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Cambridge University Press eBooks

The Dirac equation

Tommy Ohlsson B

Published Sep 22, 2011• 0 citations
Publisher

Abstract

In this chapter, we investigate the Dirac equation, which is named after P. A. M. Dirac, who is one of the fathers of quantum field theory. The Dirac equation is a relativistic quantum mechanical wave equation for spin-1/2 particles (e.g. electrons), which was derived by Dirac in 1928. The difficulties in finding a consistent single-particle theory from the Klein–Gordon equation led Dirac to search for an equation that had a positive-definite conserved probability density and was first order both in time and space. One can show that these two conditions imply that a matrix equation is required. The reason why the Klein–Gordon equation did not yield a positive-definite probability density is connected with the second-order time derivative in this equation, which arises because the Klein–Gordon equation is related to the relativistic energy–momentum relation E 2 = m 2 + p 2 via the correspondence principle that includes a term E 2 . Thus, a ‘better’ Lorentz covariant wave equation with a positive-definite probability density should have a first-order time derivative only. However, the equivalence of time and space coordinates in Minkowski space requires that such an equation also have only first-order space derivatives.

DOI
10.1017/cbo9781139032681.004

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In this chapter, we investigate the Dirac equation, which is named after P. A. M. Dirac, who is one of the fathers of quantum field theory. The Dirac equation is a relativistic quantum mechanical wave equation for spin-1/2 particles (e.g. electrons), which was derived by Dirac in 1928. The difficulties in finding a consistent single-particle theory from the Klein–Gordon equation led Dirac to search for an equation that had a positive-definite conserved probability density and was first order both in time and space. One can show that these two conditions imply that a matrix equation is required. The reason why the Klein–Gordon equation did not yield a positive-definite probability density is connected with the second-order time derivative in this equation, which arises because the Klein–Gordon equation is related to the relativistic energy–momentum relation E 2 = m 2 + p 2 via the correspondence principle that includes a term E 2 . Thus, a ‘better’ Lorentz covariant wave equation with a positive-definite probability density should have a first-order time derivative only. However, the equivalence of time and space coordinates in Minkowski space requires that such an equation also have only first-order space derivatives.
The chapter covers some of the essential aspects of relativistic quantum mechanics. The Klein-Gordon equation and its solution in coulombic fields, how to interpret probability density and probability current derived from the Klein-Gordon equation, derivation of the Dirac equation and its covariant form, probability density and probability current for Dirac equation, positive and negative energy eigenvalues in the case of a free particle, constants of motion for relativistic treatment, presence of spin magnetic moment and spin-orbit interaction energy in the Dirac equation, and the solution of the Dirac equation for central potentials and for the hydrogen atom are presented with elegant mathematical treatment and physical interpretations. A modern and reader friendly approach is adopted for derivation of the Dirac equation, constants of motion, and for the solution of the Dirac equation for central potentials. Solved examples and unsolved exercises relating to fundamental concepts of relativistic quantum mechanics are added towards the end of chapter.
This paper derives the Dirac equation as the logically forced relativistic completion of the de Broglie wave dynamics established in prior work of this series. Starting from the logical foundation that yields Lorentz/Poincaré invariance, we promote the non-relativistic framework (continuous spacetime, Fourier duality, local plane-wave structures, and probability conservation via statistical energy flux) to the relativistic regime. We show that the requirements of exact local relativistic plane-wave structures (with phase gradients satisfying the mass-shell condition pμpμ=m2c2p^\mu p_\mu = m^2 c^2pμpμ​=m2c2), first-order time evolution (needed for clean probability conservation), and full Lorentz covariance together force the introduction of a specific non-commuting algebraic structure and a multi-component wave function. The Dirac equation emerges as the unique linear differential operator of order at most one in the spacetime derivatives that consistently glues these local structures across smooth backgrounds while preserving a conserved four-current with positive-definite time component. This multi-component structure arises naturally as the minimal algebraic consequence of the constraints, without any separate postulate for intrinsic angular momentum. In exact analogy with the emergence of the finite invariant causal speed in special relativity, the Dirac dynamics is revealed not as an ad-hoc linearization of the Klein--Gordon equation, but as the mathematically inevitable description of indivisible particles in continuous relativistic spacetime. The derivation thereby completes the single-particle sector of the series, demonstrating that core structures of relativistic quantum mechanics flow deductively from a small number of deep, nearly tautological commitments.
