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Oxford University Press eBooks

PATH INTEGRALS IN QUANTUM MECHANICS

Jean Zinn‐Justin

Published Nov 18, 2004• 586 citations
Publisher

Abstract

1. Gaussian integrals 2. Path integral in quantum mechanics 3. Partition function and spectrum 4. Classical and quantum statistical physics 5. Path integrals and quantization 6. Path integral and holomorphic formalism 7. Path integrals: fermions 8. Barrier penetration: semi-classical approximation 9. Quantum evolution and scattering matrix 10. Path integrals in phase space QUANTUM MECHANICS: MINIMAL BACKGROUND A1 Hilbert space and operators A2 Quantum evolution, symmetries and density matrix A3 Position and momentum. Scrodinger equation

DOI
10.1093/acprof:oso/9780198566748.003.0002

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Path integrals are mathematical objects that can be considered as generalizations to an infinite number of variables, represented by paths, of usual integrals. They share the algebraic properties of usual integrals, but have new properties from the viewpoint of analysis. They are powerful tools for the study of quantum mechanics, since they emphasize very explicitly the correspondence between classical and quantum mechanics. Physical quantities are expressed as averages over all possible paths but, in the semi-classical limit, the leading contributions come from paths close to classical paths. Thus, path integrals lead to an intuitive understanding of physical quantities in the semi-classical limit, as well as simple calculations of such quantities. This observation can be illustrated with scattering processes, spectral properties, or barrier penetration effects. Even though the formulation of quantum mechanics based on path integrals seems mathematically more complicated than the usual formulation based on partial differential equations, the path integral formulation is well adapted to systems with many degrees of freedom, where a formalism of Schrödinger type is much less useful. It allows simple construction of a many-body theory both for bosons and fermions.
Path Integrals in Classical Theory Brownian motion: Introduction to the concept of path integration Wiener path integrals and stochastic processes Path Integrals in Quantum Mechanics Feynman path integrals Path integrals in Hamiltonian formalism Quantizations, the operator ordering problem and path integrals Path integrals and quantizations in spaces with topologiecal constraints Path integrals in curved spaces, space time transformations and the Coulomb problem Path integrals over anticommuting variables for fermions and generalizations Appendices Bibliography Index
This chapter introduces the holomorphic representation of quantum mechanics, because it allows a study of the properties of boson systems both from the point of view of evolution and of quantum statistical physics (in the so-called second quantization formalism). Path integrals then take the form of integrals over trajectories in phase space in a complex parametrization. A parallel formalism, based on integration over anti-commuting type or Grassmann variables, makes it possible to handle fermions in a way quite analogous to bosons. The corresponding path integral representation of the statistical operator is then derived. The holomorphic formalism is specially well adapted to a study of the harmonic oscillator and, more generally, of perturbed harmonic oscillators. As an illustration, the formalism is applied to the Bose-Einstein condensation. This chapter also considers complex integrals and Wick's theorem, kernel of operators, general Hamiltonians, partition function, and the quantum Bose gas.
Fundamentals Path Integrals - Elementary Properties and Simple Solutions External Sources, Correlations, and Perturbation Theory Semiclassical Time Evolution Amplitude Variational Perturbation Theory Path Integrals with Topological Constrainsts Many Particle Orbits - Statistics and Second Quantization Path Integrals in Spherical Coordinates Fixed-Energy Amplitude and Wave Functions Spaces with Curvature and Torsion Schrodinger Equation in General Metric-Affine Spaces New Path Integral Formula for Singular Potentials Path Integral of Coulomb System Solution of Further Path Integrals by the Duru-Kleinert Method Path Integrals in Polymer Physics Polymers and Particle Orbits in Multiply Connected Spaces Tunneling Nonequilibrium Quantum Statistics Relativistic Particle Orbits Path Integrals and Financial Markets.
Basically, there are two approaches to the formulation of quantum mechanics, i.e., the operator and the Feynman path integral approach. The main object in quantum mechanics is referred to as the transition amplitude between those states, matrix elements of physical operators and, in particular, the S- matrix in the problem of quantum scattering. On the basis of quantum mechanics, the operator method is closed, well formulated mathematically, and so is an appropriate universal language describing quantum field theory, the quantum physics of condensed states and quantum relativistic statistical physics. The differential equation defining the path of the system in the configuration space is called the equation of motion of the system. The aim of classical as well as quantum mechanics is to predict the time evolution of the system, starting from knowledge of the state of the system at a given point in time.
Written for a two-semester graduate course in Quantum Mechanics, this comprehensive text helps develop the tools and formalism of Quantum Mechanics and its applications to physical systems. It suits students who have taken some introductory Quantum Mechanics and Modern Physics courses at undergraduate level, but it is self-contained and does not assume any specific background knowledge beyond appropriate fluency in mathematics. The text takes a modern logical approach rather than a historical one and it covers standard material, such as the hydrogen atom and the harmonic oscillator, the WKB approximations and Bohr-Sommerfeld quantization. Important modern topics and examples are also described, including Berry phase, quantum information, complexity and chaos, decoherence and thermalization, nonstandard statistics, as well as more advanced material such as path integrals, scattering theory, multiparticles and Fock space. Readers will gain a broad overview of Quantum Mechanics, as solid preparation for further study or research.