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Time-dependent quantum mechanics

Victor M. Galitski, Boris Mikhailovich Karnakov, Vladimir I Kogan, Victor M. Galitski

Published Feb 28, 2013• 5 citations
Publisher

Abstract

Abstract This chapter analyzes problems related to the Schrödinger representation (the motion of wave packets); time-dependent observables (constants of motion); time-dependent unitary transformations (the Heisenberg picture of motion); the time-dependent Green function; and quasi-stationary and quasi-energy states (the Berry phase).
DOI
10.1093/acprof:oso/9780199232710.003.0006

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Abstract The second chapter introduces the notion of wave functions and their equation of motion proposed by Erwin Schrödinger. The interpretation and normalization of the wave function are discussed, leading to the continuity equation. The chapter also introduces basic mathematical operations that can be carried out for wave functions and operators, describing e.g., how to calculate scalar products and commutators, as well as expectation values and variances of observables. With these tools at hand, Heisenberg’s uncertainty principle is re-examined, focusing on the example of a Gaussian wave packet, which is studied both in position space and momentum space. We also discuss the time evolution of general states and of the exemplary wave packet. Finally, we will see how classical physics is recovered as a limiting case of the quantum-mechanical description
This chapter demonstrates how one can find the time evolution of the operators from the knowledge of the time evolution of the state vector, and vice versa. It introduces a unitary operator and discusses the concept of a unitary transformation to show how one could transfer the time dependence from the state vectors to the operators. The possibility that either the state vectors or the operators can depend explicitly on time will lead to introduce the Schrodinger, Heisenberg, and interaction pictures. The chapter discusses the fundamental differences between these pictures. It also discusses the Ehrenfest theorem, which shows under which conditions quantum mechanics predicts the same results for measured physical quantities as classical physics. It illustrates unitary transformations of an arbitrary operator Â(t) which can depend explicitly on time. Quantum mechanics produces the same result as classical mechanics for a system in which particles are represented by well-localized wave functions.
In this chapter, the authors describe the Heisenberg picture of quantum mechanics by formally accomplishing a time-dependent transformation of state vectors and operators of the Schrodinger picture. Any new picture of quantum mechanics will be acceptable, if the Schrodinger state vectors and operators are subjected to a transformation, which does not alter: the spectrum of the eigenvalues of the operators and the scalar product of an arbitrary state vector with the eigenstate vectors. These two conditions are easily fulfilled by means of the unitary transformations. The authors show that a unitary operator represents an isomorph mapping of a certain unitary vector space onto itself. Since the physical quantities measured in the experiment are, in fact, a measure of the scalar product, as implied by the definition of the probability W through the scalar product in, it is clear that the predictions based upon the new, Heisenberg picture must be identical to those obtained in the Schrodinger picture.
The time-dependent Schrödinger equation forms the chapter's starting point. For a time-independent Hamiltonian, a quantum state may be time evolved with the standard, unitary time evolution operator. After obtaining this operator, an algorithm is provided by which a state may be time evolved, and measurement probabilities determined. A spin 1/2 example illustrates time evolution concretely. All this makes close contact with the discussion of unitary operators in Chapter 10. The time dependence of expectation values forms the next topic, followed by the concept of a constant of the motion, which is carefully contrasted with that of a stationary state. The energy-time uncertainty relations, which rest on a quite different conceptual footing than the ‘standard’ uncertainty relations, occupy the rest of the chapter. An example from spin 1/2 illustrates the energy-time uncertainty relations.
The time-independent Schrödinger equation represents a stationary-state equation. The stationary wave functions obtained so far are time independent. Their time-dependence is obtained by means of rather general arguments. Then, stationarystate functions are found. The next step in Newton’s and Euler’s representations of classical mechanics is (to derive) the equation of change of stationary-states. Here, Euler’s principles of stationary-state change are generalized to quantum-mechanical systems. This enables us to derive the quantum-mechanical equation of change of stationary-states. The time-independent Schrödinger equation, i.e, the equation of motion will follow in the next chapter.