Chapter 4 The Quantum Plane 4.1 Position and momentum We now have the necessary machinery to treat what is probably the most fundamental example in quantum mechanics: the one-dimensional particle. Its classical analog was mentioned in Section 1.1, and there we pointed out that the phase space of this classical system can be identied with the real plane R . The phase space of the corresponding quantum system is modelled on the Hilbert space L (R), and this space, together with some associated structure, plays the role of a \\quantum" plane. As we will see in this and later chapters, the complex, topological, measure theoretic, metric, and dierentiable structures of the ordinary plane all have quantum analogs. In this section we introduce \\coordinates" and \\translations" on the quantum plane.
Chapter 4 The Quantum Plane 4.1 Position and momentum We now have the necessary machinery to treat what is probably the most fundamental example in quantum mechanics: the one-dimensional particle. Its classical analog was mentioned in Section 1.1, and there we pointed out that the phase space of this classical system can be identied with the real plane R . The phase space of the corresponding quantum system is modelled on the Hilbert space L (R), and this space, together with some associated structure, plays the role of a \quantum" plane. As we will see in this and later chapters, the complex, topological, measure theoretic, metric, and dierentiable structures of the ordinary plane all have quantum analogs. In this section we introduce \coordinates" and \translations" on the quantum plane.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation: There are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be the subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. This latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system.
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.
The wave function Before beginning to describe the quantum theory of measurement, we shall discuss briefly the main concepts of quantum mechanics. Readers familiar with quantum mechanics may skip this section and go on to section 2.2. Consider, as a pedagogical aid, a classical particle that can move only along the x direction. For example, it might be a bead on an infinite needle. If we know at any moment of time the values of two numbers, the particle's position and momentum, then we can compute from them all other features of the particle's motion: the forces acting on it, its resulting acceleration, etc. In other words, this pair of numbers, the position and momentum, completely define the state of the classical particle at the chosen moment of time. Similarly, for three-dimensional motion the state is defined by six numbers: the three spatial coordinates x, y, z and the three corresponding components of the momentum p x , p y , p z . A quantum object, with its dual particle-like and wave-like properties, is much more complex than a classical particle. Interferometric experiments (chapter I) show that the object can be spread out over some region of space, or for the bead on a needle, over an interval of x .
Abstract Chapter 9 begins laying a foundation for quantum statistical mechanics with a discussion of relevant topics in quantum mechanics. The fundamental postulates of quantum mechanics are reviewed, beginning with the definition of a quantum state and the introduction of the concept of a state vector in a Hilbert space. The representation of observables as Hermitian operators on Hilbert space vectors is described; it is shown that the eigenvalues of Hermitian operators are real and, therefore, constitute possible outcomes of measurements made on these observables. The notions compatible and non-compatible observables and implication for the measurement problem are presented. The time-dependent Schrödinger equation is introduced as generating the time-evolution of the state vector, and it is shown how to cast the Schrödinger equation into a coordinate basis to yield the wave equation of quantum mechanics. Coordinate and momentum bases and their properties are desribed. Several analytically solvable quantum systems are presented as illustrative examples. The chapter concludes with a discussion of spin and the treatment identical particles
The Hilbert-Space Description By the static description of a physical system we mean the rules that assign specified mathematical objects to the states and to the physical quantities of the system, and the prescriptions for calculating the probability distribution of the possible values of every physical quantity when the state of the system is given. In the usual Hilbert-space formulation of quantum mechanics, to each physical system is attached a separable Hilbert space (generally infinite-dimensional) over the complex field. To every physical quantity is associated a linear, self-adjoint, not necessarily bounded operator on. If one deals with a strictly quantum system, then the converse is also generally assumed: every self-adjoint operator on represents some physical quan- tity. The restriction “strictly quantum” is necessary: if the system retains some nonquantum (i.e. classical) feature, so that it requires the algorithm of so-called “superselection rules” (see Chapter 5), then there are self-adjoint operators on that do not represent physical quantities. It should also be stressed that even in the strictly quantum case, most of the self-adjoint operators actually do not represent “interesting” physical quantities: only a few of them represent physical quantities that are useful and meaningful for the description of the physical system (e.g., energy, momentum, position, angular momentum). Therefore, by asserting that every self-adjoint operator on corresponds to some physical quantity we mean there is no a priori impossibility of devising such a correspondence, but we do not claim that this correspondence is present in the real work of experimental physics.