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Taylor & Francis eBooks

Approximation Methods

Donald Gary Swanson

Published Aug 9, 2006• 1 citation
Publisher

Abstract

The concept and much of the mathematical treatment of orbital angular momentum was treated in Chapter 3. An unexpected result from that treatment is that using the result of Equation (3.41) along with the result of Equation (3.48), we find that mT −mB = 2` = n , (4.1) so ` is either an integer or a half integer! The integers correspond to orbital angular momentum, while the half-integer values correspond to intrinsic angular momentum, or spin angular momentum. There is no classical model for spin angular momentum, but the most fundamental particles (electrons, quarks, protons, and neutrons) all exhibit this type of intrinsic angular momentum.

DOI
10.1201/b15900-6

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The concept and much of the mathematical treatment of orbital angular momentum was treated in Chapter 3. An unexpected result from that treatment is that using the result of Equation (3.41) along with the result of Equation (3.48), we find that mT −mB = 2= n , (4.1) so is either an integer or a half integer! The integers correspond to orbital angular momentum, while the half-integer values correspond to intrinsic angular momentum, or spin angular momentum. There is no classical model for spin angular momentum, but the most fundamental particles (electrons, quarks, protons, and neutrons) all exhibit this type of intrinsic angular momentum.
Unlike orbital angular momentum, the total spin of a system can be integral or half-integral. Fermions such as electrons, positrons, neutrinos, and quarks possess intrinsic angular momentum or spin with a measurable value of ±1/2 (in units of ħ). Composite particles such as protons and neutrons also have measurable spin of ±1/2 and atomic nuclei can have half-integral spin values (1/2, 3/2, 5/2, …). The “spinor” function for half-integral spin is unusual in that rotation by 2π transforms it into the negative of itself. A rotation by 4π is required in order to transform the spin function into itself. While this may at first glance seem unreasonable, there are simple examples that display this property. Take a strip of paper and form a Möbius strip by twisting one end 180° and joining it to the other end. Start at any point on the strip and trace a line through 360°. You do not end up at the starting point, but rather on the other side of the paper strip, as shown in Fig. 5.1. Continue tracing along the surface for another 360° and you will return to the original starting point. Early spectroscopic experiments on hydrogen and hydrogen-like atoms revealed that there were twice as many states as predicted by the solutions of Schrödinger's equation. The idea that an electron could have intrinsic angular momentum (spin) with two possible states was proposed by Kronig, Uhlenbeck, and Goudsmit [5.1] in 1925.
Spin is well known to be an intrinsically relativistic property of particles. Nonetheless its effects are seen in many physical situations which are not obviously relativistic, perhaps the most obvious examples being magnets and the quantum mechanically permitted electronic configurations of the elements in the periodic table. The view of spin adopted in these and other problems is that the electron has a quantized spin ( s = 1/2) and that is a fundamental tenet of the theory, rather than something that has to be explained. In this chapter we are going to discuss the behaviour of spin-1/2 particles (electrons, protons and neutrons for example) without much direct reference to relativistic quantum theory and the origins of spin. This chapter should be instructive in its own right and as a guide to understanding spin when we come to discuss it in a fully relativistic context at various stages throughout this book. Unless otherwise specified, we will refer to electrons, but it should be borne in mind that the theory is equally applicable to any spin-1/2 particle. Students of quantum theory cannot delve very deeply into the subject without coming across the quantization of angular momentum. The orbital angular momentum usually surfaces in the theory leading up to the quantum description of the hydrogen atom.
This chapter covers various aspects of orbital, total, and spin angular momenta and the Clebsch-Gordon coefficients. An approach that is not found in many books, is used to derive eigenvalues of orbital angular momentum. The Pauli theory of spin half systems, addition of angular momenta, eigenfunctions of orbital angular momentum, computation of Clebsch-Gordon coefficients, solved examples, and unsolved exercises are included in the chapter. The basic purpose of the chapter has been to bring out the quantum mechanical importance of the theory of angular momenta with the use of essential mathematical derivations, which are self-consistent, and to adopt an elegant modern approach. Special mention on why orbital angular momentum cannot have non-integer values is made. The concept of spin angular momentum, which is purely a quantum mechanical quantity, is introduced in a simple and most convincing manner.
Chapter 11 is devoted to the quantum theory of angular momentum. As in classical mechanics, working with angular momentum requires leaving the one-dimensional space, with all the complications that this entails. The importance of angular momentum resides in at least three facts: i) central problems are of particular interest; (ii) many particles have an intrinsic angular momentum (the spin); and iii) the physics of angular momentum involves features such as the so-called space quantization. The first part of the chapter deals with the orbital angular momentum and its eigenfunctions, the spherical harmonics. Its algebraic properties, embodied in the matrix representation, allow for an extension of the theory to half-integer angular momentum in terms of Pauli matrices, as well as the addition of angular momenta.
Spin-s systems Angular momentum is one of the fundamental quantities of Newtonian physics, and in quantum physics its importance is at least as great. In quantum mechanics we often distinguish between two types of angular momentum: orbital angular momentum , which a system of particles possesses due to particle motion through space; and spin angular momentum , which is an intrinsic property of a particle. The distinction will be important later, but for now we will ignore it. We will here refer to angular momentum of any sort as “spin” and develop general-purpose mathematical tools for its description. We have already dealt with spin systems, particularly the example of a spin-½ particle. Our approach began with the empirical observation that a measurement of any spin component of a spin-½ particle could yield only the results +ħ/2 or −ħ/2. We introduced the basis states | z ±〉 for the two-dimensional Hilbert space ℋ. We also gave other basis states such as {| x ±〉} and {| y ±〉} in terms of the | z ±〉 states. From basis states and measurement values we constructed operators for the spin components S x , S y , and S z . With the operators in hand, we could then examine the algebraic relations between them (such as the commutation relation in Exercise 3.56). Our job here is to generalize our analysis to systems of arbitrary spin. To do this, we will reverse our chain of logic.
We know that even a single electron in a hydrogen atom generally has orbital angular momentum L (with (2 l + 1) possible orientations where l is a integer) and spin angular momentum S (with two possible orientations commonly described as spin up and spin down or s = ± 1/2). In more complicated atoms there may be many components of angular momentum; for example, the helium atom has two electrons both of which have orbital and spin angular momenta. Also, in many atomic systems of physical interest we need to know how to combine angular momenta. This chapter explains how to do it.