Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although they are well understood, a thermodynamic description of these materials remained elusive, firstly because the edges yield a non-extensive contribution to the thermodynamic potential, and secondly because topological field theories involve non-local order parameters, and cannot be captured by the Ginzburg-Landau formalism. Recently, this challenge has been overcome: by using Hill thermodynamics to describe the Bernevig-Hughes-Zhang model in two dimensions, it was shown that at the topological phase transition the thermodynamic potential does not scale extensively due to boundary effects. Here, we extend this approach to different topological models in various dimensions (the Kitaev chain and Su-Schrieffer-Heeger model in one dimension, the Kane-Mele model in two dimensions and the Bernevig-Hughes-Zhang model in three dimensions) at zero temperature. Surprisingly, all models exhibit the same universal behavior in the order of the topological-phase transition, depending on the dimension. Moreover, we derive the topological phase diagram at finite temperature using this thermodynamic description, and show that it displays a good agreement with the one calculated from the Uhlmann phase. Our work reveals unexpected universalities and opens the path to a thermodynamic description of systems with a non-local order parameter.
Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although they are well understood, a thermodynamic description of these materials remained elusive, firstly because the edges yield a non-extensive contribution to the thermodynamic potential, and secondly because topological field theories involve non-local order parameters, and cannot be captured by the Ginzburg-Landau formalism. Recently, this challenge has been overcome: by using Hill thermodynamics to describe the Bernevig-Hughes-Zhang model in two dimensions, it was shown that at the topological phase transition the thermodynamic potential does not scale extensively due to boundary effects. Here, we extend this approach to different topological models in various dimensions (the Kitaev chain and Su-Schrieffer-Heeger model in one dimension, the Kane-Mele model in two dimensions and the Bernevig-Hughes-Zhang model in three dimensions) at zero temperature. Surprisingly, all models exhibit the same universal behavior in the order of the topological-phase transition, depending on the dimension. Moreover, we derive the topological phase diagram at finite temperature using this thermodynamic description, and show that it displays a good agreement with the one calculated from the Uhlmann phase. Our work reveals unexpected universalities and opens the path to a thermodynamic description of systems with a non-local order parameter.
For a long time, it was believed that the Ginzburg-Landau formalism was able to classify all different types of phase transitions. This view changed with the discovery of the quantum Hall effect and topological insulators. Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although topological insulators are well understood by now, a thermodynamic description of their behavior remained elusive, firstly because the edges are lost in the thermodynamic limit, when the system size goes to infinity, and secondly because topological quantum field theories involve non-local order parameters, and hence cannot be captured by the conventional Ginzburg-Landau formalism. Recently, this challenge has been overcome: by using Hill thermodynamics to describe the paradigmatic Bernevig-Hughes-Zhang model in two dimensions, it has been shown that at the topological phase change the thermodynamic potential does not scale extensively due to the boundary effects.\n\nHere, we extend this thermodynamic approach firstly to the Kitaev chain in one-dimension and then to different topological models in various dimensions (the Su-Schrieffer-Heeger model in one dimension, the Kane-Mele model in two dimensions and the Bernevig-Hughes-Zhang model in three dimensions) at zero temperature. Surprisingly, we find that all these models exhibit the same universal behavior in the order of the topological-phase transition, which depends on the dimensionality of the system. Next, we use this thermodynamic approach to describe topological phases at finite-temperatures. We calculate the entropy and heat capacity for the Kitaev chain and verify its behavior in comparison with conformal field theory. Furthermore, we extend the topological phase transition to finite-temperatures, by numerically deriving the topological phase diagram for the bulk of the system, and show that it displays a good agreement with the one calculated analytically from the Uhlmann phase. Finally, we calculate measurable quantities such as the density of states and the heat capacity for different topological insulators. Our work reveals unexpected universalities and opens the path to a thermodynamic description of systems with a non-local order parameter, provided that nonlinear terms are appropriately taken into account for the thermodynamic extensive variables.
