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The Atomic Problem

David A. Robinson, John McK. Woollard

Published Jan 1, 1982• 0 citations
Publisher

Abstract

Our present-day understanding of the detailed nature of atoms and molecules is based on what is known as quantum (mechanical) theory. This approach is relatively new, dating only from the early years of the century. The reasons for its development lay in the failure of so-called classical mechanics — by which we describe and explain the behaviour and interactions of relatively large bodies of matter — to describe satisfactorily the atomic system.

DOI
10.1007/978-1-349-04540-2_10

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Our present-day understanding of the detailed nature of atoms and molecules is based on what is known as quantum (mechanical) theory. This approach is relatively new, dating only from the early years of the century. The reasons for its development lay in the failure of so-called classical mechanics — by which we describe and explain the behaviour and interactions of relatively large bodies of matter — to describe satisfactorily the atomic system.
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When physicists began to explore the world of atoms more precisely, as they endeavoured to understand its structure and the laws governing its behaviour, they soon encountered serious difficulties. Our intuitive concepts, based on our daily experience of the macroscopic world around us, proved to be completely erroneous on the atomic scale; the atom was incomprehensible within the framework of classical physics. In order to uncover these new mysteries, after a great deal of trial and error, entirely new concepts therefore had to be elaborated: the concepts of quantum physics. What are the main stages that have led us to this modern understanding of the atom? What is the present state of atomic physics? How has it contributed to the development of our knowledge and where is it heading?
1124 NOTICES OF THE AMS VOLUME 45, NUMBER 9 I n the twentieth century, the quest for deeper understanding of the laws of nature has largely revolved around the development of two great theories: namely, general relativity and quantum mechanics. General relativity is, of course, Einstein’s theory according to which gravitation results from the curvature of space and time; the mathematical framework is that of Riemannian geometry. While previously spacetime was understood as a fixed arena, given ab initio, in which physics unfolds, in general relativity spacetime evolves dynamically, according to the Einstein equations. Part of the problem of physics, according to this theory, is to determine, given the initial conditions as input, how spacetime will develop in the future. The influence of general relativity in twentiethcentury mathematics has been clear enough. Learning that Riemannian geometry is so central in physics gave a big boost to its growth as a mathematical subject; it developed into one of the most fruitful branches of mathematics, with applications in many other areas. While in physics general relativity is used to understand the behavior of astronomical bodies and the universe as a whole, quantum mechanics is used primarily to understand atoms, molecules, and subatomic particles. Quantum theory has had a much more complex history than general relativity, and in some sense most of its influence on mathematics belongs to the twenty-first century. The quantum theory of particles—which is more commonly called nonrelativistic quantum mechanics—was put in its modern form by 1925 and has greatly influenced the development of functional analysis, and other areas. But the deeper part of quantum theory is the quantum theory of fields, which arises when one tries to combine quantum mechanics with special relativity (the precursor of general relativity, in which the speed of light is the same in every inertial frame but spacetime is still flat and given ab initio). This much more difficult theory, developed from the late 1920s to the present, encompasses most of what we know of the laws of physics, except gravity. In its seventy years there have been many milestones, ranging from the theory of “antimatter”, which emerged around 1930, to a more precise description of atoms, which quantum field theory provided by 1950, to the “standard model of particle physics” (governing the strong, weak, and electromagnetic interactions), which emerged by the early 1970s, to new predictions in our own time that one hopes to test in present and future accelerators. Quantum field theory is a very rich subject for mathematics as well as physics. But its development in the last seventy years has been mainly by physicists, and it is still largely out of reach as a rigorous mathematical theory despite important efforts in constructive field theory. So most of its impact on mathematics has not yet been felt. Yet in many active areas of mathematics, problems are Edward Witten is professor of physics at the Institute for Advanced Study. His e-mail address is witten@ias.edu.
So far, this book has dealt almost exclusively with classical physics, which is a theoretical structure based on many brilliant and imaginative experiments performed on macroscopic objects, that is on objects of about our size or a few orders of magnitude smaller or larger. Classical physics was found to give good results when extrapolated downward to molecules and upward to planets, stars, and galaxies, and it was seriously suggested ate in the nineteenth century that all the major discoveries in physics had been made — that the physical basis of the universe was understood and that only minor tidying-up remained.
World Quantum Day is an international initiative dedicated to promoting public understanding of quantum science and technology.Celebrated annually on April 14, the date reflects the first three digits of Planck's constant (expressed as 4.14 × 10 -¹⁵ electronvolt-seconds).The word quantum refers to the smallest discrete unit of a physical quantity that can be exchanged or measured.Quantum science developed during the early 20th century.Pioneers such as Max Planck, Albert Einstein, Niels Bohr, and Erwin Schrödinger developed theories explaining how energy and matter behave at atomic and subatomic scales.Medical applications of quantum mechanics include imaging such as ultrasound, magnetic resonance, and positron emission tomography; tissue imaging in microscopy, radiation therapy, and nuclear medicine; drug discovery; quantum communication and cybersecurity; education and public outreach, decision-making, and the development of new computational systems.In this review, we present an updated overview of quantum computing based on an extensive literature review using the databases PubMed, EMBASE, and Scopus.
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