For a long time, it was believed that the Ginzburg-Landau formalism was able to classify all different types of phase transitions. This view changed with the discovery of the quantum Hall effect and topological insulators. Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although topological insulators are well understood by now, a thermodynamic description of their behavior remained elusive, firstly because the edges are lost in the thermodynamic limit, when the system size goes to infinity, and secondly because topological quantum field theories involve non-local order parameters, and hence cannot be captured by the conventional Ginzburg-Landau formalism. Recently, this challenge has been overcome: by using Hill thermodynamics to describe the paradigmatic Bernevig-Hughes-Zhang model in two dimensions, it has been shown that at the topological phase change the thermodynamic potential does not scale extensively due to the boundary effects.\n\nHere, we extend this thermodynamic approach firstly to the Kitaev chain in one-dimension and then to different topological models in various dimensions (the Su-Schrieffer-Heeger model in one dimension, the Kane-Mele model in two dimensions and the Bernevig-Hughes-Zhang model in three dimensions) at zero temperature. Surprisingly, we find that all these models exhibit the same universal behavior in the order of the topological-phase transition, which depends on the dimensionality of the system. Next, we use this thermodynamic approach to describe topological phases at finite-temperatures. We calculate the entropy and heat capacity for the Kitaev chain and verify its behavior in comparison with conformal field theory. Furthermore, we extend the topological phase transition to finite-temperatures, by numerically deriving the topological phase diagram for the bulk of the system, and show that it displays a good agreement with the one calculated analytically from the Uhlmann phase. Finally, we calculate measurable quantities such as the density of states and the heat capacity for different topological insulators. Our work reveals unexpected universalities and opens the path to a thermodynamic description of systems with a non-local order parameter, provided that nonlinear terms are appropriately taken into account for the thermodynamic extensive variables.
For a long time, it was believed that the Ginzburg-Landau formalism was able to classify all different types of phase transitions. This view changed with the discovery of the quantum Hall effect and topological insulators. Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although topological insulators are well understood by now, a thermodynamic description of their behavior remained elusive, firstly because the edges are lost in the thermodynamic limit, when the system size goes to infinity, and secondly because topological quantum field theories involve non-local order parameters, and hence cannot be captured by the conventional Ginzburg-Landau formalism. Recently, this challenge has been overcome: by using Hill thermodynamics to describe the paradigmatic Bernevig-Hughes-Zhang model in two dimensions, it has been shown that at the topological phase change the thermodynamic potential does not scale extensively due to the boundary effects.\n\nHere, we extend this thermodynamic approach firstly to the Kitaev chain in one-dimension and then to different topological models in various dimensions (the Su-Schrieffer-Heeger model in one dimension, the Kane-Mele model in two dimensions and the Bernevig-Hughes-Zhang model in three dimensions) at zero temperature. Surprisingly, we find that all these models exhibit the same universal behavior in the order of the topological-phase transition, which depends on the dimensionality of the system. Next, we use this thermodynamic approach to describe topological phases at finite-temperatures. We calculate the entropy and heat capacity for the Kitaev chain and verify its behavior in comparison with conformal field theory. Furthermore, we extend the topological phase transition to finite-temperatures, by numerically deriving the topological phase diagram for the bulk of the system, and show that it displays a good agreement with the one calculated analytically from the Uhlmann phase. Finally, we calculate measurable quantities such as the density of states and the heat capacity for different topological insulators. Our work reveals unexpected universalities and opens the path to a thermodynamic description of systems with a non-local order parameter, provided that nonlinear terms are appropriately taken into account for the thermodynamic extensive variables.
Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although they are well understood, a thermodynamic description of these materials remained elusive, firstly because the edges yield a non-extensive contribution to the thermodynamic potential, and secondly because topological field theories involve non-local order parameters, and cannot be captured by the Ginzburg-Landau formalism. Recently, this challenge has been overcome: by using Hill thermodynamics to describe the Bernevig-Hughes-Zhang model in two dimensions, it was shown that at the topological phase transition the thermodynamic potential does not scale extensively due to boundary effects. Here, we extend this approach to different topological models in various dimensions (the Kitaev chain and Su-Schrieffer-Heeger model in one dimension, the Kane-Mele model in two dimensions and the Bernevig-Hughes-Zhang model in three dimensions) at zero temperature. Surprisingly, all models exhibit the same universal behavior in the order of the topological-phase transition, depending on the dimension. Moreover, we derive the topological phase diagram at finite temperature using this thermodynamic description, and show that it displays a good agreement with the one calculated from the Uhlmann phase. Our work reveals unexpected universalities and opens the path to a thermodynamic description of systems with a non-local order parameter.
