A quantum mechanics representation based on position ($\vec{r}$), linear momentum($\vec{p}$) and energy($E$) eigenvalues is presented here. A set of equations, explicitly independent on wave function, was derived relating these observables. In this view, a particle has a known trajectory and at any point on space there is a linear momentum associated. Trajectory here, can be viewed as if a measurement were taken continuously. This picture does not change current quantum mechanics interpretation, rather it comes as a new route of calculation. Also, wave function can be retrieved performing an integration in all space for linear momentum. Equations derived in this work, present a potential dependent on linear momentum originating what we call quantum force. A particle experiences a total force whose resultant is composed by classic and quantum force, evolving on time according to it. In terms of evaluation, a single particle could be described by a set of auxiliary particles named as wave particles(WP). They will start with a range of initial conditions and will collectively describe probabilistic aspects of quantum mechanics. We expect this route could be applied to many problems, such as multi-body systems.
A quantum mechanics representation based on position (r), linear momentum(p) and energy(E) eigenvalues is presented here. A set of equations, explicitly independent on wave function, was derived relating these observables. In this view, a particle has a known trajectory and at any point on space there is a linear momentum associated. Trajectory here, can be viewed as if a measurement were taken continuously. This picture does not change current quantum mechanics interpretation, rather it comes as a new route of calculation. Also, wave function can be retrieved performing an integration in all space for linear momentum. Equations derived in this work, present a potential dependent on linear momentum originating what we call quantum force. A particle experiences a total force whose resultant is composed by classic and quantum force, evolving on time according to it. In terms of evaluation, a single particle could be described by a set of auxiliary particles named as wave particles(WP). They will start with a range of initial conditions and will collectively describe probabilistic aspects of quantum mechanics. We expect this route could be applied to many problems, such as multi-body systems.
A quantum mechanics representation based on position (r), linear momentum(p) and energy(E) eigenvalues is presented here. A set of equations, explicitly independent on wave function, was derived relating these observables. In this view, a particle has a known trajectory and at any point on space there is a linear momentum associated. Trajectory here, can be viewed as if a measurement were taken continuously. This picture does not change current quantum mechanics interpretation, rather it comes as a new route of calculation. Also, wave function can be retrieved performing an integration in all space for linear momentum. Equations derived in this work, present a potential dependent on linear momentum originating what we call quantum force. A particle experiences a total force whose resultant is composed by classic and quantum force, evolving on time according to it. In terms of evaluation, a single particle could be described by a set of auxiliary particles named as wave particles(WP). They will start with a range of initial conditions and will collectively describe probabilistic aspects of quantum mechanics. We expect this route could be applied to many problems, such as multi-body systems.
Classical mechanics is usually valid at the macro scale. The changes in the position and the momentum of the object over time are described by the Hamiltonian equation of motion. The wave function in quantum mechanics, if unobserved, evolves in a smooth and continuous way according to the Schrodinger equation, which is related to the Hamiltonian equation of motion. This equation describes a linear superposition of different states at time. A quantum mechanical description of a physical system is related to a probabilistic representation; it is described by a vector in Hilbert space. This description extends the two- or three-dimensional Euclidean space into spaces that have any finite or infinite number of dimensions. The state of a compound system is projected to the subspace that corresponds to the observed state and the vector representing the state is renormalized to the unit length. An observable describes a subspace for some dimensions with a special case of one dimension.
The starting point of this research is a representation of a quantum particle according to the Schrodinger equation of the conventional quantum mechanics. In this representation, a quantum particle is described by a wave packet in the coordinate space and the conjugated wave packet in the momentum space. The problem is that while in the coordinate space the group velocity is in agreement with one of the Hamilton equations, the group velocity in the momentum space is in contradiction with the other Hamilton equation - a minus sign is missing. Group velocities in agreement with the Hamilton equations are obtained only when in the time dependent phase of a quantum particle wave packet, instead of the Hamiltonian coming from the conventional Schrodinger equation, the Lagrangian is considered. This suggests us to consider the relativistic Lagrangian in the time dependent phase. In this way, the conventional relativistic principle of invariance of the time-space interval gets the more physically understandable form of the invariance of the time dependent phase of a quantum particle - the time dependent phase of a quantum particle is the same in any system of coordinates. Based on the relativistic time dependent phase invariance of a quantum particle, from the group velocities of this particle the relativistic kinematics and dynamics are obtained. The interaction with an electromagnetic field is described by a modification of the time dependent phase with a scalar potential conjugated to time and a vector potential conjugated to the space coordinates. In this paper, we find that, according to the formalism of the general relativity, any matter element in a field of forces is accelerated only perpendicularly to its velocity. This means that the matter propagation of a quantum particle can be conceived in planes perpendicular to velocity, while the mater distribution can be considered in a Fourier representation - quantum waves. We study the quantum particle dynamics in gravitational waves and derive the graviton spin. We consider a quantum particle in electromagnetic field and obtain a Schrödinger-Dirac-type equation, with additional terms describing the velocity dependence of the particle dynamics.