Superfluids and superconductors can be either fully gapped or gapless with nodal structures in momentum space. Both the gapped and nodal phases can be topologically protected and possess nontrivial topological invariants. Topological quantum phase transitions exist at zero temperature between different gapped phases or between gapped and nodal phases. These phase transitions can be driven by chemical potential and/or spin exchange fields. The two phases separated by the phase transition can have the same local order but differ in global topology. Thus, these topological quantum phase transitions cannot be described by the Landau paradigm of symmetry breaking. Although some aspects of these transitions, such as the change of topological invariants and gapless boundary states, have been discussed before, a complete theory of these transitions has yet to be developed. In this dissertation, we construct effective field theories to study the universality and thermodynamic signatures of these transitions. We find four different universality classes in superfluids and superconductors. Certain thermodynamic quantities, such as compressibility or spin susceptibility, change non-analytically across the transitions. For certain time-reversal symmetry breaking fields that lead to bulk phase transitions, there also exist topological phase transitions on the surface. All the topological phase transitions studied in this dissertation only exist at zero temperature. At finite temperature, different states are connected by smooth crossovers. There exists a quantum critical region at finite temperature near the quantum critical point (QCP). In this quantum critical region, thermodynamic quantities have universal scaling dependence on temperature dictated by the universality class of the QCP. We argue that these scaling properties can be used to probe and differentiate these QCPs. These bulk and surface topological quantum phase transitions are discussed in various concrete models, such as chiral and time-reversal invariant p-wave superfluids, topological superconductors of emergent Dirac fermions, and topological superconducting model of CuₓBi₂Se₃.
We demonstrate the existence of topological phase transitions in interacting, symmetry-protected quantum matter at finite temperatures. Using a combined numerical and analytical approach, we study a one-dimensional Su-Schrieffer-Heeger model with added Hubbard interactions, where no thermodynamic phase transition occurs at finite temperatures. The transition is signalled by a quantized, nonlocal bulk topological order parameter. It is driven by defects, which are enabled by the combination of interaction and thermal activation, with no counterpart in the noninteracting limit. The defects localize topological zero modes, which, when sufficiently abundant, cause the order parameter to vanish. This phenomenon, interpreted via bulk-boundary correspondence, reflects the loss of a topological edge mode at a well-defined critical temperature in the thermodynamic limit. Unlike zero-temperature topological transitions, these finite-temperature transitions lack thermodynamic signatures but remain observable in controlled quantum systems, such as ultracold fermionic atoms in optical lattices.
The topological order of Dirac models in any dimension and symmetry class can be mapped to lattice sites by a universal topological marker. From the topological operator that extracts this marker, one can further define a nonlocal marker that detects topological phase transitions. Several prototype models such as the Su-Schrieffer-Heeger model, Majorana chain, Chern insulator, Bernevig-Hughes-Zhang model, chiral and helical p-wave superconductors, three-dimensional time-reversal symmetric topological insulators, among many others, are employed to demonstrate the ubiquity of these markers.
We have applied the recently developed theory of topological Uhlmann numbers to a representative model of a topological insulator in two dimensions, the Qi–Wu–Zhang model. We have found a stable symmetry-protected topological phase under external thermal fluctuations in two dimensions. A complete phase diagram for this model is computed as a function of temperature and coupling constants in the original Hamiltonian. It shows the appearance of large stable phases of matter with topological properties compatible with thermal fluctuations or external noise and the existence of critical lines separating abruptly trivial phases from topological phases. These novel critical temperatures represent thermal topological phase transitions. The initial part of the paper comprises a self-contained explanation of the Uhlmann geometric phase needed to understand the topological properties that it may acquire when applied to topological insulators and superconductors.
The growing field of topological orders has been extensively studied both form the communities of condensed matter and quantum simulation. However, very little is known about the fate of topological order in the presence of disturbing effects such as external noise or dissipation. In the first part of this thesis, we start by studying how the edge states of a topological insulator become unstable when interacting with thermal baths. Motivated by these results, we generalise the notion of Chern insulators from the well-known Hamiltonian case to Liouvillian dynamics. We achieve this goal by defining a new topological witness that is still related to the quantum Hall conductivity at finite temperature. The mixed character of edge states is also well captured by our formalism, and explicit models for topological insulators and dissipative channels are considered. Additionally, we find new topological phases that remain quantised at finite temperature. The construction is based on the Uhlmann phase, a geometric quantum phase defined for general density matrices. Using this new tool, we are able to characterise topological insulators and superconductors at finite temperature both in one and two spatial dimensions. From the experimental side, we propose a state-independent protocol to measure the topological Uhlmann phase in the context of quantum simulation. Symmetry-protected topological orders have traditionally emerged from shortrange interactions. It remains very much unknown what the role played by longrange interactions is, within the physics of these topological systems. In the second part of this thesis, we analyse how topological superconducting phases are affected by the inclusion of long-range couplings. Remarkably, we unveil new topological quasi-particles due to long-range interactions, that were absent in short-range models. We also study how topological invariants are modified by the presence of long-range effects. In the appendix section of the thesis, we explore new numerical methods for driven-dissipative phase transitions. We consider quantum systems with a dissipative term driving the system into a non-equilibrium steady state. The inclusion of short-range fluctuations out-of-equilibrium deeply modifies the shape of the phase-diagram, something never observed in equilibrium thermodynamics.