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CRC Press eBooks

Spin-1/2 current density in relativistic quantum mechanics

Ole Keller

Published May 13, 2014• 0 citations
Publisher

Abstract

In the search for a relativistic wave equation for a free particle of rest mass m one must demand that the energy(E)-momentum (p) [dispersion] relation E2 = m2c4 + p2c2 (25.1) is satisfied. By the substitutions E → i~ ∂ ∂t , p→ −i~∇ (25.2) in Eq. (25.1) one obtains an operator, which when acting on a scalar wave function, gives us the Klein-Gordon wave equation for a spinless particle. The Klein-Gordon equation is of second order in the space (r) and time (t) coordinates. If one seeks a covariant first-order differential equation, r and t must play symmetric roles. A natural starting point therefore would be a linear dispersion relation of the form E = βmc2 + cα · p, (25.3) where β and α = (α1, α2, α3) are real and dimensionless. Since Eq. (25.3) must be compatible with Eq. (25.1), squaring of Eq. (25.3) leads to the following relations [already given in Eqs. (10.77)-(10.79)]: β2 = 1, (25.4) αiβ + βαi = 0, (25.5) αiαj + αjαi = 2δij , (25.6) where i, j = 1, 2, 3 (x, y, z). It is clear from Eqs. (25.4)-(25.6) that β and α cannot be numbers, but one can find matrices which satisfy these equations. Since the Hamiltonian appearing upon a substitution of the connections in (25.2) into Eq. (25.3) must be Hermitian, the αi and β matrices also have to be Hermitian, i.e., α†i = αi, i = 1− 3, (25.7) β† = β. (25.8) One can show that the matrices must have even rank and that the rank must be at least 4, see, e.g., [88]. The Dirac equation, which describes the quantum mechanics of a spin1/2 elementary particle, e.g., an electron, relates to a four-dimensional realization of Eqs. (25.4)-(25.8). Representations of a given rank are not unique.

