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Lecture notes in chemistry

A remark about the construction of the operators in quantum mechanics

André Julg

Published Jan 1, 1998• 0 citations
Publisher
DOI
10.1007/978-3-642-48939-6_3

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We postulate a formulation of quantum mechanics which is based solely on a quasi-probability function on the classical phase space. We then show that this formulation is equivalent to the standard formulation, and that the quasi-probability function is exactly analogous to the density matrix of Dirac and von Neumann. We investigate the theory of measurement in this formulation and derive the following remarkable results. As is well known, the correspondence between classical functions of both the position and conjugate momentum and quantum mechanical operators is ambiguous because of noncommutativity. We show that the solution of this correspondence problem is completely equivalent to the solution of the eigenvalue problem. This result enables us to give a constructive method to compute eigenvalues and eigenfunctions.
The concept of position is a basic one in our construction of a model of thenphysical world: yet the theory of localisation in quantum mechanics is fraughtnwith difficulties, especially in the relativistic case. A strictly localised state forna nonrelativistic particle cannot be described by an ordinary function. In thenrelativistic case the problems are manifold. For a free electron, using the Diracnposition operator x, we cannot construct positive-energy states which localisenthe particle within a compact region. Furthermore it has been suggested that anconsistent one-particle description of localisation on a scale small compared tonthe Compton wavelength of the particle is ruled out because pair-productionnwould take place. These matters are dicussed at greater length in Chaptern1, where several proposed localisation schemes (that is, sets of definitions ofnlocalised states and position operators) are reviewed: none of these is deemednwholly satisfactory. Introductory remarks are also made in this chapter aboutnthe remarkable phenomenon of 'probability backflow', which is discussed further below, and which is relevant to our discussion of localisation.In Chapter 2 we show that while strict localisation of the free Dirac particle is not describable within the usual mathematical formalism, in terms of Dirac's position operator x it is possible to describe sequences of positive-energy states whose spread Dx = ((x -- x0)2) about a point X0 approaches zero.In Chapter 3 the component states of these sequences are used as the basis of a full causally well-behaved solution to the localisation problem for the free electron, with natural space-time transformation properties. It is shown that although x is not an observable in the usual sense, the four-vector density (p(x, t), j(x, t)/c) is observable, and can be localised arbitrarily precisely about any point in space, at any instant of time, using only positive-energy states. A suitable spin operator can be diagonalised at the same time.n n