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Oxford University Press eBooks

Fundamentals of Quantum Mechanics

Muhammad Suhail Zubairy

Published May 7, 2020• 6 citations
Publisher

Abstract

The laws of quantum mechanics were formulated in the year 1925 through the work of Werner Heisenberg, followed by Max Born, Pascual Jordan, Paul Dirac, and Wolfgang Pauli. A separate but equivalent approach was independently developed by Erwin Schrödinger in early 1926. The laws governing quantum mechanics were highly mathematical and their aim was to explain many unresolved problems within the framework of a formal theory. The conceptual foundation emerged in the subsequent 2–3 years that indicated how radically different the new laws were from classical physics. In this chapter some of these salient features of quantum mechanics are discussed. The topics include the quantization of energy, wave–particle duality, the probabilistic nature of quantum mechanics, Heisenberg uncertainty relations, Bohr’s principle of complementarity, and quantum superposition and entanglement. This discussion should indicate how different and counterintuitive its fundamentals are from those of classical physics.

DOI
10.1093/oso/9780198854227.003.0005

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The laws of quantum mechanics were formulated in the year 1925 through the work of Werner Heisenberg, followed by Max Born, Pascual Jordan, Paul Dirac, and Wolfgang Pauli. A separate but equivalent approach was independently developed by Erwin Schrödinger in early 1926. The laws governing quantum mechanics were highly mathematical and their aim was to explain many unresolved problems within the framework of a formal theory. The conceptual foundation emerged in the subsequent 2–3 years that indicated how radically different the new laws were from classical physics. In this chapter some of these salient features of quantum mechanics are discussed. The topics include the quantization of energy, wave–particle duality, the probabilistic nature of quantum mechanics, Heisenberg uncertainty relations, Bohr’s principle of complementarity, and quantum superposition and entanglement. This discussion should indicate how different and counterintuitive its fundamentals are from those of classical physics.
This article discusses the history of quantum physics, beginning with an analysis of the process through which a community of quantum theorists and experimentalists came into being. In particular, it traces the roots and fruits of Max Planck’s papers in irreversible processes in nature. It proceeds by exploring the origin and subsequent development of Niels Bohr’s so-called ‘planetary model’ of the atom, focusing on the extension of the model by Arnold Sommerfeld and members of his school as well to Bohr’s use of his principles of correspondence and adiabatic invariance. It also considers the post-war years, as the problems of atomic spectroscopy sparked the development of new methodological approaches to quantum theory. Finally, it offers a history of the two distinct new forms of quantum mechanics put forward in the mid-1920s: Werner Heisenberg, Max Born, and Pascual Jordan’s matrix mechanics, and Erwin Schrödinger’s wave mechanics.
Planck's introduction of the quantum of action in 1900 was followed by 25 years of trial and error in quest of the understanding of the quantum world; different ideas and directions had to be pursued until the path leading to the elementary quantum theory was discovered. Radical changes away from traditional perceptions about natural phenomena were necessary, the entire system of basic concepts in classical physics had to be abandoned and replaced by a new mode of thought. Continuity and determinism of classical laws were no longer applicable on the quantum scale, where dynamical behaviour proceeds by discontinuous and statistical quantum transitions. Albert Einstein laid the essential foundations for the new concept; Max Born made the decisive step further leading to the breakthrough in 1925. The development of the ideas, which eventually resulted in the elementary quantum theory in 1925/26, will be described, relying on original publications and letters written during that period in time by the major contributors. The fundamental laws of Quantum Theory derived by Max Born and Pascual Jordan may mathematically be represented in many different ways, and particular emphasis is given to the distinction between physical content and mathematical representation.
This chapter presents the origins of the transformation theory and related concepts. It shows how, in 1925, a procedure initiated by Werner Heisenberg was developed by himself, Max Born, Pascual Jordan, and a little later by Paul Dirac, into a new system of quantum theory—the first complete system of quantum theory which physics has possessed. A little later Erwin Schrödinger developed the “wave mechanics” from an entirely different starting point. This accomplished the same ends, and soon proved to be equivalent to the Heisenberg, Born, Jordan, and Dirac system. On the basis of the Born statistical interpretation of the quantum theoretical description of nature, it was possible for Dirac and Jordan to join the two theories into one, the “transformation theory,” in which they make possible a grasp of physical problems which is especially simple mathematically.
High Resolution Image Download MS PowerPoint Slide In July 1925, Werner Heisenberg submitted a paper to Zeitschrift für Physik entitled ‘On quantum-theoretical reinterpretation of kinematic and mechanical relationships’, thus giving birth to quantum mechanics. In the following year, building on de Broglie’s wave-particle duality, Erwin Schrödinger developed wave mechanics, and soon, Max Born provided a probabilistic interpretation of the wave function. The theory was further enriched by the exclusion principle of Wolfgang Pauli and the uncertainty principle of Heisenberg, which ultimately led to the development of relativistic quantum mechanics by Dirac. The Copenhagen Interpretation created a probabilistic framework for understanding the theory. Over the past century, quantum mechanics has paved the way for advances in quantum field theory, computing, and modern technologies. This historical narrative provides insights into the complex discovery process that led to the development of quantum mechanics, which can potentially guide novel breakthroughs amid challenging conceptual struggles, as seen in the field of artificial intelligence today.
A hundred years ago, physics underwent one of its most dramatic transformations - a paradigm shift that fundamentally changed our understanding of nature. Over the course of several revolutionary months in 1925 and early 1926, quantum mechanics emerged as a new, foundational theory of the microscopic world. With the publication of key papers by Werner Heisenberg and Erwin Schrödinger, the theoretical framework was established that radically redefined our perception of physical reality. These works demonstrated that atoms and subatomic particles do not obey the laws of classical mechanics, but instead follow entirely new, quantum laws. Born in those intense months, quantum mechanics became one of the cornerstones of modern physics and a lasting source of inspiration in both theoretical and applied sciences. This paradigmatic shift opened new avenues of research and laid the groundwork for scientific discoveries that continue to shape our understanding of nature today. This paper is dedicated to those pivotal historical moments - the months in which science made one of its deepest leaps and most consequential strides in comprehending the world.
At the beginning of the twentieth century, it became clear that microscopic particles do not obey Newton's laws of classical mechanics. The idea of light quanta was at odds with the established wisdom that light is a wave phenomenon, of course, but no other explanation of the photoelectric effect seemed possible. The next step in the development of quantum mechanics was taken by Niels Bohr, who introduced postulates about the discreteness of the energy of the bound electrons in an atom similar to the discreteness of the energy of light quanta. Modern quantum mechanics was founded by Werner Heisenberg, Max Born, Erwin Schroedinger, Paul Adrian Maurice Dirac, Wolfgang Pauli, Enrico Fermi, and others. In quantum mechanics, it is in general fundamentally impossible to determine the exact outcome of an experiment; one can only determine the probability of any given outcome.