When a second-order phase transition is crossed at finite speed, domains with independent order parameters can appear in the system, with the consequent formation of defects at the domain boundaries. The Kibble-Zurek theory provides a description for this universal phenomenon, which applies to many different systems in nature, and it predicts a power-law dependence of the defect density on the quench rate. This thesis reports on the results of the experimental study of the Kibble-Zurek mechanism in elongated Bose-Einstein condensates of atomic sodium gases, following the observations on the spontaneous formation of defects after temperature quenches across the BEC transition. The power-law scaling of the defect number with the quench speed was observed and characterized for the first time in ultracold gases. The characterization of the density and phase profiles of the defects allowed their identification as solitonic vortices, representing the first direct experimental evidence for this kind of long living excitation, which sets a link between solitons and vortices. The measurements reported in this thesis provide a novel approach to the study of the critical phenomena happening at phase transitions, and introduce to the possibility of exploring the turbulent dynamics of quenched systems through the spontaneous production of solitonic vortices.
When a second-order phase transition is crossed at finite speed, domains with independent order parameters can appear in the system, with the consequent formation of defects at the domain boundaries. The Kibble-Zurek theory provides a description for this universal phenomenon, which applies to many different systems in nature, and it predicts a power-law dependence of the defect density on the quench rate. This thesis reports on the results of the experimental study of the Kibble-Zurek mechanism in elongated Bose-Einstein condensates of atomic sodium gases, following the observations on the spontaneous formation of defects after temperature quenches across the BEC transition. The power-law scaling of the defect number with the quench speed was observed and characterized for the first time in ultracold gases. The characterization of the density and phase profiles of the defects allowed their identification as solitonic vortices, representing the first direct experimental evidence for this kind of long living excitation, which sets a link between solitons and vortices. The measurements reported in this thesis provide a novel approach to the study of the critical phenomena happening at phase transitions, and introduce to the possibility of exploring the turbulent dynamics of quenched systems through the spontaneous production of solitonic vortices.
We investigate the dynamics of formation of topological defects in ultra-cold quantum gases. Using classical field methods, such as the truncated Wigner approximation and the stochastic Gross-Pitaevskii equation, we explore the connection between the rate of a phase transition and the number of topological defects formed as a consequence of it. We show that in various systems such defects form in number comparable with the predictions of the Kibble-Zurek theory, known for thirty years but as yet unverified experimentally. We also consider the spontaneous production of entangled vortices following a quantum phase transition in a multi-component spin-1 Bose-Einstein condensate (BEC). To begin, we provide a literature review and describe some of the background theory of multi-component condensates, stochastic methods and Kibble-Zurek theory. Part of this thesis focus on a two component Bose-Einstein condensates of the same atomic species. In particular on the quantum critical point separating the miscible from the immiscible phase of such systems. We show that such phase transition cannot only be achieved with the tuning of the interaction constants between the components, but also through changes in the intensity of the coupling between atoms in different hyperfine states. We first determine the value of the critical coupling, and also the critical exponents defining the universality class of the coupling—induced phase transition. We then proceed to simulate the dynamics of the transition in effective 1D ring and harmonically trapped condensates, and test the results against predictions of the Kibble-Zurek (KZ) mechanism. We find good agreement between the KZ theory and the numerical results in the ring geometry, and we motivate the origin of the discrepancies between the two in harmonically trapped BECs. We use the ”equivalence” of inhomogeneous phase transitions in anisotropic systems and spatially inhomogeneous quenches to engineer coupling quenches and systematically study key aspects of the inhomogeneous KZ mechanism. The coupling induced miscible—immiscible transition results in the formation of a stable pattern of domains that easily be detected and counted in current ultra-cold gases experiment, and the scheme is a viable candidate for the first experimental testing of the KZ predictions. We then examine the spontaneous formation of a superflow as result of the thermal Bose-Einstein phase transition in ring traps. According to the Kibble-Zurek theory, the fast production of a condensate in a ring trap should result in the formation of solitons, with the number depending on the rate of the temperature quench. Solitons are short-living topological defects and their observation in ultra-cold gases experiments remains challenging. We show here that even after they decay, solitons leave a signature in the variance of the final winding number of the condensate. Solitons fragment a 1D condensate into regions of random phase, hence the larger the number of solitons, the higher the probability that the resulting phase wraps around the ring by a multiple of 2π. We numerically simulate the BEC transition in this system with the stochastic Gross-Pitaevskii equation, and observe that the winding number scales with the quenching time as predicted by the KZ mechanism. We examine the effect of inhomogeneity on the expectation value of the winding number, and find that the tilting of the ring greatly suppress the spontaneous formation of vortices. This has implications for the necessary horizontal alignment of any experiment on this system. Finally, we consider the polar to anti-ferromagnetic phase transition in magnetically quenched spin-1 BEC. In this quantum phase transition a pure condensate of atoms in the mF = 0 Zeeman sublevel is converted into a three component BEC with atoms in mF = 0, ±1 through spin changing collisions. An analogous mechanism, four—wave mixing, in quantum optics produces entangled photons, and it has been proposed in ultra-cold gases as a method to obtain Einstein-Podolski-Rosen entanglement of macroscopic atomic ensembles. We begin with a rotating 1D spinor condensate of atoms in the mF = 0 component, and perform a quench of the magnetic field through the critical point. We show how the transition produces a pair of entangled components with different winding numbers, and quantify the entanglement as a function of the modes considered and of the type of magnetic quench, sudden or instantaneous. Lastly, we propose a method to use the original spin zero component as coherent source to perform homodyne detection and consider the two rotating entangled components as a resource for the sensing of rotations.
