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Cambridge University Press eBooks

Decay scattering

William C. Schieve, Lawrence Paul Horwitz

Published Apr 16, 2009• 0 citations
Publisher

Abstract

Basic notions and theWigner–Weisskopf theory Although the notions of bound states, scattering and quantum transitions are well defined in the quantum theory, the description of an unstable system, involved in the process of decay, has remained an outstanding issue for many years. The problem is fundamental, since it concerns the nature of irreversible processes, one of the most important issues in statistical mechanics and the theme that is central to this book. The theory of decay is intimately connected with scattering theory and necessarily contains mathematical ideas and methods. We shall try to explain these points carefully as we get to them. We treat elsewhere in the book the ideas of Boltzmann, Van Hove and Prigogine on irreversible phenomena. The tools that are developed there are basically approximate, although very useful. One can argue that the basic rigorous characteristic of an irreversible process is that, as represented in terms of the evolution of a state in the Hilbert space of the quantum theory, it must be a semigroup. This type of evolution, resulting in an operation Z ( t ) on a state ψ , should satisfy the property Z ( t 2 ) Z ( t 1 ) = Z ( t 1 + t 2 ). (17.1) The argument is as follows. If the system evolves in time t 1 and is stopped, then evolves further at time t 2 , since the process has no memory, the total evolution should be as if the system evolved from the initial state to a state at t 1 + t 2 independently of the fact that it was done in two stages (Piron, 1976). Since the process is irreversible, the operator Z ( t ) may have no inverse. Such an evolution is called a semigroup . As we shall see, it is not possible to obtain such an evolution law in the framework of the standard quantum theory (Horwitz et al. , 1971), but recently much work has been done, and methods have been developed, based on ideas of Sz.-Nagy and Foias (1976), such as the theory of Lax and Phillips (1967) and its extension to the quantum theory (Strauss et al. , 2000) in which semigroup evolution can be achieved.

