The initial purpose is to add two physical origins for the outstandingly clear mathematical description that Dirac has left in his Principles of Quantum Mechanics. The first is the “internal motion” in the wave function of the electron that is now expressed through dispersion dynamics; the second is the physical origin for mathematical quantization. Bohr’s model for the hydrogen atom was “the greatest single step in the development of the theory of atomic structure.” It leads to the Schrodinger equation which is non-relativistic, but which conveniently equates together momentum and electrostatic potential in a representation containing mixed powers. Firstly, we show how the equation is expansible to approximate relativistic form by applying solutions for the dilation of time in special relativity, and for the contraction of space. The adaptation is to invariant “harmonic events” that are digitally quantized. Secondly, the internal motion of the electron is described by a stable wave packet that implies wave-particle duality. The duality includes uncertainty that is precisely described with some variance from Heisenberg’s axiomatic limit. Harmonic orbital wave functions are self-constructive. This is the physical origin of quantization.
The initial purpose is to add two physical origins for the outstandingly clear mathematical description that Dirac has left in his Principles of Quantum Mechanics. The first is the “internal motion” in the wave function of the electron that is now expressed through dispersion dynamics; the second is the physical origin for mathematical quantization. Bohr’s model for the hydrogen atom was “the greatest single step in the development of the theory of atomic structure.” It leads to the Schrodinger equation which is non-relativistic, but which conveniently equates together momentum and electrostatic potential in a representation containing mixed powers. Firstly, we show how the equation is expansible to approximate relativistic form by applying solutions for the dilation of time in special relativity, and for the contraction of space. The adaptation is to invariant “harmonic events” that are digitally quantized. Secondly, the internal motion of the electron is described by a stable wave packet that implies wave-particle duality. The duality includes uncertainty that is precisely described with some variance from Heisenberg’s axiomatic limit. Harmonic orbital wave functions are self-constructive. This is the physical origin of quantization.
This paper derives the non-relativistic time-dependent Schrödinger equation as the logically unavoidable dynamical law for de Broglie matter waves, extending the reconstruction begun in the companion work “The Logical Origin of the de Broglie Matter Wave and its Physical Meaning (the Born Rule)” (Chan, 2026). Starting from the same minimal premises—continuous position in real space, Fourier conjugacy (and the logical uncertainty principle), translation invariance via Noether’s theorem, and probability conservation via statistical energy flux—the Schrödinger equation follows deductively once norm preservation and classical non-relativistic correspondence are enforced. The derivation proceeds in clear stages: Plane-wave solutions for free particles and constant potentials, Quadratic dispersion relation from classical kinematics, Exact local plane-wave structure (defined via phase gradients) that must hold at every point for any smooth wave function, The unique linear differential operator of order ≤ 2 that consistently “glues” these local structures across smooth external potentials V(x,t) while preserving the L²-norm (unitarity). No canonical quantization, operator promotion, commutation relations, or postulated wave equations are used. The Born rule is taken as already established from the prior paper and serves only to constrain unitary evolution. The Schrödinger equation thus emerges not as an empirical postulate or convenient ansatz, but as the mathematically and symmetrically forced description of indivisible particles propagating in continuous, translationally invariant (or smoothly perturbed) space. Domain of validity and natural limitations (non-relativistic kinematics, smooth potentials, single-particle/mean-field regime, closed-system unitarity) are explicitly delineated.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.
A series of successive quantizations is considered, starting with the quantization of a non-relativistic or relativistic point particle: (1) quantization of a particle’s position, (2) quantization of wave function, (3) quantization of wave functional. The latter step implies that the wave packet profiles forming the states of quantum field theory are themselves quantized, which gives new physical states that are configurations of configurations. In the procedure of quantization, instead of the Schrödinger first-order equation in time derivative for complex wave function (or functional), the equivalent second-order equation for its real part was used. In such a way, at each level of quantization, the equation a quantum state satisfies is just like that of a harmonic oscillator, and wave function(al) is composed in terms of the pair of its canonically conjugated variables.
