Confinement of ion clouds in an rf octupole ion trap is investigated with particular emphasis on the trapping stability, which is position dependent. Excitation spectra of trapped clouds of
Ba+ ions are observed, and the kinetic energy of ion clouds is derived. The spatial extension of ion clouds is measured, providing the basis for an experimental study of the trapping stability. For ion clouds in an rf octupole trap the mean kinetic energy is smaller and the spatial extension is larger than in comparable Paul traps.
We investigate the quantum dynamics of a single ion confined in a radio-frequency (RF) Paul trap in the presence of weak octupole-induced anharmonicity, as can occur in realistic ion-trap potential. The explicitly time-dependent quadrupole potential is treated in a reference-oscillator Fock basis, allowing the effects of the RF drive and the quartic correction to be resolved directly at the level of motional-state couplings. While the quadratic RF interaction generates
Δn=±2 transitions and Gaussian squeezing, the quartic contribution opens additional
Δn=±4 coupling pathways. Starting from the reference-oscillator vacuum, we show that the octupole interaction broadens the even-parity Fock-state distribution and enhances the phonon-number fluctuations more strongly than the mean occupation. At the same time, the RF-induced sub-vacuum quadrature squeezing remains robust, although its magnitude and orientation are modified by the quartic interaction. The number statistics and quadrature fluctuations therefore respond differently to the same nonlinear perturbation, reflecting the distinct roles of Fock-space redistribution and phase coherence. The resulting dynamics provide a quantum-mechanical characterization of weak octupole corrections beyond the ideal quadrupole approximation and clarify how realistic anharmonicities modify nonclassical trapped-ion motion. Importantly, the motional nonclassicality remains robust against the weak octupole perturbation, as evidenced by persistent sub-vacuum quadrature squeezing and Klyshko-inequality violation. These results characterize how realistic anharmonic corrections reshape trapped-ion motion beyond the ideal quadrupole approximation.