The Hilbert-Space Description By the static description of a physical system we mean the rules that assign specified mathematical objects to the states and to the physical quantities of the system, and the prescriptions for calculating the probability distribution of the possible values of every physical quantity when the state of the system is given. In the usual Hilbert-space formulation of quantum mechanics, to each physical system is attached a separable Hilbert space (generally infinite-dimensional) over the complex field. To every physical quantity is associated a linear, self-adjoint, not necessarily bounded operator on. If one deals with a strictly quantum system, then the converse is also generally assumed: every self-adjoint operator on represents some physical quan- tity. The restriction “strictly quantum” is necessary: if the system retains some nonquantum (i.e. classical) feature, so that it requires the algorithm of so-called “superselection rules” (see Chapter 5), then there are self-adjoint operators on that do not represent physical quantities. It should also be stressed that even in the strictly quantum case, most of the self-adjoint operators actually do not represent “interesting” physical quantities: only a few of them represent physical quantities that are useful and meaningful for the description of the physical system (e.g., energy, momentum, position, angular momentum). Therefore, by asserting that every self-adjoint operator on corresponds to some physical quantity we mean there is no a priori impossibility of devising such a correspondence, but we do not claim that this correspondence is present in the real work of experimental physics.
The Hilbert-Space Description By the static description of a physical system we mean the rules that assign specified mathematical objects to the states and to the physical quantities of the system, and the prescriptions for calculating the probability distribution of the possible values of every physical quantity when the state of the system is given. In the usual Hilbert-space formulation of quantum mechanics, to each physical system is attached a separable Hilbert space (generally infinite-dimensional) over the complex field. To every physical quantity is associated a linear, self-adjoint, not necessarily bounded operator on. If one deals with a strictly quantum system, then the converse is also generally assumed: every self-adjoint operator on represents some physical quan- tity. The restriction “strictly quantum” is necessary: if the system retains some nonquantum (i.e. classical) feature, so that it requires the algorithm of so-called “superselection rules” (see Chapter 5), then there are self-adjoint operators on that do not represent physical quantities. It should also be stressed that even in the strictly quantum case, most of the self-adjoint operators actually do not represent “interesting” physical quantities: only a few of them represent physical quantities that are useful and meaningful for the description of the physical system (e.g., energy, momentum, position, angular momentum). Therefore, by asserting that every self-adjoint operator on corresponds to some physical quantity we mean there is no a priori impossibility of devising such a correspondence, but we do not claim that this correspondence is present in the real work of experimental physics.
Operators represent physically observable quantities, as discussed in Section 2.5. The structure and property of operators depend on the nature of the degree of freedom; operators act on the state space and in particular on the state vector of a given degree of freedom. The significance of operators in the interpretation of quantum mechanics has been discussed in Baaquie (2013e). The operators discussed in this chapter are mostly based on the continuous degree of freedom, which is analyzed in Section 3.1. Hermitian operators represent physically observable properties of a degree of freedom and their mathematical properties are defined in Section 3.3. The coordinate and momentum operators are the leading exemplar of a pair of noncommuting Hermitian operators and these are studied in some detail in Section 3.4. The Weyl operators yield, as in Section 3.5, a finite-dimensional example of the shift and scaling operators; Section 3.8 provides a unitary representation of the coordinate and momentum operators. The term self-adjoint operator is used for Hermitian operators when there is a need to emphasize the importance of the domain of the Hilbert space on which the operators act – a topic not usually discussed in most books on quantum mechanics. Sections 3.10 and 3.11 discuss the concept of self-adjoint operators, in particular the crucial role played by the domain for realizing the property of self-adjointness. It is shown in Section 3.12 how the requirement of self-adjointness yields a non-trivial extension of Hamiltonians that include singular interactions.
