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Cambridge University Press eBooks

Standard Treatment of Angular Momentum in Quantum Mechanics

Lawrence C. Biedenharn, James D. Louck, Peter A. Carruthers

Published Dec 28, 1984• 2 citations
Publisher
DOI
10.1017/cbo9780511759888.006

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The approach to quantum mechanics which we have used to derive the matrix treatment of spin from first principles is now employed to treat systems of compounded angular momentum. A general treatment is first given, which is then applied to the concrete cases of a spin-0 and a spin-1 system obtained by adding the spins of two spin-1/2 systems. Thus the probability amplitudes for measurements on the systems are derived, as well as the matrix vectors and operators corresponding to the systems. The matrix operators and states obtained are different from the standard forms and are much more generalized. The new results are applied to the case of joint measurements on the subsystems of such a system; this is a problem that has been made very topical by the high level of interest in the foundations of quantum mechanics. As a consequence of the insights arising from this treatment, we show that the Clebsch-Gordan coefficients are amenable to generalization, and we give the generalized forms for these cases.
In nonrelativistic quantum mechanics, the total (i.e. orbital plus spin) angular momentum of a charged particle with spin that moves in a Coulomb plus spin–orbit-coupling potential is conserved. In a classical nonrelativistic treatment of this problem, in which the Lagrange equations determine the orbital motion and the Thomas equation yields the rate of change of the spin, the particle's total angular momentum in which the orbital angular momentum is defined in terms of the kinetic momentum is generally not conserved. However, a generalized total angular momentum, in which the orbital part is defined in terms of the canonical momentum, is conserved. This illustrates the fact that the quantum-mechanical operator of momentum corresponds to the canonical momentum of classical mechanics.
The magnitude of the angular momentum (J2J^2J2) in quantum mechanics is larger than expected from a classical model. We explain this deviation in terms of quantum fluctuations. A standard quantum mechanical calculation gives the correct interpretation of the components of the angular momentum in the vector model in terms of projections and fluctuations. We show that the addition of angular momentum in quantum mechanics gives results consistent with the classical intuition in this vector model.