DOI
10.1017/cbo9780511626555.018

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Basic notions and theWigner–Weisskopf theory Although the notions of bound states, scattering and quantum transitions are well defined in the quantum theory, the description of an unstable system, involved in the process of decay, has remained an outstanding issue for many years. The problem is fundamental, since it concerns the nature of irreversible processes, one of the most important issues in statistical mechanics and the theme that is central to this book. The theory of decay is intimately connected with scattering theory and necessarily contains mathematical ideas and methods. We shall try to explain these points carefully as we get to them. We treat elsewhere in the book the ideas of Boltzmann, Van Hove and Prigogine on irreversible phenomena. The tools that are developed there are basically approximate, although very useful. One can argue that the basic rigorous characteristic of an irreversible process is that, as represented in terms of the evolution of a state in the Hilbert space of the quantum theory, it must be a semigroup. This type of evolution, resulting in an operation Z ( t ) on a state ψ , should satisfy the property Z ( t 2 ) Z ( t 1 ) = Z ( t 1 + t 2 ). (17.1) The argument is as follows. If the system evolves in time t 1 and is stopped, then evolves further at time t 2 , since the process has no memory, the total evolution should be as if the system evolved from the initial state to a state at t 1 + t 2 independently of the fact that it was done in two stages (Piron, 1976). Since the process is irreversible, the operator Z ( t ) may have no inverse. Such an evolution is called a semigroup . As we shall see, it is not possible to obtain such an evolution law in the framework of the standard quantum theory (Horwitz et al. , 1971), but recently much work has been done, and methods have been developed, based on ideas of Sz.-Nagy and Foias (1976), such as the theory of Lax and Phillips (1967) and its extension to the quantum theory (Strauss et al. , 2000) in which semigroup evolution can be achieved.
It is assumed that any decay process is described in a Hilbert space $\Cal H=\oplus \Cal H_D$, where $\Cal H_A$ corresponds to an unstable particle and $\Cal H_D$ to its decay products. It is shown that the generalized Weisskopf-Wigner condition (which guarantees an exponential decay law of the given unstable particle) has a close relation to the irreversibility of decay processes as well as of collision ones described in the same space $\Cal H$. If unitarity is added the principal structure of $\Cal H$ is identical with that onwhich the scattering theory of Lax and Phillips is based.
It has been shown by Flesia and Piron that the scattering theory of Lax and Phillips, developed primarily for the treatment of hyperbolic systems (e.g., classical scattering of electromagnetic waves on a finite target), can be applied to the quantum theory. In order to construct the correspondence, the continuously infinite family of (isomorphic) Hilbert spaces associated with each value of the time (are taken to be a direct integral representation (with a choice of measure) of a larger Hilbert space which includes the variable t in its measure space. We show that this theory, for which the evolution contracted to the subspace orthogonal to the incoming and outgoing subspaces is a contractive semigroup, provides a natural description of the irreversible motion of an unstable quantum system
In this talk we discuss how to combine aspects of the theory of stable relativistic particles and of the theory of non-relativistic decaying particles into a relativistic theory of unstable particles and resonances. For the theory of stable relativistic particles we use Wigner’s description by unitary irreducible representations (UIR) of the Poincaré group [ 1 ] which has been the foundation for relativistic quantum mechanics and field theory [ 2 ]. For the non-relativistic decaying particles we use a time asymmetric quantum mechanics in which the Hilbert space axiom, that allows only symmetric (unitary group) time evolution, is replaced by time asymmetric boundary conditions which lead to an irreversible , semigroup time evolution [ 3 ]. In the limit in which certain contributions to the energy continuum are neglected, this new quantum mechanics leads to the Weisskopf-Wigner approximate methods [ 4 ] for decay, and to the Breit-Wigner energy distribution [ 5 ] for the resonance lineshape. We thus generalize and combine two fundamental contributions of Wigner into a description of relativistic resonances and decaying states. The central concept of this description is the relativistic Gamow vector, which is a generalized eigenvector (ket) of the self-adjoint invariant square mass operator https://www.w3.org/1998/Math/MathML" display="inline"> M 2 = P μ P μ P μ = P 1 μ + P 2 μ in resonance scattering 1±2→ R →3±4) with a complex eigenvalue, a relativistic Breit-Wigner energy distribution, and an exponential time evolution governed by a semigroup of continuous operators in the space of kets.
Traditional Quantum Scattering theory is built upon a Hilbert space formalism. The nature of the Hilbert space has led to a number of ideas about the nature of scattering systems, chief among them being the understanding that the decay of unstable quan- tum systems cannot be purely exponential and that there can only be an approximate relationship between the width Γ of a scattering resonance and the lifetime τ of the resonant state whose formation gives rise to it. That such physical conclusions are de- rived from purely mathematical properties of the underlying topological vector space inform the notion that, in choosing a particular space, one is choosing the mathemat- ical representation of the physical universe for the system. With this notion in mind, purely physical characteristics of quantum systems are used to answer the question: “What is the proper mathematical space for quantum mechanical calculations?” In the particular case of quantum scattering, it is shown that this approach casts the choice of the Hilbert space into doubt and motivates instead the use of rigged Hilbert spaces employing Hardy spaces; in these Hardy rigged Hilbert spaces, exponential decay is permissible and the time evolution of decaying states is governed by semigroups. The original theories concerning deviation from exponential decay in the Hilbert space are revisited to reveal how their conclusions flow from a mathematical property whose physical interpretation is problematic. Finally, an application of a Hardy rigged Hilbert space formalism is presented: Time Asymmetric Quantum Mechanics, as developed by A. Bohm, M. Gadella, and S. Wickramasekara.
Intrinsic theory of irreversibility In connection with the previous chapter on Wigner–Weisskopf, quantum irreversibility, Gamov states and the Lax–Phillips theory of decay, we shall examine the recent program in statistical mechanics carried forward by Ilya Prigogine and his colleagues since his early book in 1962 (Prigogine, 1962). This discussion is somewhat out of the focus of the present book, since the work to be discussed has principally been devoted to isolated quantum systems, not those in interaction with “reservoirs.” In addition, Prigogine's work is very classical in its content. We shall not attempt the task of reviewing the many changes that have taken place between 1962 and the present. Fine texts describing some of this work are those of Balescu (1963, 1975). A recent critical overview of the “modern view” is in the unpublished thesis of B. C. Bishop of the University of Texas Philosophy Department (Bishop, 1999). In many ways this is related to the use of Gel'fand triplets (Gel'fand and Vilenkin, 1968), mentioned in Chapter 17.6, to describe irreversible quantum states, i.e. Gamov states. See Chapter 17, the book of Bohm and Gadella (1989) and also the more recent review article by Bohm and colleagues (Bohm et al. , 1997). The object in statistical mechanics is to extend the range of the Liouville operator (classical and quantum) such that its eigenvalues are complex and intrinsically irreversible. Statistical mechanics has always been focused on many particle systems and the appearance of a continuum spectrum in the thermodynamic limit, already used in many places in this book. In the classical case Antoniou and Tasaki carried out the adaptation of the Gel'fand triplet approach to the Liouville operator, but this is, apparently, not possible quantum mechanically (Antoniou and Tasaki, 1993). Thus, another route must be taken in what Prigogine has termed, for emphasis, “large Poincaré systems” which have a continuum spectrum (Prigogine, 1997).
A Lyapunov operator is a self-adjoint quantum observable whose expectation value varies monotonically as time increases and may serve as a marker for the flow of time in a quantum system. In this paper it is shown that the existence of a certain type of Lyapunov operator leads to representations of the quantum dynamics, termed transition representations, in which an evolving quantum state ψ(t) is decomposed into a sum ψ(t) = ψb(t) + ψf(t) of a backward asymptotic component and a forward asymptotic component such that the evolution process is represented as a transition from ψb(t) to ψf(t). When applied to the evolution of scattering resonances, such transition representations separate the process of decay of a scattering resonance from the evolution of outgoing waves corresponding to the probability “released” by the resonance and carried away to spatial infinity. This separation property clearly exhibits the spatial probability distribution profile of a resonance. Moreover, it leads to the definition of exact resonance states as elements of the physical Hilbert space corresponding to the scattering problem. These resonance states evolve naturally according to a semigroup law of evolution.