This chapter shows how scattering problems are formulated in the framework of path integrals. In quantum mechanics, the state of an isolated system evolves under the action of a unitary operator, as a consequence of the conservation of probabilities and, thus, of the norm of vectors in Hilbert space. Quantum evolution (that is, in real time) is introduced, after which a path integral representation of the scattering matrix is constructed. From this S matrix, the standard perturbative expansion in powers of the potential is recovered. Even the evolution of a free quantum particle is slightly non-trivial; in general, one observes a spreading of wave packets. Scattering is then characterized by the asymptotic deviations at infinite time from this free evolution and this leads to the definition of a scattering or S-matrix. An S-matrix is defined in the example of bosons and fermions. Various other semi-classical approximation schemes are then discussed.
Abstract Chapter 4 has introduced the functional integral representation of the quantum statistical operators and thus, formally, evolution in imaginary or Euclidean time. By contrast, to calculate the evolution operator and the scattering S-matrix elements, quantities relevant to particle physics, it is necessary to make a continuation from imaginary to real time. However, the representation of the S-matrix follows from additional considerations. To illustrate the power of the formalism, we show how to recover the perturbative expansion of the scattering amplitude, some semi-classical approximations, and the eikonal approximation. When the asymptotic states at large time are eigenstates of the harmonic oscillator, instead of free particles, the holomorphic formalism becomes useful. A simple generalization of the path integral of Chapter 4 leads to the corresponding path integral representation of the S-matrix. In the case of the Bose gas, the evolution operator is then given by a holomorphic field integral. A parallel formalism leads to an analogous representation for the evolution operator of a system of non-relativistic fermions.
Given two Hamiltonians
H0,H1=H0+V corresponding respectively to a free particle Hamiltonian and the free particle Hamiltonian plus its interaction energy with a scattering centre, we can compute the S-matrix, i.e., the matrix that determines the quantum mechanical amplitude of the process involving a particle coming from a free particle state at an infinite distance from the scattering centre at time
t=−∞, entering into an initial scattered state, interacting with the scattering centre, entering into a final scattered state, and then escaping away to infinity at time
t→∞ to a final free particle state. Such amplitudes were first studied by Lippmann and Schwinger (Steven Weinberg, The Quantum Theory of Fields, Vol. 1, W.O. Amrein, Hilbert Space Methods in Quantum Mechanics) and then analyzed in a mathematically precise way by [T. Kato], [W. Amrein], and [K.B. Sinha]. In this paper, we first derive the Lippmann-Schwinger equation for the input and output scattered states in terms of the input and output free particle states using intuitive arguments originally due to Lippmann and Schwinger, and then, using rigorous operator theoretic arguments revolving around the spectral theorem for unbounded self-adjoint operators in a Hilbert space, we obtain an elegant formula for the scattering matrix elements in terms of the interaction potential and the free particle Hamiltonian between two free particle states corresponding to the same measure. We then discuss a computationally more efficient method based on the Dyson series expansion (Steven Weinberg, The Quantum Theory of Fields, Vol. 1), which works even in the case when the interaction Hamiltonian is time varying, in contrast to the Lippmann-Schwinger method, for calculating the S-matrix. We assume that the scattering potential, which can be time varying, can be controlled by incorporating control parameters and explain how the resulting unitary S-matrix can be made to approximate a given unitary gate in infinite-dimensional Hilbert space by optimizing the Hilbert-Schmidt/Frobenius norm distance between the given gate and the S-matrix gate, in which the latter is approximated by a truncated Dyson series. Of course, the S-matrix given by the Dyson series is a Taylor series functional expansion in the interaction potential and hence is a highly nonlinear function of the control parameters, and hence we propose numerical methods for such optimization. We then observe that if the control parameters are taken as random variables with joint moments, then the TPCP map involving statistical averaging of the adjoint action of the S-matrix acting on an initial mixed state w.r.t. the probability distribution of the control parameters will result in a final mixed state that is linear in the statistical moments of the control parameters, and hence optimization w.r.t. these moments can be easily carried out. Our method of TPCP map design is to optimize the sum of Frobenius distance squares between a sequence of desired output mixed states and the S-matrix based formula for the TPCP map acting on the corresponding input mixed states w.r.t. the statistical moments of the control parameters. We then generalize this method to include the case of TPCP maps obtained from the Hudson-Parthasarathy quantum noisy Schrödinger equation. In summary, we simulate the S-matrix gate for independent realizations of the control parameters having a probability distribution defined by their joint moments obtained by the above optimization procedure and apply the adjoint action of these independent S-matrices on a given input state, and take their ensemble average to obtain a good approximation to the action of the desired TPCP map on any given input state. This suggests that TPCP maps of arbitrarily large size can be realized using scattering experiments in the laboratory.
