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Birkhäuser Basel eBooks

Quantum-statistical self-consistent field models

Published Jan 1, 2005• 1 citation
Publisher
DOI
10.1007/3-7643-7346-6_3

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Abstract The Feynman quantum-classical isomorphism between classical statistical mechanics in 3+1 dimensions and quantum statistical mechanics in 3 dimensions is used to connect classical polymer self-consistent field theory with quantum time-dependent density functional theory. This allows the theorems of density functional theory to relate non-relativistic quantum mechanics to a classical statistical mechanical derivation of polymer self-consistent field theory for ring polymers in a 4 dimensional thermal-space. One dynamic postulate is added to two static postulates which allows for a description of quantum physics from a 5 dimensional thermal-space-time ensemble perspective. A connection with aspects of classical field theory can be made in the classical limit.
The self-consistent field approximation (SCFA)[1]-[4] is used to calculate the steady-state mode energies and frequency shifts for a gas laser. The SCFA is a statistical approximation which was shown[3] to be accurate for small values of a parameter (\gamma^{2}N), which is always small for gas lasers. The SCFA is simpler and more convenient for studying the complicated dynamical effects that occur in gas lasers than the more recent[5]-[8] quantum theoretical models. It does not, of course, give any new description of the laser photon statistics, since the approximation treats the field as a pure coherent state[9] and is, therefore, equivalent to the semiclassical theory. The main results of this paper are to show how dynamical effects can be calculated nonperturbatively for arbitrary values of the field strength, and to analyze the different roles played by different kinds of inhomogeneous effects in gas lasers. These inhomogeneous effects are due to the dependence of the atomic inversion density on the atomic positions and velocities. Some numerical results are given which show that the nonperturbative theory can explain some effects not previously explained by perturbation theories. [1], [2].
A self-consistent field (SCF) model is constructed for spatially inhomogeneous Bose systems with broken symmetry. A system of self-consistent equations is obtained for the wave functions of the quasiparticles and the wave function of the condensate particles and another system of equations for the normal and anomalous single-particle density matrices. The many-particle wave function is found. The thermodynamics of multiparticle Bose systems is constructed on the basis of a microscopic treatment in the SCF approximation. It is stressed that Bose condensation in the ideal gas model is substantially different from Bose condensation in a system of interacting Bose particles because a pair condensate is necessarily present as well as the single-particle condensate, even for an arbitrarily weak interaction. The role of single-particle and collective excitations in Bose systems is discussed.