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WORLD SCIENTIFIC eBooks

The Origin of Quantum Mechanics

Published Dec 10, 2014• 0 citations
Publisher

Abstract

Action at distance in Newtonian physics is replaced by finite propagation speeds in classical post-Newtonian physics.As a result, the differential equations of motion in Newtonian physics are replaced by functional differential equations, where the delay associated with the finite propagation speed is taken into account.Newtonian equations of motion, with post-Newtonian corrections, are often used to approximate the functional differential equations.Are the finite propagation speeds the origin of the quantum mechanics?In this work a simple atomic model based on a functional differential equation which reproduces the quantized Bohr atomic model is presented.As straightforward application of the result the fine structure of the hydrogen atom is approached.

DOI
10.1142/9789814635202_0007

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Action at distance in Newtonian physics is replaced by finite propagation speeds in classical post-Newtonian physics.As a result, the differential equations of motion in Newtonian physics are replaced by functional differential equations, where the delay associated with the finite propagation speed is taken into account.Newtonian equations of motion, with post-Newtonian corrections, are often used to approximate the functional differential equations.Are the finite propagation speeds the origin of the quantum mechanics?In this work a simple atomic model based on a functional differential equation which reproduces the quantized Bohr atomic model is presented.As straightforward application of the result the fine structure of the hydrogen atom is approached.
The initial purpose is to add two physical origins for the outstandingly clear mathematical description that Dirac has left in his Principles of Quantum Mechanics. The first is the “internal motion” in the wave function of the electron that is now expressed through dispersion dynamics; the second is the physical origin for mathematical quantization. Bohr’s model for the hydrogen atom was “the greatest single step in the development of the theory of atomic structure.” It leads to the Schrodinger equation which is non-relativistic, but which conveniently equates together momentum and electrostatic potential in a representation containing mixed powers. Firstly, we show how the equation is expansible to approximate relativistic form by applying solutions for the dilation of time in special relativity, and for the contraction of space. The adaptation is to invariant “harmonic events” that are digitally quantized. Secondly, the internal motion of the electron is described by a stable wave packet that implies wave-particle duality. The duality includes uncertainty that is precisely described with some variance from Heisenberg’s axiomatic limit. Harmonic orbital wave functions are self-constructive. This is the physical origin of quantization.
In this chapter, the Schrödinger equation is “derived” for particles that can be described by de Broglie waves. The Schrödinger equation is very different from the corresponding equation of motion in classical mechanics. In order to illustrate the fundamental differences between the two theories, one of the simplest problems of particle dynamics is solved in both Newtonian and quantum mechanics. This simple example also helps to show that quantum mechanics is the fundamental theory and classical mechanics is an approximation, a remarkably good approximation, when considering macroscopic objects. The solution of the Schrödinger equation is presented for a particle inside a box and the quantization condition is derived. The amazing possibility of quantum tunneling when a particle is incident on a barrier of height larger than the energy of the incident particle is also discussed. Finally the three-dimensional Schrödinger equation is solved for the hydrogen atom.
This chapter presents the origins of quantum mechanics. The story of how people hit on the highly non-intuitive world picture of quantum mechanics, in which the physical state of a system is represented by an element in an abstract linear space and its observable properties by operators in the space, is fascinating and exceedingly complicated. The much greater change from the classical world picture of Newtonian mechanics and general relativity to the quantum world picture came in many steps taken by many people, often against the better judgment of participants. There are three major elements in the story. The first is the experimental evidence that the energy of an isolated system can only assume special discrete or quantized values. The second is the idea that the energy is proportional to the frequency of a wave function associated with the system. The third is the connection between the de Broglie relation and energy quantization through the mathematical result that a wave equation with fixed boundary conditions allows only discrete quantized values of the frequency of oscillation of the wave function (as in the fundamental and harmonics of the vibration of a violin string).
Abstract The origins of atomic physics were entwined with the development of quantum mechanics itself ever since the first model of the hydrogen atom by Bohr. This introductory chapter surveys some of the early ideas, including Einstein’s treatment of the interaction of atoms with radiation, and a classical treatment of the Zeeman effect. These methods, developed before the advent of the Schrodinger equation, remain useful as an intuitive way of thinking about atomic structure and transitions between the energy levels. The ‘proper’ description in terms of atomic wave functions is presented in subsequent chapters.
The Eherenfest theorem states that Schrodinger representation of quantum mechanics (wave mechanics) reproduces Newton laws of motion in terms of expectation values. Remarkably, the contrary is considered elusive and, indeed, many authors have tried to obtain wave mechanics starting from other alternative frameworks of classical mechanics (for instance, Hamilton-Jacobi theory). Despite this common opinion, we present here a simple method to make Newtonian dynamics develop naturally into Schrodinger representation. The proof is based on the assumption of matter waves and is laid out in three fundamental steps. First, the role of classical density functions is underlined in view of their use to define constants of the motion for massive particles. Thanks to this preparatory step, density functions generate wave functions whose spatial and time variables obey Newton laws of motion. The resulting wave equation is defined in dependence on a parameter that plays the identical role of the constant K introduced by Schrodinger in the original formulation of his theory. In the final step, the classical wave equation is treated under the hypothesis of conservative forces common to the Eherenfest theorem and, after some algebra, the Schrodinger equation emerges by means of the identification of the classical momentum with de Broglie momentum of matter waves.