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Journal of Physics Conference Series

Quantum Decoherence and Thermalization at Finite Temperatures of Non-Degenerate Spin Systems via Small Spin Environments

M. A. Novotny, Fengping Jin, Hans A. De Raedt, Kristel F. L. Michielsen

Published Sep 1, 2016• 1 citation
Publisher

Abstract

We study the case of a small quantum spin system S with a non-degenerate groundstate coupled to a small quantum spin bath. Finite temperature measures for both quantum decoherence and thermalization are studied. The computational results, obtained from exact diagonalization, compare well with a recent perturbation theory prediction, even when the system and bath are of comparable sizes.

DOI
10.1088/1742-6596/750/1/012021

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In this review, we discuss the decoherence and thermalization of a quantum spin system interacting with a spin bath environment, by numerically solving the time-dependent Schrödinger equation of the whole system. The effects of the topologic structure and the initial state of the environment on the decoherence of the two-spin and many-spin system are discussed. The role of different spin-spin coupling is considered. We show under which conditions the environment drives the reduced density matrix of the system to a fully decoherent state, and how the diagonal elements of the reduced density matrix approach those expected for the system in the microcanonical or canonical ensemble, depending on the character of the additional integrals of motion. Our demonstration does not rely on time-averaging of observables nor does it assume that the coupling between system and bath is weak. Our findings show that the microcanonical distribution (in each eigenenergy subspace) and canonical ensemble are states that may result from pure quantum dynamics, suggesting that quantum mechanics may be regarded as the foundation of quantum statistical mechanics. Furthermore, our numerical results show that a fully decoherent quantum system prefers to stay in an equilibrium state with a maximum entropy, indicating the validity of the second law of thermodynamics in the decoherence process.
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We present an exactly solvable model to study the role of the system-bath coupling for the generalized canonical thermalization, which reduces almost all the pure states of the ``universe'' (formed by a system SSS plus its surrounding heat bath BBB) to a canonical equilibrium state of SSS. It is found that, for the overwhelming majority of the ``universe'' states (they are entangled at least), the diagonal canonical typicality remains robust with respect to finite interactions between SSS and BBB. Particularly, a decoherence mechanism is utilized here to account for the vanishing of the off-diagonal elements of the reduced density matrix of SSS. The nonvanishing off-diagonal elements due to the finite size of the bath and the stronger system-bath interaction might offer more to quantum thermalization.
We consider the buildup and decay of two-spin entanglement through phase interactions in a finite environment of surrounding spins, as realized in quantum computing platforms based on arrays of atoms, molecules, or nitrogen vacancy centers. The non-Markovian dephasing caused by the spin environment through Ising-type phase interactions can be solved exactly and compared to an effective Markovian treatment based on collision models. In a first case study on a dynamic lattice of randomly hopping spins, we find that non-Markovianity boosts the dephasing rate caused by nearest-neighbor interactions with the surroundings, degrading the maximum achievable entanglement. However, we also demonstrate that additional three-body interactions can mitigate this degradation, and that randomly timed reset operations performed on the two-spin system can help sustain a finite average amount of steady-state entanglement. In a second case study based on a model nuclear magnetic resonance system, we elucidate the role of bath correlations at finite temperature on non-Markovian dephasing. They speed up the dephasing at low temperatures while slowing it down at high temperatures, compared to an uncorrelated bath, which is related to the number of thermally accessible spin configurations with and without interactions.
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