We propose that the Schrodinger equation results from applying the classical wave equation to describe the physical system in which subatomic particles play random motion, thereby leading to quantum mechanics. The physical reality described by the wave function is subatomic particle moving randomly. Therefore, the characteristics of quantum mechanics have a dual nature, one of them is the deterministic nature carried on from classical physics, and the other is the probabilistic nature coined by particle's random motion. Based on this model, almost all of open questions in quantum mechanics can be explained consistently, which include the particle-wave duality, the principle of quantum superposition, the interference pattern of double-slit experiments, and the boundary between the classical world and the quantum world. The current quantum mechanics is a mixture of matrix mechanics and wave mechanics, which are sharply conflicting in principle. Matrix mechanics treats quantum particles as classical particles with fixed relation between the particle's position and its momentum. The matrix mechanics, in fact, belongs to the old quantum theory. Both Born's non-commutative relation and Heisenberg uncertainty relation originate from matrix mechanics. However, in wave mechanics, there is no any fixed relation between the particle's position and its momentum, and the particle's position and its momentum belong to immeasurable physical quantities. Therefore, there is no need for non-commutative relation and uncertainty relation in wave mechanics.
Dispersion dynamics applies wave-particle duality, together with Maxwell’s electromagnetism, and with quantization E = hν = ħω (symbol definitions in footnote) and p = h/λ = ħk, to special relativity E2 = p2c2 + m2c4. Calculations on a wave-packet, that is symmetric about the normal distribution, are partly conservative and partly responsive. The complex electron wave function is chiefly modelled on the real wave function of an electromagnetic photon; while the former concept of a “point particle” is downgraded to mathematical abstraction. The computations yield conclusions for phase and group velocities, vp⋅vg = c2 with vp ≥ c because vg ≤ c, as in relativity. The condition on the phase velocity is most noticeable when p≪mc. Further consequences in dispersion dynamics are: derivations for ν and λ that are consistently established by one hundred years of experience in electron microscopy and particle accelerators. Values for vp = νλ = ω/k are therefore systematically verified by the products of known multiplicands or divisions by known divisors, even if vp is not independently measured. These consequences are significant in reduction of the wave-packet by resonant response during interactions between photons and electrons, for example, or between particles and particles. Thus the logic of mathematical quantum mechanics is distinguished from experiential physics that is continuous in time, and consistent with uncertainty principles. [Footnote: symbol E = energy; h = Planck’s constant; ν = frequency; ω = angular momentum; p = momentum; λ = wavelength; k = wave vector; c = speed of light; m = particle rest mass; vp = phase velocity; vg = group velocity].
Assuming a background in basic classical physics, multivariable calculus, and differential equations, A Concise Introduction to Quantum Mechanics provides a self-contained presentation of the mathematics and physics of quantum mechanics. The relevant aspects of classical mechanics and electrodynamics are reviewed, and the basic concepts of wave-particle duality are developed as a logical outgrowth of experiments involving blackbody radiation, the photoelectric effect, and electron diffraction. The Copenhagen interpretation of the wave function and its relation to the particle probability density is presented in conjunction with Fourier analysis and its generalization to function spaces. These concepts are combined to analyze the system consisting of a particle confined to a box, developing the probabilistic interpretation of observations and their associated expectation values. The Schrödinger equation is then derived by using these results and demanding both Galilean invariance of the probability density and Newtonian energy-momentum relations. The general properties of the Schrödinger equation and its solutions are analyzed, and the theory of observables is developed along with the associated Heisenberg uncertainty principle. Basic applications of wave mechanics are made to free wave packet spreading, barrier penetration, the simple harmonic oscillator, the Hydrogen atom, and an electric charge in a uniform magnetic field. In addition, Dirac notation, elements of Hilbert space theory, operator techniques, and matrix algebra are presented and used to analyze coherent states, the linear potential, two state oscillations, and electron diffraction. Applications are made to photon and electron spin and the addition of angular momentum, and direct product multiparticle states are used to formulate both the Pauli exclusion principle and quantum decoherence. The book concludes with an introduction to the rotation group and the general properties of angular momentum.