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Journal of the Korean Physical Society

Exact partition functions of the ising model on L × L square lattices with free boundary conditions up to L = 22

Seung‐Yeon Kim

Published Jan 1, 2013• 2 citations
Publisher

Abstract

The exact partition functions of the Ising model on L × L square lattices with free boundary conditions are evaluated up to L = 22 for the first time by using a microcanonical transfer matrix and counting all possible spin states. The total number of states is 2 22×22 = 2 484 ≈ 5.0 × 10 145 for L = 22. Using the partition function zeros in the complex temperature plane of the Ising model on L × L square lattices with free boundary conditions, we analyze the critical behavior of the square-lattice Ising antiferromagnet and compare them with the results for periodic boundary conditions (the most popular boundary conditions). Our results show clearly that free boundary conditions are much more efficient than periodic boundary conditions in the study of an antiferromagnet.

DOI
10.3938/jkps.62.214

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The exact partition functions of the Ising model on L × L square lattices with free boundary conditions are evaluated up to L = 22 for the first time by using a microcanonical transfer matrix and counting all possible spin states. The total number of states is 2 22×22 = 2 484 ≈ 5.0 × 10 145 for L = 22. Using the partition function zeros in the complex temperature plane of the Ising model on L × L square lattices with free boundary conditions, we analyze the critical behavior of the square-lattice Ising antiferromagnet and compare them with the results for periodic boundary conditions (the most popular boundary conditions). Our results show clearly that free boundary conditions are much more efficient than periodic boundary conditions in the study of an antiferromagnet.
The exact integer values for the density of states of the Ising model on an equilateral triangular lattice with free boundary conditions are evaluated up to L = 24 spins on a side for the first time by using the microcanonical transfer matrix. The total number of states is 2 N s = 2300 ≈ 2.037 × 1090 for L = 24, where N s = L(L+1)/2 is the number of spins. Classifying all 2300 spin states according to their energy values is an enormous work. From the density of states, the exact partition function zeros in the complex temperature plane of the triangular-lattice Ising model are evaluated. Using the density of states and the partition function zeros, we investigate the properties of the triangularlattice Ising antiferromagnet. The scaling behavior of the ground-state entropy and the form of the correlation length at T = 0 are studied for the triangular-lattice Ising antiferromagnet with free boundary conditions. Also, the scaling behavior of the Fisher edge singularity is investigated.
The exact integer values for the density of states of the Ising model on an L×L square lattice with self-dual boundary conditions are evaluated up to L = 22 for the first time by counting all possible spin states (enormous 2 485 ≈ 10 146 states for L = 22). The exact partition function zeros in the complex temperature plane, very sensitive indicators for phase transitions and critical phenomena, are obtained by using the density of states. From the behavior of the partition function zeros, the shift exponent λ of the square-lattice Ising model with self-dual boundary conditions is accurately and precisely estimated to be λ = 2.0000000(2), clearly indicating λ = 2.
The square-lattice Ising model is the simplest system showing phase transitions (the transition between the paramagnetic phase and the ferromagnetic phase and the transition between the paramagnetic phase and the antiferromagnetic phase) and critical phenomena at finite temperatures. The exact solution of the squarelattice Ising model with free boundary conditions is not known for systems of arbitrary size. For the first time, the exact solution of the Ising model on the square lattice with free boundary conditions is obtained after classifying all ) spin configurations with the microcanonical transfer matrix. Also, the phase transitions and critical phenomena of the square-lattice Ising model are discussed using the exact solution on the square lattice with free boundary conditions.
The properties of the antiferromagnetic Ising model in the critical magnetic field are investigated by evaluating exactly its all possible ground states on L × L square lattice (L = 4∼16) with free boundary conditions for the first time. From the exact integer values for the number of ground states Ωc(L) on L × L square lattice, the exact ground-state entropy (in unit of the Boltzmann constant kB) per volume sc(L) = L−2lnΩc(L) and the exact ground-state magnetization mc(L;T = 0) = L−2〈Σiσi〉 are calculated in the critical magnetic field, where σi is the magnetic spin on a lattice site i. The values of the ground-state entropy sc(L) and the ground-state magnetization mc(L), in the limit L → ∞, are accurately estimated to be sc/kB = 0.40750±0.00108 and mc = 0.54696±0.00065. In addition, for the first time, we estimate the values of the scaling exponents ωs and ωm, controlling the finite-size scaling behaviors of the ground-state entropy and the ground-state magnetization as sc−sc(L)∼L−ωs and mc−mc(L)∼L−ωm respectively. Our results show clearly that ωs = ωm = 1.
The microcanonical transfer matrix is used to evaluate the exact integer values for the number of states $\ensuremath{\Omega}(E,M)$, as a function of energy EEE and magnetization MMM, of the Ising model in an external magnetic field HHH on $L\ifmmode\times\else\texttimes\fi{}2L$ honeycomb lattices (L=6,8,…,14)(L=6,8,\dots{},14)(L=6,8,…,14) and (due to memory limitations) the exact real values for $\overline{\ensuremath{\Omega}}(a,M)={\ensuremath{\sum}}_{E}\ensuremath{\Omega}(E,M){a}^{E}$ (L=16,…,22)(L=16,\dots{},22)(L=16,…,22), where $a={e}^{2\ensuremath{\beta}J}$. Given $\ensuremath{\Omega}(E,M)$ or $\overline{\ensuremath{\Omega}}(a,M)$, the exact partition functions $Z(a,x)={\ensuremath{\sum}}_{E,M}\ensuremath{\Omega}(E,M){a}^{E}{x}^{M}={\ensuremath{\sum}}_{M}\overline{\ensuremath{\Omega}}(a,M){x}^{M}$, where $x={e}^{\ensuremath{-}2\ensuremath{\beta}H}$, are obtained. From the exact partition functions, the precise distributions of the partition function zeros in the complex xxx plane of the honeycomb-lattice Ising antiferromagnet in a uniform external magnetic field, where the famous circle theorem for the partition function zeros of the Ising ferromagnet is not applicable, are determined. In addition, the critical points xcp(a){x}_{cp}(a)xcp​(a) and the magnetic scaling exponents yh(a){y}_{h}(a)yh​(a) of the honeycomb-lattice Ising antiferromagnet in a uniform magnetic field are estimated using its partition function zeros in the complex xxx plane. Our results for the critical points are also compared to those of the two different closed-form approximations.