Topological phases of matter are purely quantum mechanical and have no classical analogue. Most phases in nature can be classified and studied classically through the concept of symmetry breaking and its theoretical description, Landau-Ginzburg field theory. In contrast to the general wisdom of Landau-Ginzburg field theory, the topological phases share the same symmetry as a trivial insulator and still are different phases. Having gapped spectrum in bulk, they support a metallic edge excition robust against symmetry-respecting perturbation or an emergent fractional excitation in bulk. Following after fractional quantum Hall fluids, many topologically orderd phases, such as spin liquids and topological insulators, have been found and studied. Spin liquids are disordered phases of frustrated antiferromagnets and do not freeze and order even at the lowest temperature. They support an electrically neutral spin-1/2 excitation, which does not exist in a microscopic scale, with emergent dynamical gauge field in bulk and do not have an adiabatic path to a trivial paramagnet phase. The topological insulators are time-reversal symmetric band insulators which cannot evolve smoothly into a trivial insulator with the symmetry, and they have been intensely studied theoretically and experimetally for the last decade. Though the topological insulators are inherently non-interacting systems, they have exotic gapless edge and surface states which demonstrate many interesting quantum phenomena such as fractionalization, axionic electromagnetism, and half quantum Hall effect. In this thesis, we study various quantum phenomena of the topological phases, mainly of the topological insulator and its close relatives in which the physics of spin liquids has been merged into. As they are intrinsically quantum many-body states, the quantum field theory is an invaluable tool to explore the venue of the phases and will be used thorougly in this work. First, we present a topological field theoretic description of the topological insulators and translational symmetric Z2 spin liquid. We demostrate that abelian BF theory is an effective field theory for the two and three dimensional topological insulators. We show that the phenomenologies of BF theory are consistent with those of the topological insulators such as gapless edge and surface excitations and response functions to external gauge field. The same form of the BF theory is also applicable to study the certain classes of Z2 spin liquids with the gapless edge states. We closely examine the possible gapless edge theory of the BF theory and the translational symmetric spin liquids, and we show that the effective BF theories capture the bulk properties as well as the gapless edge spectrum of the spin liquid. Also we discuss the zero-temperature phase diagram of a thin film three dimensional topological insulators with two competing mass terms: time-reversal symmetric exciton condensation and time-reversal symmetry breaking Zeeman effect. There are two phases, quantum spin Hall phase and quantum anomalous Hall phase, and both phases support fractional excitations. We derive an effective topological field theory for the fractional excitations and examine the origin of the fractional excitations. Next we consider the relatives of the topological insulators. First we discuss the proximate symmetry broken phases of topological Mott insulator, a U(1) spin liquid with fermionic spinons in the topological insulator state. The topologically non-trivial band structure of the spinon generates the axion term for the gauge field, and we show that the axion term changes the nature of the confined phase of the spin liquid. Contrast to the conventional confined phase which has only a bond order, the confined phase of the spin liquid is in general a coexisting phase of the two different orders : a current order and a bond order. We then consider another relative of the topological insulator: a bosonic symmetry protected topological phase in two dimensional space, with both PSU(N) and time reversal symmetry. We develop an effective field theory for the phase, which is a SU(N) principal chiral model with a theta-term, and reveal the physics of the topological phase in detail.Finally we consider a topological semimetal, namely a Weyl semimetal. We first demonstrate that the Weyl semimetal can be realized in the magnetically doped topological band insulators. We explicitly derive the low energy theory of Weyl points from the general continuum Hamiltonian and tight-binding model of the topological insulators. Then we study superconducting instabilities of doped Weyl semimetals. We consider a minimal model for a Weyl semimetal and study the superconducting instabilities induced by a short-ranged attractive interaction. With the interaction, we find two competing states: a fully gapped finite-momentum pairing state and a nodal even-parity pairing state. We show that, in a mean field approximateion, the finite-momentum pairing state wins energetically against the usual even-parity paired state. We also show that exotic modes are localized at the full and half quantum vortices of the finite-momentum pairing state.
Superfluids and superconductors can be either fully gapped or gapless with nodal structures in momentum space. Both the gapped and nodal phases can be topologically protected and possess nontrivial topological invariants. Topological quantum phase transitions exist at zero temperature between different gapped phases or between gapped and nodal phases. These phase transitions can be driven by chemical potential and/or spin exchange fields. The two phases separated by the phase transition can have the same local order but differ in global topology. Thus, these topological quantum phase transitions cannot be described by the Landau paradigm of symmetry breaking. Although some aspects of these transitions, such as the change of topological invariants and gapless boundary states, have been discussed before, a complete theory of these transitions has yet to be developed. In this dissertation, we construct effective field theories to study the universality and thermodynamic signatures of these transitions. We find four different universality classes in superfluids and superconductors. Certain thermodynamic quantities, such as compressibility or spin susceptibility, change non-analytically across the transitions. For certain time-reversal symmetry breaking fields that lead to bulk phase transitions, there also exist topological phase transitions on the surface. All the topological phase transitions studied in this dissertation only exist at zero temperature. At finite temperature, different states are connected by smooth crossovers. There exists a quantum critical region at finite temperature near the quantum critical point (QCP). In this quantum critical region, thermodynamic quantities have universal scaling dependence on temperature dictated by the universality class of the QCP. We argue that these scaling properties can be used to probe and differentiate these QCPs. These bulk and surface topological quantum phase transitions are discussed in various concrete models, such as chiral and time-reversal invariant p-wave superfluids, topological superconductors of emergent Dirac fermions, and topological superconducting model of CuₓBi₂Se₃.