Abstract This chapter is seeking relativistic wave equations, which are invariant under Lorentz transformations, in an attempt to obtain a quantum mechanical description of relativistic particles. First, the chapter starts with the Klein–Gordon equation and then it discusses the Dirac equation. It also takes the non-relativistic limit of the Dirac equation to derive the Schrödinger equation with two additional terms, the Zeeman term and the spin–orbit coupling term. These two terms emerge naturally from the Dirac equation, and thus the spin, as an internal quantum number which behaves like angular momentum, is clearly identified. Finally, the existence of antimatter is clearly supported by the nature of the solutions to the Dirac equation.
The Klein–Gordon equation, written down in 1926 by Oskar Klein and Walter Gordon (and earlier in unpublished form by Schrödinger himself), is the natural relativistic extension of quantum mechanics for spin‑zero particles: (□ + m²c²/ℏ²) Ψ = 0 where □ = (1/c²) ∂ₜ² − ∇². The equation is second‑order in both time and space, treats them symmetrically, and reduces to the free‑particle Schrödinger equation in the non‑relativistic limit. Its plane‑wave solutions satisfy the relativistic mass‑shell condition E² = p²c² + m²c⁴. Why is a relativistic version needed at all? The Schrödinger equation describes how quantum systems evolve when they’re moving slowly compared to the speed of light — fine for atoms, molecules, and everyday chemistry, where electrons move at less than 1% of c. But the Schrödinger equation is first‑order in time and second‑order in space, treating the two on different footings. Special relativity says space and time are unified into a single four‑dimensional structure where Lorentz transformations mix them, and any equation that privileges time over space breaks Lorentz invariance. A truly fundamental quantum equation must respect this symmetry. Klein–Gordon is the minimal scalar‑field equation that does. The standard derivation runs by analogy: start with the relativistic energy–momentum relation E² = p²c² + m²c⁴, replace E by iℏ∂ₜ and p by −iℏ∇, apply both sides to a wavefunction. This produces the right equation but it’s not really a derivation — it’s a guess motivated by the Schrödinger operator‑substitution procedure. This walkthrough shows how the Event Density framework derives the Klein–Gordon equation from substrate primitives — the same primitives that gave the Born rule, the Schrödinger equation, and the Bell–Tsirelson bound — plus the commitment to Lorentz covariance. The participation measure becomes Lorentz‑covariant. The unique second‑order Lorentz‑scalar differential operator on a scalar field is the d’Alembertian; the minimum‑order Lorentz‑scalar linear equation is therefore (□ + M²) Ψ = 0. Dimensional analysis fixes M² = m²c²/ℏ². Local U(1) gauge invariance forces the covariant derivative and the conserved four‑current. The non‑relativistic limit, via rest‑energy factorization, recovers the free‑particle Schrödinger equation exactly. The structural payoff: the Klein–Gordon equation is what you get when the substrate ontology is pushed through a Lorentz‑covariant reformulation. No new primitives are required. Relativistic and non‑relativistic quantum mechanics are not two theories glued together by analogy; they are the same substrate ontology applied at different velocity regimes. The walkthrough is honest about the known caveats — negative‑energy solutions and the non‑positive‑definite j₀ current — both of which resolve at the Dirac level and at QFT.
In special relativity, time and space are transformed according to the Lorentz transformation. Relativistic quantum mechanics is quantum mechanics that is consistent with special relativity. Nevertheless, relativistic quantum mechanics is only an approximation to a fully self-consistent relativistic theory of known particle interactions because it does not describe cases where the number of particles changes. In special relativity, mass can emerge from energy, which is not possible in quantum mechanics based on the conservation of probability. Dirac proposed the equation named after him to solve the difficulty encountered in the Klein-Gordon equation stemmed from the fact that it is a second-order differential equation in time.
Abstract The Klein–Gordon and the Dirac equations are studied as candidates for a relativistic generalisation of the Schrödinger equation. We show that the first is unacceptable because it admits solutions with arbitrarily large negative energy and has no conserved current with positive definite probability density. The Dirac equation on the other hand does have a physically acceptable conserved current, but it too suffers from the presence of negative energy solutions. We show that the latter can be interpreted as describing anti-particles. In either case there is no fully consistent interpretation as a single-particle wave equation and we are led to a formalism admitting an infinite number of degrees of freedom, that is a quantum field theory. We can still use the Dirac equation at low energies when the effects of anti-particles are negligible and we study applications in atomic physics.