A method for enhancement of the sensitivity of a spin sensor based on an ensemble of nitrogen vacancy (NV) color centers was demonstrated. Gold nanoparticles (NPs) were deposited on the bulk diamond, which had NV centers distributed on its surface. The experimental results demonstrate that, when using this simple method, plasmon enhancement of the deposited gold NPs produces an improvement of ∼10 times in the quantum efficiency and has also improved the signal-to-noise ratio by approximately ∼2.5 times. It was also shown that more electrons participated in the spin sensing process, leading to an improvement in the sensitivity of approximately seven times; this has been proved by Rabi oscillation and optical detection of magnetic resonance (ODMR) measurements. The proposed method has proved to be a more efficient way to design an ensemble of NV centers-based sensors; because the result increases in the number of NV centers, the quantum efficiency and the contrast ratio could greatly increase the device's sensitivity.
A method for enhancement of the sensitivity of a spin sensor based on an ensemble of nitrogen vacancy (NV) color centers was demonstrated. Gold nanoparticles (NPs) were deposited on the bulk diamond, which had NV centers distributed on its surface. The experimental results demonstrate that, when using this simple method, plasmon enhancement of the deposited gold NPs produces an improvement of ∼10 times in the quantum efficiency and has also improved the signal-to-noise ratio by approximately ∼2.5 times. It was also shown that more electrons participated in the spin sensing process, leading to an improvement in the sensitivity of approximately seven times; this has been proved by Rabi oscillation and optical detection of magnetic resonance (ODMR) measurements. The proposed method has proved to be a more efficient way to design an ensemble of NV centers-based sensors; because the result increases in the number of NV centers, the quantum efficiency and the contrast ratio could greatly increase the device's sensitivity.
Abstract The nitrogen-vacancy (NV) color center in diamond has demonstrated great promise in a wide range of quantum sensing. Recently, there have been a series of proposals and experiments using NV centers to detect spin noise of quantum materials near the diamond surface. This is a rich complex area of study with novel nano-magnetism and electronic behavior, that the NV center would be ideal for sensing. However, due to the electronic properties of the NV itself and its host material, getting high quality NV centers within nanometers of such systems is challenging. Band bending caused by space charges formed at the metal-semiconductor interface force the NV center into its insensitive charge states. Here, we investigate optimizing this interface by depositing thin metal films and thin insulating layers on a series of NV ensembles at different depths to characterize the impact of metal films on different ensemble depths. We find an improvement of coherence and dephasing times we attribute to ionization of other paramagnetic defects. The insulating layer of alumina between the metal and diamond provide improved photoluminescence and higher sensitivity in all modes of sensing as compared to direct contact with the metal, providing as much as a factor of 2 increase in sensitivity, decrease of integration time by a factor of 4, for NV T 1 relaxometry measurements.
Nitrogen vacancy centers in diamond are among the leading solid state quantum platforms, offering exceptional spatial resolution and sensitivity for applications such as magnetic field sensing, thermometry, and bioimaging. However, in high background environments,such as those encountered in in vitro diagnostics, the performance of NV based sensors can be compromised by strong background fluorescence, particularly from substrates such as nitrocellulose. In this work, we analytically and experimentally investigate the use of pulsed laser excitation combined with time gating techniques to suppress background fluorescence and enhance the signal to noise ratio in NV based quantum sensing, with an emphasis on spin enhanced biosensing. Through experimental studies using mixed ensembles of silicon vacancy and NV centers in bulk diamond, as well as fluorescent nanodiamonds on NC substrates, we demonstrate significant improvements in NV spin resonance visibility, demonstrated by an increase of the SNR by up to 4x, and a resulting measurement time reduction by 16x. The presented technique and results here can help significantly increase the readout efficiency and speed in future applications of NV centers in high background environments, such as in IVD, where the NV centers are used as a fluorescent label for biomolecules.