DOI
10.1201/b16917-35

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In the search for a relativistic wave equation for a free particle of rest mass m one must demand that the energy(E)-momentum (p) [dispersion] relation E2 = m2c4 + p2c2 (25.1) is satisfied. By the substitutions E → i~ ∂ ∂t , p→ −i~∇ (25.2) in Eq. (25.1) one obtains an operator, which when acting on a scalar wave function, gives us the Klein-Gordon wave equation for a spinless particle. The Klein-Gordon equation is of second order in the space (r) and time (t) coordinates. If one seeks a covariant first-order differential equation, r and t must play symmetric roles. A natural starting point therefore would be a linear dispersion relation of the form E = βmc2 + cα · p, (25.3) where β and α = (α1, α2, α3) are real and dimensionless. Since Eq. (25.3) must be compatible with Eq. (25.1), squaring of Eq. (25.3) leads to the following relations [already given in Eqs. (10.77)-(10.79)]: β2 = 1, (25.4) αiβ + βαi = 0, (25.5) αiαj + αjαi = 2δij , (25.6) where i, j = 1, 2, 3 (x, y, z). It is clear from Eqs. (25.4)-(25.6) that β and α cannot be numbers, but one can find matrices which satisfy these equations. Since the Hamiltonian appearing upon a substitution of the connections in (25.2) into Eq. (25.3) must be Hermitian, the αi and β matrices also have to be Hermitian, i.e., α†i = αi, i = 1− 3, (25.7) β† = β. (25.8) One can show that the matrices must have even rank and that the rank must be at least 4, see, e.g., [88]. The Dirac equation, which describes the quantum mechanics of a spin1/2 elementary particle, e.g., an electron, relates to a four-dimensional realization of Eqs. (25.4)-(25.8). Representations of a given rank are not unique.
According to non-relativistic quantummechanics, the evolution of the wave function of a free particle of mass m and momentum p is described by the Schro¨dinger equation: i ∂ψ ∂t = Hψ , (6.1) with the Hamiltonian operator H = −∇2/2m obtained from the expression for energy E = p2 2m , (6.2) using the substitution E → i ∂ ∂t , p → −i∇ . (6.3) Schro¨dinger himself [6] first suggested a generalisation of equation (6.1) based on the use of the relativistic energy equation: E2 = p2 +m2 . (6.4) (+m2)ψ = 0 , (6.5) Multiplying by ψ∗ and subtracting the product of ψ and the complex conjugate of (6.5) from the result, the continuity equation is obtained ∂ρ ∂t = ∇j , (6.6) with ρ = ψ∗ ∂ψ ∂t − ψ∂ψ ∂t (6.7) and j = −∇ (ψ∗∇ψ − ψ∇ψ∗) . (6.8) However, the ρ which appears in equation (6.6) cannot be identified with the probability density, in analogy with the similar quantity obtained from the Schro¨dinger equation, because it does not have the required property of being always positive-definite. To be convinced of this it is sufficient to substitute i∂/∂t→ E in (6.7). The result, ρ = E|ψ|2 , shows that ρ can be either positive or negative, following from the fact that the Klein-Gordon equation has solutions for the energy with both signs E = ± √ p2 +m2 , Note that in the non-relativistic limit E ≈ m > 0, and the familiar result ρ ∝ |ψ|2 is recovered.
In this chapter, we investigate the Dirac equation, which is named after P. A. M. Dirac, who is one of the fathers of quantum field theory. The Dirac equation is a relativistic quantum mechanical wave equation for spin-1/2 particles (e.g. electrons), which was derived by Dirac in 1928. The difficulties in finding a consistent single-particle theory from the Klein–Gordon equation led Dirac to search for an equation that had a positive-definite conserved probability density and was first order both in time and space. One can show that these two conditions imply that a matrix equation is required. The reason why the Klein–Gordon equation did not yield a positive-definite probability density is connected with the second-order time derivative in this equation, which arises because the Klein–Gordon equation is related to the relativistic energy–momentum relation E 2 = m 2 + p 2 via the correspondence principle that includes a term E 2 . Thus, a ‘better’ Lorentz covariant wave equation with a positive-definite probability density should have a first-order time derivative only. However, the equivalence of time and space coordinates in Minkowski space requires that such an equation also have only first-order space derivatives.
The Klein-Gordon equation describes the wave-like behavior of spinless particles since it is Lorentz invariant. While it seemed initially ripe for explaining the electronic structure of the hydrogen atom, the lack of a unconditional positive probability density really limited its applications. Yet, it is intimately connected with fermions. Any solution to the Dirac equation is automatically a solution to the Klein-Gordon equation. What is even more surprising, the Klein-Gordon equation for a free particle turns into the Schrödinger equation in the non-relativistic limit. In this work we show that these problems disappear when we use the relativistic mass instead of the rest mass. While the Klein-Gordon equation losses its Lorentz invariance because of this transformation, it gains most of the features present the Schrödinger equation, including the unconditional positivity of probability density, while keeping most of its relativistic characteristics intact, including the matter-wave dispersion relation. What is even more surprising, the non-relativistic, quasi-static limit of the Klein-Gordon equation with relativistic mass is simply the Schrödinger equation under all possible conditions. So, it can be argued that this Klein-Gordon equation is a sort of relativistic Schrödinger equation.
The Klein–Gordon equation, written down in 1926 by Oskar Klein and Walter Gordon (and earlier in unpublished form by Schrödinger himself), is the natural relativistic extension of quantum mechanics for spin‑zero particles: (□ + m²c²/ℏ²) Ψ = 0 where □ = (1/c²) ∂ₜ² − ∇². The equation is second‑order in both time and space, treats them symmetrically, and reduces to the free‑particle Schrödinger equation in the non‑relativistic limit. Its plane‑wave solutions satisfy the relativistic mass‑shell condition E² = p²c² + m²c⁴. Why is a relativistic version needed at all? The Schrödinger equation describes how quantum systems evolve when they’re moving slowly compared to the speed of light — fine for atoms, molecules, and everyday chemistry, where electrons move at less than 1% of c. But the Schrödinger equation is first‑order in time and second‑order in space, treating the two on different footings. Special relativity says space and time are unified into a single four‑dimensional structure where Lorentz transformations mix them, and any equation that privileges time over space breaks Lorentz invariance. A truly fundamental quantum equation must respect this symmetry. Klein–Gordon is the minimal scalar‑field equation that does. The standard derivation runs by analogy: start with the relativistic energy–momentum relation E² = p²c² + m²c⁴, replace E by iℏ∂ₜ and p by −iℏ∇, apply both sides to a wavefunction. This produces the right equation but it’s not really a derivation — it’s a guess motivated by the Schrödinger operator‑substitution procedure. This walkthrough shows how the Event Density framework derives the Klein–Gordon equation from substrate primitives — the same primitives that gave the Born rule, the Schrödinger equation, and the Bell–Tsirelson bound — plus the commitment to Lorentz covariance. The participation measure becomes Lorentz‑covariant. The unique second‑order Lorentz‑scalar differential operator on a scalar field is the d’Alembertian; the minimum‑order Lorentz‑scalar linear equation is therefore (□ + M²) Ψ = 0. Dimensional analysis fixes M² = m²c²/ℏ². Local U(1) gauge invariance forces the covariant derivative and the conserved four‑current. The non‑relativistic limit, via rest‑energy factorization, recovers the free‑particle Schrödinger equation exactly. The structural payoff: the Klein–Gordon equation is what you get when the substrate ontology is pushed through a Lorentz‑covariant reformulation. No new primitives are required. Relativistic and non‑relativistic quantum mechanics are not two theories glued together by analogy; they are the same substrate ontology applied at different velocity regimes. The walkthrough is honest about the known caveats — negative‑energy solutions and the non‑positive‑definite j₀ current — both of which resolve at the Dirac level and at QFT.
Abstract This chapter is seeking relativistic wave equations, which are invariant under Lorentz transformations, in an attempt to obtain a quantum mechanical description of relativistic particles. First, the chapter starts with the Klein–Gordon equation and then it discusses the Dirac equation. It also takes the non-relativistic limit of the Dirac equation to derive the Schrödinger equation with two additional terms, the Zeeman term and the spin–orbit coupling term. These two terms emerge naturally from the Dirac equation, and thus the spin, as an internal quantum number which behaves like angular momentum, is clearly identified. Finally, the existence of antimatter is clearly supported by the nature of the solutions to the Dirac equation.
The chapter covers some of the essential aspects of relativistic quantum mechanics. The Klein-Gordon equation and its solution in coulombic fields, how to interpret probability density and probability current derived from the Klein-Gordon equation, derivation of the Dirac equation and its covariant form, probability density and probability current for Dirac equation, positive and negative energy eigenvalues in the case of a free particle, constants of motion for relativistic treatment, presence of spin magnetic moment and spin-orbit interaction energy in the Dirac equation, and the solution of the Dirac equation for central potentials and for the hydrogen atom are presented with elegant mathematical treatment and physical interpretations. A modern and reader friendly approach is adopted for derivation of the Dirac equation, constants of motion, and for the solution of the Dirac equation for central potentials. Solved examples and unsolved exercises relating to fundamental concepts of relativistic quantum mechanics are added towards the end of chapter.