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Oxford University Press eBooks

2. The light dawns

John Charlton Polkinghorne

Published Aug 29, 2002• 0 citations
Publisher

Abstract

‘The light dawns’ describes the period in 1925 and 1926 when modern quantum theory became fully fledged. German theorist Werner Heisenberg, working on spectroscopy, developed matrix mechanics. At the same time, Prince Louis de Broglie and then Erwin Schrödinger developed a second account of quantum theory — wave mechanics. The Schrödinger equation is the fundamental dynamical equation of quantum theory. Paul Dirac, in Cambridge, set out the general principles in his Principles of Quantum Mechanics, published in 1930. The superposition principle and double slits experiment are described and probabilities, observables, and the uncertainty principle explained. Finally, Niels Bohr's idea of complementarity and quantum logic are discussed.

DOI
10.1093/actrade/9780192802521.003.0002

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‘The light dawns’ describes the period in 1925 and 1926 when modern quantum theory became fully fledged. German theorist Werner Heisenberg, working on spectroscopy, developed matrix mechanics. At the same time, Prince Louis de Broglie and then Erwin Schrödinger developed a second account of quantum theory — wave mechanics. The Schrödinger equation is the fundamental dynamical equation of quantum theory. Paul Dirac, in Cambridge, set out the general principles in his Principles of Quantum Mechanics, published in 1930. The superposition principle and double slits experiment are described and probabilities, observables, and the uncertainty principle explained. Finally, Niels Bohr's idea of complementarity and quantum logic are discussed.
The important discoveries and events that occurred in the development of quantum mechanics may be ordered as follows: Blackbody radiation formulated by Max Planck in 1901. Photoelectric effect interpreted by Albert Einstein in 1905. Model of the atom proposed by Ernest Rutherford in 1911. Quantum theory of atomic spectra developed by Niels Bohr in 1913. Photon–electron scattering experiments done by Arthor Holly Compton in 1922. Exclusion principle proposed by Wolfgang Pauli in 1925. Matter waves proposed by Prince Louis Victor de Broglie in 1925. Wave equation proposed by Erwin Shrödinger in 1926. Electron diffraction experiments done by Clinton Joseph Davisson and L.H. Germer in 1927. Uncertainty principle proposed by Werner Karl Heisenberg in 1927. Interpretation of the wave function done by Max Born in 1927. Relativistic wave equation proposed by Paul A. M. Dirac in 1928.
Till 1925 the idea of what the quantum theory would be was unknown. During 1925 three different but equivalent versions of quantum theory were proposed – Schrödinger-proposed wave mechanics; Heisenberg-developed matrix mechanics and Dirac-introduced operator theory. Considering the de Broglie’s matter waves Erwin Schrödinger, an Austrian physicist, argued that if a particle like an electron behaves as a wave then the equation of wave motion could be successfully applied to it. He postulated a function varying in both space and time in a wave-like manner (hence called wave function and denoted it as ψ). This function is generally complex and assumed to contain information about a system. Schrödinger set up a linear and time-dependent wave-like equation, called Schrödinger wave equation, to describe the wave aspect of a particle taking account of de Broglie’s relation for wavelength. Physically, |ψ(X, t)|2, where ψ(X, t) is the solution of the Schrödinger equation, is interpreted as position probability density. That is, |ψ(X, t)|2 is the probability density of observing a particle at position X at time t. ψ does not give exact outcomes of observations but helps us to know all possible events and their probabilities . Further, the probability interpretation allows us to find the average or expected result of a set of measurements on a quantum system.
The laws of quantum mechanics were formulated in the year 1925 through the work of Werner Heisenberg, followed by Max Born, Pascual Jordan, Paul Dirac, and Wolfgang Pauli. A separate but equivalent approach was independently developed by Erwin Schrödinger in early 1926. The laws governing quantum mechanics were highly mathematical and their aim was to explain many unresolved problems within the framework of a formal theory. The conceptual foundation emerged in the subsequent 2–3 years that indicated how radically different the new laws were from classical physics. In this chapter some of these salient features of quantum mechanics are discussed. The topics include the quantization of energy, wave–particle duality, the probabilistic nature of quantum mechanics, Heisenberg uncertainty relations, Bohr’s principle of complementarity, and quantum superposition and entanglement. This discussion should indicate how different and counterintuitive its fundamentals are from those of classical physics.
Abstract In addition to recounting some contemporary scientific history, Chapter 6 describes the hypothesis that matter, like light, can display wavelike properties, and the creation of the various formulations of quantum mechanics. That matter could have a wavelength was proposed in 1924 by Louis de Broglie, who presented a specific formula for calculating it, one that was verified experimentally in 1927. However, de Broglie’s hypothesis was overshadowed by the creation of three versions of quantum mechanics in 1925/26. The first, denoted matrix mechanics, was proposed by Werner Heisenberg. It was quickly and successfully applied by Wolfgang Pauli to the hydrogen atom. Paul Dirac introduced the next version, which was followed by that of Erwin Schrödinger via a wave equation whose solutions, denoted wave functions, were soon interpreted byMax Born to be related to the probability that certain outcomes or events will occur: classical-physics determinism was thereby removed from quantum mechanics.
Our modern understanding of atoms, molecules, solids, atomic nuclei, and elementary particles is largely based on quantum mechanics. Quantum mechanics grew in the mid-1920s out of two independent developments: the matrix mechanics of Werner and the wave mechanics of Erwin Schrödinger. For the most part this chapter follows the path of wave mechanics, which is more convenient for all but the simplest calculations. The general principles of the wave mechanical formulation of quantum mechanics are laid out and provide a basis for the discussion of spin, identical particles. and scattering processes. The general principles are supplemented with the canonical formalism to work out the Schrödinger equation for charged particles in a general electromagnetic field. The chapter ends with the unification of the approaches of wave and matrix mechanics by Paul Dirac, and a modern approach, known as Hilbert space, is briefly described.
This article discusses the history of quantum physics, beginning with an analysis of the process through which a community of quantum theorists and experimentalists came into being. In particular, it traces the roots and fruits of Max Planck’s papers in irreversible processes in nature. It proceeds by exploring the origin and subsequent development of Niels Bohr’s so-called ‘planetary model’ of the atom, focusing on the extension of the model by Arnold Sommerfeld and members of his school as well to Bohr’s use of his principles of correspondence and adiabatic invariance. It also considers the post-war years, as the problems of atomic spectroscopy sparked the development of new methodological approaches to quantum theory. Finally, it offers a history of the two distinct new forms of quantum mechanics put forward in the mid-1920s: Werner Heisenberg, Max Born, and Pascual Jordan’s matrix mechanics, and Erwin Schrödinger’s wave mechanics.