The nitrogen-vacancy (NV) color center in diamond has demonstrated great promise in a wide range of quantum sensing. Recently, there have been a series of proposals and experiments using NV centers to detect spin noise of quantum materials near the diamond surface. This is a rich complex area of study with novel nano-magnetism and electronic behavior, that the NV center would be ideal for sensing. However, due to the electronic properties of the NV itself and its host material, getting high quality NV centers within nanometers of such systems is challenging. Band bending caused by space charges formed at the metal-semiconductor interface force the NV center into its insensitive charge states. Here, we investigate optimizing this interface by depositing thin metal films and thin insulating layers on a series of NV ensembles at different depths to characterize the impact of metal films on different ensemble depths. We find an improvement of coherence and dephasing times we attribute to ionization of other paramagnetic defects. The insulating layer of alumina between the metal and diamond provide improved photoluminescence and higher sensitivity in all modes of sensing as compared to direct contact with the metal, providing as much as a factor of 2 increase in sensitivity, decrease of integration time by a factor of 4, for NV T1 relaxometry measurements.
The nitrogen-vacancy (NV) center in diamond is very sensitive to magnetic and electric fields, strain, and temperature. In addition, it is possible to optically interrogate individual defects, making it an ideal quantum-limited sensor with nanoscale resolution. A key limitation for the application of NV sensing is the optical brightness and collection efficiency of these defects. Plasmonic resonances of metal nanoparticles have been used in a variety of applications to increase the brightness and efficiency of quantum emitters, and therefore are a promising tool to improve NV sensing. However, the interaction between NV centers and plasmonic structures is largely unexplored. In particular, the back-action between NV and plasmonic nanoparticles is nonlinear and depends on optical wavelength, nanoparticle position, and metal type. Here we present the general theory of NV-plasmonic nanoparticle interactions. We detail how the interplay between NV response, including optical and vibrational signatures, and the plasmonic response of the metal nanoparticle results in modifications to the emission spectra. Our model is able to explain quantitatively the existing experimental measurements of NV centers near metal nanoparticles. In addition, it provides a pathway to developing new plasmonic structures to improve readout efficiencies in a range of applications for the NV center. This will enable higher precision sensors, with greater bandwidth as well as new readout modalities for quantum computing and communication.
The nitrogen-vacancy (NV) color center in diamond is a promising solid-state quantum system at room temperature. However, its sensitivity is limited by its low fluorescence collection efficiency, and its coherence time is limited by spin interference of impurity electrons around the NV color center. Here, we innovatively fabricated a one-dimensional photonic crystal on the surface of diamond, which greatly improved the fluorescence intensity of the NV color centers and increased the sensitivity of NV ensembles by a factor of 2.92. In addition, the laser reflected by the photonic crystal excites impurity electrons around the NV color centers, improving the electric field environment around the NV color centers, which exponentially prolongs the dephasing time (from 209 to 841 ns), opening avenues for NV color-center ensemble sensors.
We present a dual-wavelength analysis of nitrogen-vacancy (NV) center quantum magnetometry enhanced by uniformly coated gold nanoparticles (AuNPs). An ensemble-averaged model is developed to analyze the AuNP-enhanced stimulated absorption at the 532 nm excitation wavelength and the spontaneous emission at 637 nm. The resulting detected optically magnetic resonance (ODMR) signal profiles are simulated for both enhancement mechanisms. We find that the enhanced stimulated absorption at 532 nm significantly amplifies the ODMR signal intensity without broadening the linewidth, thereby improving the signal-to-noise ratio (SNR) without sacrificing the magnetic field sensing resolution. Conversely, enhancing the 637 nm spontaneous emission increases the total photo emission rate but simultaneously broadens the ODMR detection linewidth due to the direct reduction in the effective spin coherence time of excited states by the enhanced spontaneous rate. The dual-wavelength analysis provides valuable design guidance for the development of low-cost spin-coated AuNP-enhanced NV-center quantum magnetometry technologies.