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Journal of Dezhou University

The Explanation of Oppositely Aligned Electron Pairs in Molecules

Shutao Wang

Published Jan 1, 2011• 0 citations
OpenAlex

Abstract

The symmetric properties of wave functions of bosons and fermons were proposed by the principles of quantum mechanics.The calculation of the expectation value of the square of the separation distance between two particles confirms that bosons with symmetric wave functions under exchange tend to be attractive,while fermions with antisymmetric wave functions under exchange have some repulsive properties.Based on this point of view,the electron wave function is product of position wave function and spin wave function,the position wave functions of oppositely aligned electrons must be symmetric and attraction appears,resulting in electron pairs.

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The symmetric properties of wave functions of bosons and fermons were proposed by the principles of quantum mechanics.The calculation of the expectation value of the square of the separation distance between two particles confirms that bosons with symmetric wave functions under exchange tend to be attractive,while fermions with antisymmetric wave functions under exchange have some repulsive properties.Based on this point of view,the electron wave function is product of position wave function and spin wave function,the position wave functions of oppositely aligned electrons must be symmetric and attraction appears,resulting in electron pairs.
Bosons have symmetric wave function under particle exchange, while fermions have antisymmetric wave functions. This leads to differences in behavior of the two kinds of particles even in the gaseous state. Strong repulsive forces between atoms at close range are due to the Pauli principle that forbids two electrons to be in the same energy or position state. A repulsive Pauli pressure operates similarly in white dwarf stars. Bosons undergo Bose–Einstein condensation because of Bose statistics. The wave function symmetry of particles with spin can affect the magnetic states and the behavior of transport properties, for example, viscosity and thermal conductivity. The symmetry properties of bosons at a beam splitter are demonstrated in the Hong–Ou–Mandel effect or in a Michelson interferometer via the Hanbury Brown-Twiss effect. Researchers see boson bunching and fermion antibunching in experiments considered.
Abstract Two concepts, of fundamental importance to quantum mechanics, will be discussed in this chapter. The first is that of symmetry. Even though the concept of symmetry is familiar in a wide range of natural sciences, the way symmetry constrains the consequences of quantum mechanics is rather subtle and, at the same time, far-reaching. The second is the symmetry property of the states under the exchange of two identical particles. Identical particles with a half-integer spin (fermions) obey the Fermi–Dirac statistics: the wave functions are totally antisymmetric under the exchange of the particles. Identical particles with an integer spin (bosons) are instead subject to the Bose–Einstein statistics. Their wave functions are totally symmetric.
This chapter discusses the properties of systems of identical particles. It presents the wave functions of a system composed of N identical and independent particles. From the properties of the wave functions, the chapter shows that identical particles can be characterized by symmetric as well as antisymmetric wave functions. As a result, it distinguishes two kinds of particles: bosons and fermions. Fermions have half integer spin, whereas bosons have integer spin. Since an arbitrary number of bosons can occupy the same state, atoms with integer spin can abruptly condensate into a single ground state when the temperature of the atoms goes below a certain critical value. In atoms, a limited number of electrons can occupy the same energy level. The Pauli principle prevents the energy states being occupied by an arbitrary number of electrons. Thus, the Pauli principle prevents all atoms having the same size and the same energy.
Abstract “Identical particles and the helium atom” introduces bosons and fermions. Fermion states are expressed in terms of Slater determinants and the Pauli Principle. Helium is presented in such a way as to show what properties are and are not due to electron identity. Quantum states are described according as the space wave function is symmetric or antisymmetric under interchange of labels attached to the electrons. These in turn form singlet and triplet spin states when the electrons’ fermion identity is taken into account. Helium is an example of LS coupling, but a rather stunted example.
Symmetries and wave functions An important difference between the classical and quantum perspectives is their different criteria of distinguishability. Identical particles are classically distinguishable when separated in phase space. On the other hand, identical particles are always quantum mechanically indistinguishable for the purpose of counting distinct microstates. But these concepts and these distinctions do not tell the whole story of how we count the microstates and determine the multiplicity of a quantized system. There are actually two different ways of counting the accessible microstates of a quantized system of identical, and so indistinguishable, particles. While these two ways were discovered in the years 1924–1926 independently of Erwin Schrödinger’s (1887–1961) invention of wave mechanics in 1926, their most convincing explanation is in terms of particle wave functions. The following two paragraphs may be helpful to those familiar with the basic features of wave mechanics. A system of identical particles has, as one might expect, a probability density that is symmetric under particle exchange, that is, the probability density is invariant under the exchange of two identical particles. But here wave mechanics surprises the classical physicist. A system wave function may either keep the same sign or change signs under particle exchange. In particular, a system wave function may be either symmetric or antisymmetric under particle exchange.
For a quantum mechanical system of N particles, the Hamiltonian is a sum of the total kinetic energy and the potential energy. In classical physics, it is possible to keep track of individual particles. A system of N identical particles is said to satisfy Bose-Einstein statistics if its wave function is symmetric under the exchange of particles, and these particles are known as bosons. In the nonrelativistic quantum mechanics, this principle must be accepted as an empirical postulate. In the relativistic quantum theory, it can be proven that half-integer-spin particles cannot be bosons and integer-spin particles cannot be fermions. The Pauli exclusion principle plays a critical role in programming physical properties of electrons or more generally fermions.