleneck is entropy removal. Notably, the current solution, namely, diffusion, is too slow. A coherent approach offers a possible solution; specifically, quantum coherent control is the method of choice for manipulating ultracold matter. Finally, the many degrees of freedom of molecules should be an asset that allows the design and implementation of complex tasks such as sensing communication and computing.
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