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Oxford University Press eBooks

An introduction to superfluidity and superconductivity

K.H. Bennemann, John B. Ketterson

Published Feb 28, 2013• 2 citations
Publisher

Abstract

This chapter covers some of the basics of superfluidity. It discusses Bose–Einstein condensation in an ideal gas; the Bogoliubov transformation; superfluid helium II; microscopic interpretation of the Bose order parameter; phenomenological theories of superconductivity; the Bardeen–Cooper–Schrieffer (BCS) theory of superconductivity; the first unusual superfluid, 3He; and recent developments in superfluidity.

DOI
10.1093/acprof:oso/9780199585915.003.0001

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This chapter covers some of the basics of superfluidity. It discusses Bose–Einstein condensation in an ideal gas; the Bogoliubov transformation; superfluid helium II; microscopic interpretation of the Bose order parameter; phenomenological theories of superconductivity; the Bardeen–Cooper–Schrieffer (BCS) theory of superconductivity; the first unusual superfluid, 3He; and recent developments in superfluidity.
Abstract The book covers three main strands, Bose-Einstein condensates (BEC), superfluid and superconductivity. The subjects are developed in a way which gradually builds up the key concepts and the necessary mathematical machinery. The book begins with the simplest of the three topics, BEC, and first thoroughly reviews the basics of the Bose-Einstein ideal gas before going into the techniques of magnetic trapping and cooling of atoms and the discovery of BEC in dilute atomic gases. Superfluidity in helium-4 is more difficult to understand, because it is a strongly interacting quantum liquid. The book introduces the main physical phenomena of superfluidity, and how it follows from the key concept of macroscopic quantum coherence and off-diagonal long ranged order. The theory of superconductivity is developed in stages, starting with the simpler London and Ginzburg Landau theories and their main applications, before developing the mathematical concepts of a quantum coherent state and the Bardeen Cooper Schrieffer (BCS) theory. The final chapter deals with the more advanced topics, including superfluid helium-3 and evidence for unconventional Cooper pairing in exotic superconductors. No prior knowledge of quantum many-body theory is assumed, and the necessary mathematical concepts are introduced in a self-contained manner where needed.
The crucial demonstration that superfluidity was linked to Bose particles and Bose-Einstein condensation came after the discovery of He3 in 1949, which failed to show the characteristic A transition within a reasonable wide temperature interval around the critical temperature for the onset of superfluidity in He4. The idea of the bosonization of electrons due to their pairing, introduced by Ogg (1946) became very attractive as an explanation for superconductivity after Schafroth (1955) showed that a gas of charged bosons with charge 2e would indeed show a Meissner effect, which is one of the most crucial features of superconductors (see Chapter 1). However this phenomenological Bose-gas picture was condemned and later on practically forgotten because it was unable to account quantitatively for the critical parameters of the classical (low-temperature) superconductors. Using for Tc the Bose-Einstein condensation temperature Eq.(l.S) one obtains the utterly meaningless result Tc = lOOOO.R&s; with the atomic density of electron pairs ~ 1022cm~3 and with the effective mass m** = 2me. The failure of the Schafroth picture stems from a very large size £ of pairs in classical superconductors, which can be estimated from the uncertainty principle: The uncertainty of the momentum 8p is estimated from the uncertainty of the kinetic energy 8E ~ vpSp, which should be of the order of Tc, the only characteristic energy of the superconducting state. Therefore and turns out to be more than one micron for simple metals with Tc ~ IK and the Fermi velocity VF — I0scm/s. That means that pairs in classical superconductors overlap strongly and the Shafroth model of real space pairs is wrong. The finally successful theory for classical superconductors was formulated by Bardeen, Cooper and Schrieffer (1957). In this chapter we present the main points of the BCS theory, using the Bogoliubov transformation (1947,1958) for the weak-coupling regime and the Green&s;s function technique for the intermediate coupling in Chapter 3. More details will be found in the excellent books by Schrieffer(1965), De Gennes (1989) and Abrikosov, Gor&s;kov and Dzyaloshinskii (1963).
Superfluidity is one of the most striking manifestations of quantum mechanics at macroscopic scales, characterized by frictionless flow and the emergence of collective quantum phenomena. The theoretical foundation of superfluidity in fermionic systems was revolutionized by the Bardeen-Cooper-Schrieffer (BCS) theory, developed in 1957 to explain superconductivity in metals. This groundbreaking work provided a microscopic description of how attractive interactions between electrons near the Fermi surface can lead to the formation of Cooper pairs-correlated pairs of fermions that condense into a coherent quantum state. The BCS theory not only explained superconductivity but also laid the groundwork for understanding superfluidity in systems like liquid helium-3 and ultracold fermionic gases, becoming a cornerstone of condensed matter physics.
Abstract We have seen in the previous chapters that the concept of the macroscopic wave functionΨ(r), is central to understanding atomic Bose–Einstein condensates (BEC), superfluid He, and even superconductivity within the Ginzburg–Landau (GL) theory. But the connection between these ideas is not at all clear, since the atom condensates and He are bosonic systems, while super-conductivity is associated with the conduction electrons in metals which are fermions. The physical meaning of the GL order parameter was not explained until after 1957 when Bardeen Cooper and Schrieffer (BCS) published the first truly microscopic theory of superconductivity. Soon afterward the connection was finally established by Gor’ kov. He was able to show that, at least in the range of temperatures near Tc, the GL theory can indeed be derived from the BCS theory. Furthermore this provides a physical interpretation of the nature of the order parameter. Essentially it is describing a macroscopic wave function, or condensate, of Cooper pairs.
Various BCS-like pairing theories are still invariably used to describe the unusual superconducting/superfluid states and properties of condensed matters without clarifying the fermionic or bosonic nature of Cooper pairs and the relevant mechanisms of superconductivity and superfluidity. We show that the bosonization of Cooper pairs and the novel superconductivity and superfluidity resulting from the condensation of an attractive Bose gas of Cooper pairs into a superfluid state in high-Tc cuprates and other exotic systems occur under the condition εF≲2εA (where εF is the Fermi energy, εA is the energy of the effective attraction between fermions). We argue that the simple BCS criterion (i.e. formation of an energy gap on the Fermi surface) is insufficient for the occurrence of unconventional superconductivity (superfluidity) and the superconducting/superfluid transition in attractive Bose systems is more λ-like than the usual Bose–Einstein condensation. The new and specific criteria for unconventional superconductivity and superfluidity are formulated. Mean-field theory of the three- and two-dimensional superfluid Bose condensates of Cooper pairs describes reasonably well the novel superconducting states (i.e., two distinct superconducting phases below the bulk superconducting transition temperature Tc and a vortex-like state above Tc) and properties (such as λ-like transition at Tc, first-order phase transition and gapless bosonic excitations somewhat below Tc or even far below Tc) of high-Tc cuprates in full agreement with the experimental findings. The unusual superconducting/superfluid states and properties of heavy-fermion and organic compounds, Sr2RuO4, 3He, 4He and atomic Fermi gases are explained more clearly by this theory.