We study the formation of defects in a Bose-Einstein condensate as is described by the Kibble-Zurek mechanism. The mechanism describes the formation of defects when a second order phase transition is crossed at a finite rate. This is done by shock cooling or quenching the last part of the evaporative cooling process where the transition into the condensed state is made. This allows for the study of the amount of solitons formed as a function of the quench time with the ultimate goal of determining the critical exponents of the phase transition. The amount of solitons is predicted by the Kibble-Zurek mechanism to scale as the quench time to the power alpha, which we attempted to measure. The dynamics of solitons are also studied in order to determine the time scale on which they decay. This turns out to be in the order of 0.29 seconds, and thus an important factor, since we consider quench times in the order of seconds. When correcting for the decay on this timescale, it turns out that alpha is extremely sensitive to variations in the decay time and therefore we were not able to give conclusive evidence on a value for the exponent. Instead we estimate the value of alpha to be between 0.5 and 2, based on our measurements.
Atomic Bose-Einstein condensates confined to a dual-ring trap support Josephson vortices as topologically stable defects in the relative phase. We propose a test of the scaling laws for defect formation by quenching a Bose gas to degeneracy in this geometry. Stochastic Gross-Pitaevskii simulations reveal a -1/4 power-law scaling of defect number with quench time for fast quenches, consistent with the Kibble-Zurek mechanism. Slow quenches show stronger quench-time dependence that is explained by the stability properties of Josephson vortices, revealing the boundary of the Kibble-Zurek regime. Interference of the two atomic fields enables clear long-time measurement of stable defects and a direct test of the Kibble-Zurek mechanism in Bose-Einstein condensation.
The problem of understanding how a coherent, macroscopic Bose- Einstein condensate (BEC) emerges from the cooling of a thermal Bose gas has attracted significant theoretical and experimental interest over several decades. The pioneering achievement of BEC in weakly interacting dilute atomic gases in 1995 was followed by a number of experimental studies examining the growth of the BEC number, as well as the development of its coherence. More recently, there has been interest in connecting such experiments to universal aspects of nonequilibrium phase transitions, in terms of both static and dynamical critical exponents. Here, the spontaneous formation of topological structures such as vortices and solitons in quenched cold-atom experiments has enabled the verification of the Kibble-Zurek mechanism predicting the density of topological defects in continuous phase transitions, first proposed in the context of the evolution of the early universe. This chapter reviews progress in the understanding of BEC formation and discusses open questions and future research directions in the dynamics of phase transitions in quantum gases. Introduction The equilibrium phase diagram of the dilute Bose gas exhibits a continuous phase transition between condensed and noncondensed phases. The order parameter characteristic of the condensed phase vanishes above some critical temperature T c and grows continuously with decreasing temperature below this critical point. However, the dynamical process of condensate formation has proved to be a challenging phenomenon to address both theoretically and experimentally. This formation process is a crucial aspect of Bose systems and of direct relevance to all condensates discussed in this book, despite their evident system-specific properties. Important questions leading to intense discussions in the early literature include the time scale for condensate formation and the role of inhomogeneities and finite-size effects in “closed” systems. These issues are related to the concept of spontaneous symmetry breaking, its causes, and implications for physical systems (see, for example, Chapter 5 by Snoke and Daley). In this chapter, we give an overview of the dynamics of condensate formation and describe the present understanding provided by increasingly well-controlled cold-atom experiments and corresponding theoretical advances over the past twenty years. We focus on the growth of BECs in cooled Bose gases, which, from a theoretical standpoint, requires a suitable nonequilibrium formalism.
The emergence of order from an initially uncorrelated state across a phase transition is a central problem in quantum many-body physics, particularly in multicomponent systems where interactions between components lead to rich nonequilibrium dynamics. While defect formation is known to follow universal scaling laws, prior studies have focused mainly on defect density, leaving their spatial organization largely unexplored. Here we show that gradually tuning the chemical potential in a two-dimensional binary Bose gas drives condensation into either a miscible or immiscible phase. In the immiscible regime, domains form whose number, size, and boundary length obey Kibble-Zurek (KZ) scaling and evolve self-similarly. In the miscible regime, vortices emerge with KZ scaling. In both cases, the spatial distribution of vortices and domains is well described by a Poisson point process with KZ-determined density. These results reveal universal features of far-from-equilibrium dynamics and provide a framework to characterize stochastic geometry in multicomponent quantum systems. Driving a binary quantum gas mixture through a continuous phase transition can create domains or vortices, depending on the interaction regime. Here, the authors show that their formation universally follow Kibble-Zurek scaling and Poisson spatial statistics with predictions testable in ultracold atom experiments.
We study the spontaneous formation of defects in the order parameter of a trapped ultracold bosonic gas while crossing the critical temperature for Bose-Einstein condensation at different rates. The system has the shape of an elongated ellipsoid, whose transverse width can be varied. For slow enough temperature quenches we find a power-law scaling of the average defect number with the quench rate, as predicted by the Kibble-Zurek mechanism. A breakdown of such a scaling is found for fast quenches, leading to a saturation of the average defect number. We suggest an explanation for this saturation in terms of the mutual interactions among defects.