Standard Mechanics (SQM) is the most widely accepted route starting from the common “main road” provided by de Broglie’s and Schrodinger’s discovery of matter waves and of their eigen-functions and eigen-values. Another route is offered by Bohm’s Mechanics, able to reproduce the same results of SQM, while interpreting the streamlines of probability current density as a set of quantum trajectories”. We exploit here a further and somewhat different route, based on the fact that the stationary Schrodinger equation (as well as any other Helmholtz-like equation) may be treated, bypassing any kind of quasi-optical approximation, in terms of exact trajectories, coupled and guided by a stationary, energy dependent function (which we call “Wave Potential”) encoded in the structure itself of Helmholtz-like equations and acting normally to the relevant particle momentum. The basic property of the Wave Potential is therefore to leave the particle energy unchanged: a property which cannot be shared (in spite of its formal analogy) by the time-dependent Quantum Potential” of the Bohmian theory, involving the entire spectrum of possible eigen-energies. This property turns out to allow the numerical computation of the particle trajectories in stationary external force fields, and to show that all diffractive processes consist of energy-preserving exchanges between the longitudinal and transverse momentum components of each single particle. We compute and discuss the trajectories of particles moving, under the guiding rule of the Wave Potential, in many different force-fields, such as a constant field and the ones due to a potential barrier, a potential step and a focalizing potential, respectively. The very existence of these exact, point-particle, trajectory-based solutions appears to reserve the uncertainty relations to wave-packet particle representations.
Bohm theory is a formulation of Quantum Mechanics that characterises the state of a quantum system according to both the wave function, as in the conventional formulation, and the coordinates (positions) of all the particles that evolve in time drawing quantum continuous trajectories. Furthermore, a statistical ensemble of all the possible trajectories, raising from the impossibility to know the initial position of all the particles, establishes the exact correspondence with the traditional Quantum Mechanics. From a computational point of view, Bohm theory has found many applications in Chemical Physics especially to develop new methodologies for solving the Schrödinger equation and to address semi-classical approximations of Quantum Mechanics. From a theoretical point of view, the most appealing feature of Bohm theory is its capability to supply a conceptual map between the quantum formalism and our representation of what a chemical system is. Chemical systems are composed of molecules, but the same idea of molecule requires a specific arrangement in the space of particles, i.e., the nuclei of the atoms. The statistical description of conventional Quantum Mechanics on the basis of wave function alone is insufficient to establish a clear correspondence with such a picture of molecules. Indeed, chemists employ usually Classical Mechanics in order to overcome this drawback of the standard quantum theory. On the other hand, if the particles position is included in the quantum formalism, as Bohm theory does, the map can be defined in a self-consistent way. In other words, Bohm theory appears to be the suitable quantum framework to represent molecules and their motion. The chemical representation of molecular systems finds a natural correspondence with a single Bohm trajectory, since it is always implicitly assumed that molecular components have specific spatial position independently of our knowledge about it. Consequently, we develop a quantum method whose fundamental assumption is that a single Bohm trajectory, i.e., a quantum molecular trajectory, describes the molecular systems and the molecular motion correctly. First of all, we examine the correspondence between a single Bohm trajectory and the conventional Quantum Mechanics, without using the ensemble of trajectories. We verify that such a correspondence exists through numerical simulations and we prove formally that the statistical properties of a single Bohm trajectory explain the probabilistic description of Quantum Mechanics. Once the consistency of this original approach has been established, we investigate the predicted properties. For instance, we take into account the constants of motion (such as the energy) corresponding to the time evolution of the coordinates and the behaviour of simple chemical systems, e.g., the vibrational motion of single molecules interacting with a resonant field. In this way, unexpected features of the molecular motion are found. Secondly, we tackle the challenge of describing many components systems (like the chemical systems in ordinary conditions). As a matter of fact, the computation of the Bohm trajectory and of the wave function is extremely demanding. However, the statistical properties of the Bohm trajectory allow the derivation of stochastic theories for examining the dynamics of open quantum systems, i.e., few molecules (or few degrees of freedom) interacting with their environment (the other molecules). One of the developed stochastic methods correlates the dynamics of the reduced density matrix, for the degrees of freedom of interest, to the evolution of the corresponding Bohm coordinates. In other words, the Bohm equation, determining the set of all the particles velocities according to the full wave function, is replaced with a stochastic one that approximates the velocity of a subset of coordinates according to the reduced density matrix. In such a way, the quantum fluctuations induced by the environment are taken into account. The advantage of this method concerns its capability of describing quantum systems, including open quantum systems, in terms of a quantum trajectory. This could allow the understanding of the molecular motion during a spectroscopical experiment. The possibility of investigating reactive systems, such as conformational changes, is particularly interesting. As a matter of fact, chemical reactions can be completely characterised only through the particles motion and we define the suit- able quantum methodology providing a self-consistent description of the molecular motion.
In classical physics, the ‘state’ of a particle, at any particular time, is taken to involve a definite position in space and a definite motion; and the state of a system of particles is taken to involve a definite position in space and a definite motion for each of the particles. The situation in relation to quantum mechanics is completely different. As in classical physics, calculations can be made concerning the position and motion of a particle. However, this representation is not by means of symbols for scalar or vector quantities: it is by a more complex mathematical object. This quantum state does not indicate or represent position or motion in any direct way: what it does in substance is to enable calculation of the probability of the particle in question being found to have a position or momentum if an appropriate measurement is made.