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Entropy

Maximum Entropy Models for Quantum Systems

Andrzej Łuczak, Hanna Podsȩdkowska, Michał T. Seweryn

Published Dec 22, 2016• 192 citations
Publisher

Abstract

We show that for a finite von Neumann algebra, the states that maximise Segal’s entropy with a given energy level are Gibbs states. This is a counterpart of the classical result for the algebra of all bounded linear operators on a Hilbert space and von Neumann entropy.
DOI
10.3390/e19010001

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Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a minimality property of the von Neumann entropy of a density matrix with respect to its possible decompositions into pure states, we give a purely algebraic definition of entropy for states of an algebra of observables, thus solving the above ambiguity. The entropy so-defined satisfies all the desirable thermodynamic properties and reduces to the von Neumann entropy in the quantum mechanical case. Moreover, it can be shown to be equal to the von Neumann entropy of the unique representative density matrix belonging to the operator algebra of a multiplicity-free Hilbert-space representation.
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The problem of constructing models for the statistical dynamics of finite-level quantum mechanical systems is considered. The maximum entropy principle formulated by E.T. Jaynes in 1957 and asserting that the entropy of any physical system increases until it attains its maximum value under constraints imposed by other physical laws is applied. In accordance with this principle, the von Neumann entropy is taken for the objective function; a dynamical equation describing the evolution of the density operator in finite-level systems is derived by using the speed gradient principle. In this case, physical constraints are the mass conservation law and the energy conservation law. The stability of the equilibrium points of the system thus obtained is investigated. By using LaSalle’s theorem, it is shown that the density function tends to a Gibbs distribution, under which the entropy attains its maximum. The method is exemplified by analyzing a finite system of identical particles distributed between cells. Results of numerical simulation are presented.
We study an entropy measure for quantum systems that generalizes the von Neumann entropy as well as its classical counterpart, the Gibbs or Shannon entropy. The entropy measure is based on hypothesis testing and has an elegant formulation as a semidefinite program, a type of convex optimization. After establishing a few basic properties, we prove upper and lower bounds in terms of the smooth entropies, a family of entropy measures that is used to characterize a wide range of operational quantities. From the formulation as a semidefinite program, we also prove a result on decomposition of hypothesis tests, which leads to a chain rule for the entropy.