We present in this paper a set of postulates for a physical system and deduce from these the main general features of the quantum theory of stationary states. Our theory is strictly operational in the sense that only the observables of the physical system are involved in the postulates. The collection of all bounded self-adj oint operators on a Hilbert space, which has previously been used as a mathematical model for the observables in quantum mechanics, satisfy the postulates, as do a variety of considerably more general mathematical structures. We show that for any two observables there exists a pure state of the system (this term being defined essentially as done by von Neumann and Weyl) in which they have different (expectation) values. Each observable has a spectral resolution, and a state of the system induces, in a natural way, a probability distribution on the range of spectral values of each observable. A number of observables are simultaneously observable if and only if they commute (although the product of two observables is not defined in general, a reasonable notion of commutativity can be introduced). Inasmuch as Hilbert space plays no role in our theory, our proofs are necessarily of a different character from the proofs of these results for the case of the system of all bounded selfadjoint operators. Actually, Hilbert space appears to be somewhat inadequate as a state space even for the latter system, in that there exist pure states of the system which cannot be represented in the usual way by rays of the Hilbert space. The postulates are partly algebraic and partly metric. The algebraic postulates require essentially that an observable can be multiplied by real numbers and raised to integral powers, and that any two observables can be added. It is assumed that the usual algebraic laws are satisfied so that (1) the observables can be treated like the elements of a linear space, and (2) the usual rules for dealing with polynomials in one variable with real coefficients remain valid when the variable is replaced by an observable. It is not assumed that two observables have a product. The metric postulates require that for each observable there be defined a kind of maximum numerical value, which plays the part of a norm, and has various properties in accord with its physical significance. While this norm is quite essential to the development of the theory, an interesting consequence of the theory is that the norm can be (uniquely) defined in a purely algebraic fashion. This shows that the objective features of a physical system,-the spectral values and probability distributions of the observables, and the pure states,-are completely determined by the algebra of observables, i.e., by the rules for addition, scalar multiplication, and powers, of observables.
Abstract The object of this book is to present the new quantum mechanics in a unified representation which, so far as it is possible and useful, is mathematically rigorous [A]presentation of the mathematical tools necessary for the purposes of this theory will be given, i.e., a theory of Hilbert spaces and the so-called Hermitian [or self-adjoint] operators. To this end, an accurate introduction to unbounded operators is also necessary; that is, an extension of the theory beyond its classical limits (developed by Hilbert and E. Hellinger, F. Riesz, E. Schmidt, 0. Toeplitz). The following may be said regarding the method employed in this type of treatment: as a rule, calculations should be performed with the operators themselves (which represent physical quantities) and not with the matrices, which, after the introduction of a (special and arbitrary) coordinate system in Hilbert space, result from them. This “coordinate free” (i.e., invariant) method, with its strongly geometric language, possesses noticeable formal advantages.
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.
The purpose of the paper is to study the foundations of the main axioms of Quantum Mechanics. From a general study of the mathematical properties of the models used in Physics to represent systems, we prove that the states of a system can be represented in a Hilbert space, that a self-adjoint operator is associated to any observable, that the result of a measure must be the eigen value of the operator and appear with the usual probability. Furthermore an equivalent of the Wigner's theorem holds, which leads to the Schr{ö}dinger equation. These results are based on well known mathematics, and do not involve any specific hypothesis in Physics. They validate and explain the methods currently used, which are made simpler and safer, and open new developments. In the third edition of this paper developments have been added about the estimation of physical anomalies.
Vectors and operators in a Hilbert space are independent quantities and there is no obvious link between them. The mathematical description of the states and observables of a quantum system given by Postulates 25.1(PS) and 26.1(OV) in terms of vectors and operators does not tell us how a given state would determine the value of an observable. Physically the relationship between states and observables is about how the measurable values of an observable is related to a state. This relationship should lead to the quantum properties QMP5.3(1) to QMP5.3(3). First we must know how a state can give rise to a probability distribution of measurable values of an observable. This would require a prescription to relate a unit vector to the spectrum of selfadjoint operators. The discussion in Chapter 22 tells us how to obtain such a prescription. Because of the intricacy of the relationship both physically and mathematically we shall set out the relationship for discrete and continuous observables separately.