The growing field of topological orders has been extensively studied both form the communities of condensed matter and quantum simulation. However, very little is known about the fate of topological order in the presence of disturbing effects such as external noise or dissipation. In the first part of this thesis, we start by studying how the edge states of a topological insulator become unstable when interacting with thermal baths. Motivated by these results, we generalise the notion of Chern insulators from the well-known Hamiltonian case to Liouvillian dynamics. We achieve this goal by defining a new topological witness that is still related to the quantum Hall conductivity at finite temperature. The mixed character of edge states is also well captured by our formalism, and explicit models for topological insulators and dissipative channels are considered. Additionally, we find new topological phases that remain quantised at finite temperature. The construction is based on the Uhlmann phase, a geometric quantum phase defined for general density matrices. Using this new tool, we are able to characterise topological insulators and superconductors at finite temperature both in one and two spatial dimensions. From the experimental side, we propose a state-independent protocol to measure the topological Uhlmann phase in the context of quantum simulation. Symmetry-protected topological orders have traditionally emerged from shortrange interactions. It remains very much unknown what the role played by longrange interactions is, within the physics of these topological systems. In the second part of this thesis, we analyse how topological superconducting phases are affected by the inclusion of long-range couplings. Remarkably, we unveil new topological quasi-particles due to long-range interactions, that were absent in short-range models. We also study how topological invariants are modified by the presence of long-range effects. In the appendix section of the thesis, we explore new numerical methods for driven-dissipative phase transitions. We consider quantum systems with a dissipative term driving the system into a non-equilibrium steady state. The inclusion of short-range fluctuations out-of-equilibrium deeply modifies the shape of the phase-diagram, something never observed in equilibrium thermodynamics.
We demonstrate the existence of topological phase transitions in interacting, symmetry-protected quantum matter at finite temperatures. Using a combined numerical and analytical approach, we study a one-dimensional Su-Schrieffer-Heeger model with added Hubbard interactions, where no thermodynamic phase transition occurs at finite temperatures. The transition is signalled by a quantized, nonlocal bulk topological order parameter. It is driven by defects, which are enabled by the combination of interaction and thermal activation, with no counterpart in the noninteracting limit. The defects localize topological zero modes, which, when sufficiently abundant, cause the order parameter to vanish. This phenomenon, interpreted via bulk-boundary correspondence, reflects the loss of a topological edge mode at a well-defined critical temperature in the thermodynamic limit. Unlike zero-temperature topological transitions, these finite-temperature transitions lack thermodynamic signatures but remain observable in controlled quantum systems, such as ultracold fermionic atoms in optical lattices.
For decades, Landau’s theory of phase transition has provided a successful classification for quantum and classical states of matter based on their symmetry broken patterns, except for certain exotic quantum states such as the fractional quantum Hall (FQH) effect. However, such exotic phenomena are crucial for a complete understanding of the nature. This thesis explores new physical principles emerging from topology and topological states. First, we use an example to demonstrate Landau’s theory by studying a pair-density wave system, where the symmetry-breaking paradigm is applicable. It turns out that such a system exhibits the Kosterlitz-Thouless (KT) transition, a phase transition driven by the proliferation of topological defects, i.e. vortex-antivortex pairs. For topological systems, where symmetry broken pattern cannot be used as a classification tool, we prove a theorem that two gapped systems with non-vanishing ground-state overlap must be adiabatically connected, and thus are necessarily in the same topological phase. This theorem provides a simple and generic approach to classify topological band insulators/superconductors, without the needs to calculate any known or yet-to-known topological indices. Once the overlap is found nonzero, the two systems must be topologically identical. After presenting a generic proof, the theorem is also verified through calculating the overlap for several milestone topological band insulators and certain interacting systems. Such an overlap technique is then generalized to (2+1)-D strongly-interacting topological systems at fixed points, including both symmetry-protected topological (SPT) states and intrinsic topological states like FQH. For interacting topological states, the main challenge of utilizing wave-function overlaps to classify them lies in the famous Anderson orthogonality catastrophe (AOC), which states that two different many-body wave functions must have zero overlap in the thermodynamic limit. In this thesis, we found that wave-function overlaps indeed carry critical information about the topological nature of quantum states and this information can be extracted from the finite-size scaling of the overlaps. In the finite-size scaling analysis, we found a universal topological response term as a sub-leading contribution. This term depends on both the central charge of the corresponding conformal field theory (CFT) and the Euler characteristics of the underlying manifolds on which the system is defined. This term reveals a fundamental connection between ground-state overlaps and CFT’s. In addition, surprisingly, the overlap between an intrinsic topological state and a topologically trivial product state shows a decay faster than the exponential behavior expected via a typical AOC analysis. Such finite-size scaling behaviors could be utilized to theoretically detect the gapless edge modes, and to distinguish the topology of quantum states or serve as a signature of topological phase transitions. Possible generalization to higher dimensions and generic non-fixed-point topological systems is also discussed.