1. Gaussian integrals 2. Path integral in quantum mechanics 3. Partition function and spectrum 4. Classical and quantum statistical physics 5. Path integrals and quantization 6. Path integral and holomorphic formalism 7. Path integrals: fermions 8. Barrier penetration: semi-classical approximation 9. Quantum evolution and scattering matrix 10. Path integrals in phase space QUANTUM MECHANICS: MINIMAL BACKGROUND A1 Hilbert space and operators A2 Quantum evolution, symmetries and density matrix A3 Position and momentum. Scrodinger equation
Background: Path integrals are a powerful tool for solving problems in quantum theory that are not amenable to a treatment by perturbation theory. Most path integral computations require an analytic continuation to imaginary time. While imaginary time treatments of scattering are possible, imaginary time is not a natural framework for treating scattering problems. More importantly, quantum algorithms for calculating path integrals require real-time evolution.Purpose: We test a recently introduced method for performing direct calculations of scattering observables using real-time path integrals in order to understand the challenges facing real-time path integral calculations of scattering observables.Method: The computations are based on a new interpretation of the path integral as the expectation value of a potential functional on cylinder sets of continuous paths with respect to a complex probability distribution. The method can in principle be applied to arbitrary short-range potentials.Results: The method is applied to compute matrix elements of M\o{}ller wave operators applied to narrow wave packets. These are used to calculate half-shell sharp-momentum transition matrix elements for one-dimensional potential scattering. The calculations for half-shell transition operator matrix elements converge to the numerical solution of the Lippmann-Schwinger equation.Conclusions: This work presents a proof in principle that scattering observables can be computed using real-time Feynman path integrals. While the computational method is not efficient, it can be improved. It provides a laboratory for studying quantum computational algorithms that are applicable to scattering problems.
To introduce the formalism of the functional integral in quantum mechanics, this chapter starts from the definition of the temporal evolution operator. It is important to emphasize that in the classical limit is not only the classic trajectory that have the grater contribution, but all the paths close to this also contribute. The chapter shows how integral formulation is perfectly consistent with Schrödinger's time-dependent differential equation. It retrieves this equation from definition of transition amplitude as a path integral. The chapter discusses functional derivative generalized to the case of the ordinary functional derivative. A very useful tool to solve problems related to functional integrals is the Wick rotation or Euclidean rotation. In quantum mechanics there are few problems we can solve exactly, and very often, when possible, we use perturbation theory to find an approximate solution. The chapter follows this approach with formalism of functional integration and construct a perturbation theory from which can be obtained a physical interpretation.
The quantizer–dequantizer method is employed. Using the construction of probability distributions describing density operators of a quantum system states, the connection between the Feynman path integral and the time evolution of the density operator (Landau density matrix) as well as the wave function of the stateconsidered. For single–mode systems with continuous variables, a tomographic propagator is introduced in the probability representation of quantum mechanics. An explicit expression for the probability in terms of the Green function of the Schrödinger equation is obtained. Equations for the Green functions defined by arbitrary integrals of motion are derived. Examples of probability distributions describing the evolution of state of a free particle, as well as states of systems with integrals of motion that depend on time (oscillator type) are discussed.