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Physical Review

Formulation of Quantum Mechanics Based on the Quasi-Probability Distribution Induced on Phase Space

George Allen Baker Jr.

Published Mar 15, 1958• 242 citations
Publisher

Abstract

We postulate a formulation of quantum mechanics which is based solely on a quasi-probability function on the classical phase space. We then show that this formulation is equivalent to the standard formulation, and that the quasi-probability function is exactly analogous to the density matrix of Dirac and von Neumann. We investigate the theory of measurement in this formulation and derive the following remarkable results. As is well known, the correspondence between classical functions of both the position and conjugate momentum and quantum mechanical operators is ambiguous because of noncommutativity. We show that the solution of this correspondence problem is completely equivalent to the solution of the eigenvalue problem. This result enables us to give a constructive method to compute eigenvalues and eigenfunctions.

DOI
10.1103/physrev.109.2198

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We postulate a formulation of quantum mechanics which is based solely on a quasi-probability function on the classical phase space. We then show that this formulation is equivalent to the standard formulation, and that the quasi-probability function is exactly analogous to the density matrix of Dirac and von Neumann. We investigate the theory of measurement in this formulation and derive the following remarkable results. As is well known, the correspondence between classical functions of both the position and conjugate momentum and quantum mechanical operators is ambiguous because of noncommutativity. We show that the solution of this correspondence problem is completely equivalent to the solution of the eigenvalue problem. This result enables us to give a constructive method to compute eigenvalues and eigenfunctions.
The problem of quantization in the phase-space formulation of quantum mechanics is considered. An integral equation for the phase-space eigenfunctions is derived which is equivalent to the standard eigenvalue equation for a quantum mechanical operator. A differential form is also given. A variational principle is derived for quasiprobability distributions. It is shown that the expected value of the classical Hamiltonian calculated with a trial quasiprobability distribution will be greater than the ground state energy only if the distribution is chosen from a certain class of functions. The notion of ψ-representability is introduced to classify these functions. They represent distributions which correspond to possible quantum mechanical states. Also, a general relation is given between different distribution functions.
A set of quasi-probability distribution functions which give the correct quantum mechanical marginal distributions of position and momentum is studied. The phase-space distribution does not have to be bilinear in the state function. The Wigner distribution is a special case. A general relationship between the phase-space distribution functions and the rule of associating classical quantities to quantum mechanical operators is derived. This allows the writing of correspondence rules at will,of which the ones presently known are particular cases. The dynamics and other properties of the generalized phase-space distribution are considered.
For physical systems with Hamiltonians analytic in the position and momentum operators the diagonal matrix elements of the density operator in the coherent state representation may be considered as a phase-space probability measure in the stochastic formulation of quantum mechanics. The correspondence rule relating quantum-mechanical observables to ordinary functions in phase space is obtained. It is shown that the dynamics of the time-dependent phase-space probability densities is again representable in the form of a stochastic process.
The phase space formulation of quantum mechanics is equivalent to standard quantum mechanics where averages are calculated by way of phase space integration as in the case of classical statistical mechanics. We derive the quantum hierarchy equations, often called the contracted Schrödinger equation, in the phase space representation of quantum mechanics which involves quasi-distributions of position and momentum. We use the Wigner distribution for the phase space function and the Moyal phase space eigenvalue formulation to derive the hierarchy. We show that the hierarchy equations in the position, momentum, and position-momentum representations are very similar in structure. © 2017 Wiley Periodicals, Inc.
This paper deals with certain aspects of the phase-space formulation of quantum mechanics. Noting the ambiguities involved in quantizing the classical phase-space dynamics, a generalized quantum-mechanical phase space is introduced in terms of eigenvalues of two mutually incompatible complete sets of operators. General definitions are given for the phase-space distribution function corresponding to a given abstract state of the system and the phase-space function for an arbitrary operator. Our formulation goes over to the Wigner formulation when the complete sets correspond to position and momentum operators in Cartesian coordinates. Explicit examples are discussed with use of action-angle and polar coordinates for simple one-, two-, and three-dimensional systems. Symmetry changes in phase space are discussed by applying Gel'fand-Levitan transformations and it is shown that, in general, the degeneracies of motion in phase space are not reflected in the energy eigenvalues.
A quantum mechanical representation suitable for studying the time evolution of quantum densities in phase space is proposed and examined in detail. This representation on ℒ2 (2) phase space is based on definitions of the operators P̂ and Q̂ in phase space that satisfy various correspondences for the Liouville equation in classical and quantum phase space, as well as quantum position and momentum ℒ2 (1) spaces. The definitions presented here, P̂=p/2−iℏ∂/∂q and Q̂=q/2+iℏ∂/∂p, are related to definitions that have been recently proposed [J. Chem. Phys. 93, 8862 (1990)]. The resulting quantum phase space representation shares many of the mathematical properties of usual representations in coordinate and momentum spaces. Within this representation, time evolution equations for complex-valued functions (wave functions) and their square magnitudes (distribution functions) are derived, and it is shown that the coordinate and momentum space time evolution equations can be recovered by a simple Fourier projection. The phase space quantum probability conservation equation obtained is a good illustration of the quantization rule that requires one to replace the classical Poisson bracket between the Hamiltonian and the probability density with the quantum commutator between the corresponding operators. The possible classical analogs to quantum probabilities densities are also considered and some of the present results are illustrated for the dynamics of the coherent state.